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1.
针对钛合金薄壁曲面工件磨粒流抛光后表面粗糙度分布不均匀的问题,提出一种基于液态金属的磨粒流加工方法。基于SST k-ω模型、OKA冲蚀模型,流体流动颗粒追踪模型,采用COMSOL有限元软件对不同电场布置下的液态金属-磨粒流动力学特性开展深入研究。仿真结果表明,通过电场的合理布置可以控制液态金属颗粒在流场中运动;合理的电场布置可以有效提高工件表面加工均匀性,并通过仿真得出了一组冲蚀较好的试验参数。基于仿真结果开展了液态金属-磨粒流加工试验,试验结果表明:液态金属-磨粒流加工方法可有效提高工件表面加工的均匀性。在加工14 h后,不加电场的磨粒流加工表面不同区域的粗糙度分布不均,工件凹陷处粗糙度明显大于凸起处,各区域表面粗糙度极差达到66.1 nm。使用液态金属-磨粒流加工后的工件表面各区域粗糙度的均匀性明显提高,各区域表面粗糙度极差减小为20.3 nm,为液态金属-磨粒流加工的开展及其调控提供了理论和试验依据。 相似文献
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3.
周清庄油田存在地层产状陡、砂体厚度薄、油层埋藏深等特征,导致水平井在油层钻进过程中,极易造成井眼轨迹出层,为了解决这一难题,开展了水平井地质导向技术研究。通过分析该地区邻井钻遇储集层的实际情况,结合录井曲线中的钻时、气测以及测井曲线中的自然伽马、电阻率等参数对周清庄地区沙三3储集层的标志层以及储集层内部进行精细划分,在纵向上建立储集层与标志层在岩性、电性上的响应特征模型,并以该模型指导水平井钻进,即首先把钻遇的标志层与模型中的标志层进行分析对比确保着陆于油层,其次运用“蛙泳法”计算地层动态倾角,为确保水平段始终处于目的层内及时调整井眼轨迹,最终达到提高储集层钻遇率的目的。 相似文献
4.
Mechanical properties and thermal shock in thin ZrO2–Y2O3–Al2O3 films obtained by the sol-gel method
Antonio Díaz-Parralejo M. Ángeles Díaz-Díez José Sánchez-González Antonio Macías-García Juan Pablo Carrasco-Amador 《Ceramics International》2021,47(1):80-86
Thin multilayer coatings of ZrO2–Y2O3–Al2O3 were prepared using the sol-gel method and dip-coating technique in order to advance in the study of what influence the incorporation of Al2O3 has on films of Y2O3-doped ZrO2, investigating its role in the synthesis of the solutions and in the characteristics and properties of the coatings. After the characterization of the solutions used in the process, the microstructure of the films was studied and their mechanical behaviour and resistance to thermal shock were determined so as to optimize the characteristics and functionality of these coatings. With increased alumina content, 3YSZ-Al2O3 (20 mol%), the cubic phase of the zirconia disappeared completely at the sintering temperature used (700 °C), resulting in the tetragonal phase with Al in solution. There was also a decrease in the coatings' hardness and Young's modulus, and an increase in toughness and resistance to thermal shock. These results allow guidelines to be established for the design of multilayer structures that are, tougher, more resistant, and have improved surface properties. 相似文献
5.
《Ceramics International》2021,47(18):25574-25579
Vanadium dioxide (VO2) is known as a typical 3d-orbital transition metal oxide exhibiting the metal-to-insulator-transition (MIT) property near room temperature. However, their electronic applications have been challenged by the quality and uniformity of VO2 thin films. In this work, we demonstrate the high sensitivity in the valence charge of vanadium and the MIT properties of the VO2 thin films to the deposition temperature. This observation indicates the necessity to eliminate the inhomogeneity in the temperature distribution of substrate during the vacuum-deposition process of VO2. In addition, a high thermoelectric power factor (PF, e.g., exceeding 1 μWcm−1K−2) was achieved in the metallic phase of the VO2 thin films and this value is comparable to typical organic or oxide thermoelectric materials. We believe this high PF enriches the potential functionality in thermoelectric energy conversions beyond the existing electronic applications of the current vacuum-grown VO2 thin films. 相似文献
6.
《Ceramics International》2021,47(22):31442-31450
ITO/Ag/ITO multilayer thin films have been a potential substitute of the conventional single-layer transparent conducting film. Nevertheless, the mechanical stability under preparation and in-service conditions still limits their applications and developments. In this paper, the influences of different structural properties as well as layer structure on both surface morphological properties and mechanical properties of the ITO/Ag/ITO multilayer thin films in comparison with commercial single-layer ITO thin film were systematically investigated. The results demonstrate that, i) the tri-layer composite has large impacts on the preferential orientation, and exhibits the decreased values of surface roughness, net lattice distortion and residual stress; ii) the increased hardness (H) and decreased Young's modulus (E) for full annealed ITO/Ag/ITO multilayer films indicate that it is possible to tailor mechanical properties of the materials by manufacturing multilayer composite; iii) the ITO/Ag/ITO multilayer thin film exhibits remarkable improvements in wear resistance with the increase of annealing temperature, which is mainly attributed to the increased ratios of H/E and H3/E2. 相似文献
7.
Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films are attracting famous applications in antistatic coating, energy storage and conversion, printed electronics, and biomedical fields due to their conductivity, optical transparency and flexibility. However, PEDOT:PSS has poor dispersion stability during long-term storage and transport. Moreover, the dried PEDOT:PSS films are insoluble in any solvent and cannot be redispersed again. In comparison to bake drying, here, a feasible strategy to achieve mechanically redispersed PEDOT:PSS with the help of freeze-drying process was reported. The redispersed PEDOT:PSS can recover not only the initial characters such as pH, chemical composition, viscosity, and particle size under similar solid contents, but also conductivity and surface morphology of treated films. In addition, the treated film exhibits self-healing properties similar to pristine film in terms of mechanical and electrical properties. This technology enables reuse and overcomes the technical problems of PEDOT:PSS dispersion, realizing real-time processing to meet variable applications. 相似文献
8.
Min Ma Wan-Chang Sun Ya-Ru Dong Ya-Gang Zhang Yu-Wan Liu Sha-Sha Tian Yan Xiao 《工业材料与腐蚀》2021,72(5):912-924
Diamond-like carbon (DLC) possesses brilliant and excellent properties, including excellent corrosion resistance as well as outstanding wear resistance. Ni and B co-doped DLC films were deposited on AZ91D magnesium alloy by electrodeposition under mild conditions (300 V and 25°C). Uniform and dense morphology of co-doped DLC films were observed, and Ni and B were uniformly incorporated into the carbon-based films. Among all the electrodeposits, the appearance of D and G peaks near 1330 and 1570 cm−1 revealed that the as-deposited films were typical DLC films. As the addition of Ni was increased to 0.05 g, the highest microindentation hardness, the lowest friction coefficient, and wear loss were achieved to be 164.5 HV, 0.3, and 0.6 × 10−5 kg/m, respectively. The amorphous carbon films fabricated at 0.05 g Ni had the lowest corrosion current density and the most positive corrosion potential, which was mainly due to the small and dense granular structure effectively hindering the penetration of corrosion media. 相似文献
9.
Ian A. Brummel Daniel E. Drury Andrew R. Kitahara Farid El Gabaly Jon F. Ihlefeld 《Journal of the American Ceramic Society》2021,104(2):711-721
Lithium zirconium phosphate (LiZr2P3O12) thin films have been prepared on platinized silicon substrates via a chemical solution deposition approach with processing temperatures between 700°C and 775°C. Films that were subject to a single high-temperature anneal were found to crystallize at temperatures above 725°C. Crystallization was observed in films annealed after each deposited layer at 700°C and above. In both cases, grain size was found to increase with annealing temperature. Ion conductivity was found to increase with annealing temperature in singly annealed films. In per-layer annealed films ion conductivity was found to initially increase then decrease with increasing annealing temperature. A maximum ion conductivity of 1.6 × 10−6 S/cm was observed for the singly annealed 775°C condition, while a maximum ion conductivity of 5.8 × 10−7 S/cm was observed for the 725°C per-layer annealed condition. These results are consistent with an increasing influence of cross-plane, internal interface resistance and vapor phase carrier loss in the per-layer annealed samples. This work demonstrates that post-deposition processing methods can strongly affect the ion conducting properties of LiZr2P3O12 thin films. 相似文献
10.
The luminescent hydrogen-bonded organic framework (HOF) based films have become one of the most remarkable materials for optical application, thus, developing facile synthesis methods and establishing multifunctional applications for HOF-based luminescent materials are essential. Herein, a dual-emitting Eu3+-functionalized HOF hydrogel film ( 1 ) is fabricated successfully. 1 emits a blue-green long afterglow when turning off the UV lamp, and the long afterglow lifetime gets to 1.99 s. 1 performs great selectivity, high sensitivity, and low detection limit toward ofloxacin and flumequine, and the sensing toward ofloxacin and flumequine is in accord with the chroma and ratio modes. The fluorescent response mechanisms of 1 toward ofloxacin and flumequine are investigated in depth, which are further utilized to build an anticounterfeiting platform with high-level security. The film-based anticounterfeiting platform can conduct information encryption on demand inline with different fluorescent responses and can also fetch specific information by controlling the long afterglow intensity and excited light. This study not only provides a representative case of the fabrication of dual-emitting Eu3+-functionalized HOF-based hydrogel film but also opens the possibility of HOF-based film as intelligent luminescent materials with multifunctionalities. 相似文献