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《International Journal of Hydrogen Energy》2022,47(52):22203-22214
The gas purging states affect electricity output and energy storage capacity of unitized regenerative fuel cells. In this study, a model of unitized regenerative fuel cell is established. Cell voltages and operating temperatures influences on the dynamic distribution of thermal fluid during purging process and the discharge of residual liquid water in electrolytic cell mode are investigated. The motivation of the present study is better understanding the gas purging characteristics and its effect on reaction behaviors of unitized regenerative fuel cells. Simulation results reveal a significant influence of purging gas temperature on the water flooding and a great effect of operating voltage on the water diffusion. The operating temperature of electrolytic cell model almost has little effect on purging results at different cell temperature and the same purging gas temperature. When the purging gas temperature is changed, higher temperatures of cell and purging gas facilitate liquid water discharging out from the cell regions. In cell water flooding situation, when having large liquid content, the purging gas has little effects on the water expelling process. 相似文献
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《International Journal of Hydrogen Energy》2022,47(78):33272-33281
According to the International Energy Agency, only a small part of the full potential of biomass energy is currently used in the world. The annual amount of agricultural waste in the Russian Federation is estimated at about 152 million tons, and the energy potential of animal waste is 201 PJ/year. Anaerobic digestion is an efficient method of converting organic waste into renewable energy sources. Previously, the positive effect of pretreatment of various organic feedstocks in vortex layer apparatus (VLA) on the characteristics of anaerobic digestion and energy efficiency was shown. Currently, there is a significant interest in the world in obtaining biohydrogen from organic waste using the dark fermentation (DF) process. During pretreatment in the VLA, the iron working bodies are abraded and iron particles are introduced into the feedstock of the DF reactor. This may have a positive effect on the production rate and yield of hydrogen, which has not been previously studied. This work is aimed at evaluating the possibility of using the VLA as a method for pretreatment of a dark fermentation feedstock for the intensification of biohydrogen production. To achieve this goal, an experimental setup was constructed. It consisted of a 45 L DF reactor, a VLA and a process control system to collect data on the DF process parameters every 5 min. At a hydraulic retention time in the DF reactor of 24 h and in the VLA of 30 s, the hydrogen content in the biogas increased from 51.1% to 52.2%. At the same time, the pH increased from 3.85 to 4.8–4.9, and the hydrogen production rate increased by 16% to 1.941 L/(L day). The hydrogen yield was 80.9 ml/g VS. Thus, pretreatment of the feedstock in VLA can be an effective way to intensify the DF process; however, further study of the VLA operating modes is required in order to optimize the concentrations of iron particles introduced into the feedstock for the most efficient continuous production of dark fermentative biohydrogen. 相似文献
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《Mechatronics》2022
This paper considers the shared path following control of an unmanned ground vehicle by a single person. A passive measure of human intent is used to blend the human and machine inputs in a mixed initiative approach. The blending law is combined with saturated super-twisting sliding mode speed and heading controllers, so that exogenous disturbances can be counteracted via equivalent control. It is proven that when the proposed blending law is used, the combined control signals from both the human and automatic controller respect the actuator magnitude constraints of the machine. To demonstrate the approach, shared control experiments are performed using an unmanned ground vehicle, which follows a lawn mower pattern shaped path. 相似文献
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Dr. Barbara Wienen-Schmidt Matthias Oebbeke Dr. Khang Ngo Prof. Dr. Andreas Heine Prof. Dr. Gerhard Klebe 《ChemMedChem》2021,16(1):292-300
In lead optimization, protein crystallography is an indispensable tool to analyze drug binding. Binding modes and non-covalent interaction inventories are essential to design follow-up synthesis candidates. Two protocols are commonly applied to produce protein–ligand complexes: cocrystallization and soaking. Because of its time and cost effectiveness, soaking is the more popular method. Taking eight ligand hinge binders of protein kinase A, we demonstrate that cocrystallization is superior. Particularly for flexible proteins, such as kinases, and larger ligands cocrystallization captures more reliable the correct binding pose and induced protein adaptations. The geometrical discrepancies between soaking and cocrystallization appear smaller for fragment-sized ligands. For larger flexible ligands that trigger conformational changes of the protein, soaking can be misleading and underestimates the number of possible polar interactions due to inadequate, highly impaired positions of protein amino-acid side and main chain atoms. Thus, if applicable cocrystallization should be the gold standard to study protein–ligand complexes. 相似文献
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华润水泥(罗定)有限公司根据物料储存需求,共有三个长堆棚分为9个室内料场堆放原材料及混合材,厂内有4台铲车无规则轮流在这8个料场内作业,同时外来运料货车、公司化验及验收人员也会不间断地进入不同堆棚。由于料场内空间狭窄,驾驶员视线不好,如果堆棚料场内铲车在作业时,有其他人员或车辆进入铲车工作区域共同作业,在没有检测装置对进入的人、车进行识别,提醒铲车驾驶员的情况下,容易发生碾压进入人员或车辆碰撞的安全事故。公司根据现场实际,自2020年起决定实施从堆场出入口智能红外感应技术、装载机车载识别系统、智能声光语音提醒、实时监控显示、照明、堆场硬件设施等五方面实施物料堆场车辆智能化安全预警系统项目。 相似文献
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设计实现了一种可用于脊髓神经刺激器的多通道大电流神经刺激器。提出将电极短接和插入短电流脉冲相结合的混合模式,在大电流下,能更加快速地实现电荷平衡。电路设计上,将ADC动态比较器的回踢噪声消除技术应用于神经刺激器,使得动态比较器在输入压差较小时能够输出正确的比较结果,从而将电极上残留电压保持在更安全的范围内。基于CSMC 0.25 μm BCD工艺进行设计与仿真,结果表明,在单向且最大刺激电流为4 mA、刺激脉宽为60 μs、刺激周期为750 μs的条件下,该15 V、16路神经刺激器能实现±50 mV安全电压的有源电荷平衡。 相似文献
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This study focuses on the asynchronous control problem for two‐dimensional discrete‐time hidden Markovian jump systems where the mode observation conditional probability matrix is partly known. Considering the original system modes are invisible, the observed modes emitted from an observer serve as an alternative for stability analysis and controller design where a mode observation conditional probability matrix is constructed to characterize the emission between system modes and observed modes. Specially, only partly known information of the mode observation conditional probability matrix is accessible. With the introduction of the free‐connection weighting matrices, the asymptotic mean square stability criterion is firstly derived based on Lyapunov method. This introduction provides a further degree of relaxation and less conservatism is therefore achieved. Secondly, we present synthesis conditions for asynchronous state feedback controller design given in terms of a set of interconnected linear matrix inequalities. Moreover, cluster concept based on the partitions of observed modes is adopted which helps to decrease the number of controllers and simplify the design complexity. A numerical example, regarding the cases with and without clustering of the observed modes, is presented to illustrate the effectiveness of the proposed method. 相似文献