1.0 Mt/a催化裂化装置催化剂跑损原因分析

从催化剂性质、旋分器运行工况、工艺操作条件等方面分析了1.0 Mt/a催化裂化装置催化剂跑损原因,提出了相应整改措施。     

重油催化裂化装置再生器的设计

再生器是重油催化裂化装置中的关键设备,再生器设计的成功与否,将直接关系到装置能否高效、长周期地运行。随着诸多新技术、新工艺的不断出现,装置的大型化对再生器设备的设计、制造、安装、运行提出了更高的要求。该文就重油催化裂化装置再生器的结构设计、选材的考虑、壳体应力腐蚀预防措施等问题进行了较详细的论述和分析。     

Experimental results for a magnetic refrigerator using three different types of magnetocaloric material regenerators

Magnetic refrigeration is a potentially environmentally-friendly alternative to vapor compression technology because it has a potentially higher coefficient of performance and does not use a gaseous refrigerant. The active magnetic regenerator refrigerator is currently the most common magnetic refrigeration device for near room temperature applications, and it is driven by the magnetocaloric effect in the regenerator material. Several magnetocaloric materials with potential magnetic refrigeration applications have recently been developed and characterized; however, few of them have been tested in an experimental device. This paper compares the performance of three magnetocaloric material candidates for AMRs, La(Fe,Co,Si)₁₃, (La,Ca,Sr)MnO₃ and Gd, in an experimental active magnetic regenerator with a parallel plate geometry. The performance of single-material regenerators of each magnetocaloric material family were compared. In an attempt to improve system performance, graded two-material regenerators were made from two different combinations of La(Fe,Co,Si)₁₃ compounds having different magnetic transition temperatures. One combination of the La(Fe,Co,Si)₁₃ materials yielded a higher performance, while the performance of the other combination was lower than the single-material regenerator. The highest no-load temperature span was achieved by the Gd regenerator.     

A single-stage GM-type pulse tube cryocooler operating at 10.6 K

In order to explore the lowest attainable refrigeration temperature and improve cooling performance at temperatures around 20 K for a single-stage G-M type pulse tube cryocooler (PTC), numerical and experimental studies were performed. The National Institute of Standards and Technology (NIST) numerical model known as REGEN was applied to the simulation of a G-M type PTC for the first time. Based on the calculation results, a single-stage G-M type PTC was designed, fabricated and tested. The performance improvement of the regenerator in the temperature range of 10-80 K was investigated. The calculations predicted a lowest temperature of 10 K. A lowest temperature of 10.6 K was achieved experimentally with an input power of 7.5 kW, which is the lowest temperature ever achieved by a single-stage PTC. Further more, the cryocooler can provide a cooling power of 20 W at 20.6 K and 39.5 W at 30 K, respectively.     

Performance analysis for glass furnace regenerator

Glass manufacturing is an energy intensive process where fossil fuel is used to maintain high temperature (about 1700 °C) for glass melting. Heat recovery from flue gas (1350–1500 °C) is usually in the form of combustion air pre-heating (900–1200 °C) using a regenerator. Dust from flue gas which is carried over from the furnace gets deposited in the regenerator storage matrix path. This leads to a deterioration of regenerator efficiency. A regenerator model is developed to estimate the actual performance of the regenerator and to compare it with the target performance. The proposed model is based on mass and energy balance of streams along with heat transfer characteristic equations. The model is illustrated for a 130 TPD (Ton per Day) furnace regenerator of an industrial glass plant at Mumbai, India. Model results for the regenerator studied indicate a blockage of 50% on the doghouse side and 22% on the non-doghouse side of the regenerator. The actual performance of the regenerator is found to be 7% lower than its target performance for the doghouse side regenerator. The model developed can also be used in other industrial sectors like steel, chemical etc.     

Analysis and design consideration of mean temperature differential Stirling engine for solar application

This article presents a technical innovation, study of solar power system based on the Stirling dish (SD) technology and design considerations to be taken in designing of a mean temperature differential Stirling engine for solar application. The target power source will be solar dish/Stirling with average concentration ratio, which will supply a constant source temperature of 320 °C. Hence, the system design is based on a temperature difference of 300 °C, assuming that the sink is kept at 20 °C. During the preliminary design stage, the critical parameters of the engine design are determined according to the dynamic model with losses energy and pressure drop in heat exchangers was used during the design optimisation stage in order to establish a complete analytical model for the engine. The heat exchangers are designed to be of high effectiveness and low pressure-drop. Upon optimisation, for given value of difference temperature, operating frequency and dead volume there is a definite optimal value of swept volume at which the power is a maximum. The optimal swept volume of 75 cm³ for operating frequency 75 Hz with the power is 250 W and the dead volume is of 370 cm³.     

Performance improvement of a two-stage GM cryocooler by use of Er(Ni0.075Co0.925)2 magnetic regenerator material

A newly developed magnetic regenerator material Er(Ni_0.075Co_0.925)₂, having high specific heat at temperatures from 10 to 20 K, has been tested inside the second regenerator of a two-stage GM cryocooler. Different working conditions have been examined: four Er(Ni_0.075Co_0.925)₂/Pb material ratios, three displacer reciprocating speeds, and two cryocooler stroke lengths. In the best working conditions, the experimental results show a cooling power improvement up to 15% over the whole temperature range from 10 to 20 K compared to that of the same GM cryocooler employing only lead.     

Comparison of two models of a double inlet miniature pulse tube refrigerator: Part B electrical analogy

The design of a double inlet pulse tube refrigerator is investigated by means of an analogy with an electric circuit. The results obtained are compared with both those of the thermodynamic model (Part A) and experiments. The basic formulation of equivalent electronic components is discussed and a few improvements are proposed for adjusting the theoretical expressions of the electric impedance concerning the capillaries and the regenerator. Then additional effects such as pressure drops due to geometrical singularities are taken into account considering the different internal flow regimes that may occur. Besides a simplified formulation for the regenerator efficiency is deduced from considerations on its harmonic functioning. In this analysis, the emphasis concerns principally the design of miniature cryocoolers dedicated to electronic applications. Those models are applied to a commercial miniature refrigerator. A discussion of their relevance is achieved and a few suggestions on the refrigerator design are proposed in order to improve the cooling production.     

利用立体图分析马蹄焰窑蓄热室内流场分布

介绍了一种能直观、形象地反映蓄热室流场分布的新方法－把离散的实验数据绘制成透视立体图。对蓄热室流场的改善结果利用立体图进行了分析，认为流场分布立体图为流场改善程度的判断提供了一个有力的依据。     

Heat capacities and magnetic moments of potential regenerator materials at low temperatures

Several samples of rare-earth oxides of perovskite structure were developed and investigated between 1.5 and 10 K. The measurements have shown, that these materials have large magnetic moments and most of them exhibit a magnetic phase transition below 4 K. The heat capacities of the samples have been measured with the adiabatic heat-pulse method. The dependence of the heat capacity on the preparation temperature of the samples has been studied. The results of the measurements are presented in this paper. The possibility of using these materials as regenerator materials in cryocoolers, e.g. pulse-tube refrigerators, is discussed.