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排序方式: 共有8182条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2022,48(5):6266-6276
Porous diatomite ceramics with hierarchical pores and high apparent porosity (50.29–56%) were successfully fabricated via direct stereolithography. The pre-ball-milling time, dispersant type and dispersant concentration were systematically investigated to prepare diatomite pastes with high solid loading, low viscosity and a self-supporting effect. The results showed that a pre-ball-milling time of 24 h was more suitable to prepare diatomite pastes with high solid loading, and Span80 at 2 wt% was the optimal dispersant to obtain 40 vol% diatomite paste with a low viscosity and a self-supporting effect. To restrain the formation of defects, a heating rate as low as 0.2 °C/min was allowed to control the pyrolysis rate in the multistage debinding process. At sintering temperatures ranging from 900 °C to 1000 °C, porous diatomite ceramics exhibited a typical bimodal porosity, high apparent porosity and great flexural strength.  相似文献   
2.
《Ceramics International》2022,48(6):8155-8168
In the present study, the effect of oxy-acetylene flame angle on the erosion resistance of SiC/ZrB2–SiC/ZrB2 multilayer coatings with the gradient structure was investigated. To this aim, first, the SiC inner layer was applied by the reactive melt infiltration (RMI) technique; then ZrB2 and ZrB2–SiC layers with 10, 20 and 30%wt. SiC were applied on graphite by the plasma spraying technique. To prevent the oxidation of ZrB2 and SiC particles, the plasma spraying process was performed by a solid protective shield. To evaluate the performance of the coatings in erosive environments, the samples were exposed to oxy-acetylene flame at the angles of 30°, 60° and 90° for 360 s; the destruction mechanism of SiC/ZrB2–SiC/ZrB2 multilayer coatings appeared to be controlled mechanically and chemically. The results of the erosion test showed that at the low flame angles of about 30°, due to the shear forces of oxy-acetylene flame, mechanical erosion overcame the chemical one. With increasing the flame angle, due to raising the surface temperature, chemical erosion overcame the mechanical one; so, most chemical destruction occurred at the flame angle of 90°. Also, the results of the erosion test showed that the total chemical and mechanical destruction at the angle of 60° was greater than that in other angles. Also, among the coatings tested, SiC/ZrB2- 20% wt. SiC/ZrB2 coatings had the best erosion resistance; so, the weight changes under the oxy-acetylene flame at the angles of 30° and 60°, respectively, were about ?0.038%. and ?0.355%; meanwhile, at the angle of 90°, it was about +4.3%.  相似文献   
3.
《Ceramics International》2022,48(15):21268-21282
Mullite-Al2O3-SiC composites were in-situ synthesized through carbothermal reduction reaction of fly ash (FA) with a high alumina content and activated carbon (AC). The effects of sintering temperature, holding time, and amount of AC on the β-SiC yield, microstructure, dielectric properties, and electromagnetic (EM) absorption performance of the composites in the 2–18 GHz frequency range were studied. The results show that increasing the AC improves the porosities of the composites, with the highest porosity of 56.17% observed. The β-SiC yield varies considerably as the sintering parameters were altered, with a maximum yield of 23% achieved under conditions of 12 wt% AC, 1400 °C sintering temperature, and 3 h holding time. With a thickness of 3.5 mm, this composite has excellent EM absorption performance, exhibiting a minimum reflection loss (RLmin) of -51.55 dB at 7.60 GHz. Significantly, the maximum effective absorption bandwidth (EAB) reaches 3.39 GHz when the thickness is 3.0 mm. These results demonstrate that the composite prepared under ideal conditions can absorb 99.99% of the waves passing through it. Because of the interfacial polarization, conductive loss, and impedance matching of the heterostructure, the synthesized mullite-Al2O3-SiC composites with densities ranging from 1.43 g/cm3 to 1.62 g/cm3 demonstrate outstanding EM attenuation capabilities. Therefore, this study presents a remarkable way of utilizing fly ash to fabricate inexpensive, functional ceramic materials for EM absorption applications.  相似文献   
4.
Graphene nanoplatelets (GNPs) as reinforcement in the ceramic matrix is rising continuously due to their outstanding mechanical and lubricative properties. Herein, different compositions of GNPs (0.5–2 wt%) reinforced alumina-titania coatings were prepared using atmospheric plasma spraying. The relative density of AT coating increased from 83% to 94% with just (1.5 wt%) addition of GNP. Consequently, mechanical properties i.e. hardness and elastic modulus were improved by ~77% and ~69% respectively. Fracture toughness also increased from 2.65 ± 0.95 MPa.m1/2 to 5.85 ± 1.07 MPa.m1/2. Furthermore, the seawater wear test, using a ball-on-disc tribometer revealed that the wear rate of AT coating decreased from ~11 × 10?14 m3/Nm to ~4 × 10?14 m3/Nm, whereas the coefficient of friction reduced from 0.33 ± 0.05–0.16 ± 0.03. The mechanisms involved to improve these properties, viz. GNP sandwiching, crack bridging, crack arrest, etc. GNP’s multi-layers facilitated long-term lubricity and enhanced the wear resistance properties of the coatings.  相似文献   
5.
陈金焕 《石油物探》2022,(1):146-155
近地表速度模型层析反演多采用基于初至旅行时射线追踪的迭代反演方法。通常采用基于共享存储的MPI并行方式提高计算效率,但当计算节点增至一定规模时会存在网络I/O压力过大的计算瓶颈。为此,提出了一种快速、稳健的基于Spark技术的近地表速度模型层析反演方法,采用分布式内存管理技术将迭代中重复计算的数据持久化至内存中,提高程序运行效率。同时,为了解决共享存储中随着节点规模扩大而产生网络I/O堵塞的瓶颈问题,在分布式存储环境下组织弹性分布式数据集(RDD),设计基本规约单位为深度方向的一维反演数据,基于Spark Shuffle在规约过程中分布并行规约,利用Spark调度器在各个进程中分配任务,实现并行计算。实际数据计算结果表明:在反演结果精度不变的情况下,相对于常规MPI并行技术,该实现方法能够大幅度降低迭代过程中产生的网络I/O;当计算节点较多时,计算效率能够提高4倍以上;并行加速比呈现类线性增长趋势。  相似文献   
6.
《Ceramics International》2022,48(20):30393-30406
Plasma methods are efficient processing for metal recovery from metal scrap, bearing minerals, electronic waste, etc. In this work, pure titanium nitride nanoparticles (TiN NPs) were synthesized from titanium scraps by the thermal plasma arc discharge (TPAD) method. TPAD synthesized TiN NPs have a highly crystalline nature with cubic and spherical morphologies with average particle sizes of 30–100 nm. Further, prepared TiN NPs involving surface modification (SM) or etching processes were investigated by using the non-thermal DC glow discharge plasma technique with air atmosphere at different processing times. SM@TiN NPs have a comparatively low crystalline, which was confirmed from the powder X-ray diffraction technique. SM@TiN NPs have very interesting core shell morphologies, which are due to the surface interactions of ionized air molecules. TiN and SM@TiN NPs have room-temperature ferromagnetic properties with high saturation magnetization (Ms) up to 2.6 and 3.0 emu/g and very high coercivity (Hc) of 235.5 Oe, respectively. TiN and SM@TiN NPs have superior energy storage performance with an outstanding specific capacitance of 192.8 and 435.1 F/g at a current density of 2 A/g with pseudocapacitive behavior. These results reveal that TiN and SM@TiN NPs have highly promising electrodes for supercapacitor applications.  相似文献   
7.
Using spark plasma sintering (SPS), >98.5 % dense boron carbide (B4C) samples were made from commercially available and lab-synthesised powders made via a low temperature synthesis (LTS) process. The work showed that the LTS powder can be produced in batches of tens to hundreds of grams whilst maintaining a high purity material with lower levels of residual free carbon (20.6–21.3 wt.% C) than commercially available samples (22.4 wt.% C). The LTS material was seen to exhibit higher hardness values (37.8 GPa) than the commercial grade material (32.5 GPa) despite featuring a coarser average grain size (10.8 μm and 2.4 μm respectively). This is largely thought to be due to the influence of ZrO2 and AlB2 impurities introduced to the material during micronising milling of the powder after synthesis, as opposed to the influence of the materials lower carbon content.  相似文献   
8.
The plasma spray technique was well proven in producing metal oxide based gas sensors in the last two decades using different powder feedstocks. However, limited research was made to fabricate hydrogen gas sensor from tin oxide layer coated over tungsten oxide layer. This paper attempts to interpret the hydrogen gas sensing performances of plasma sprayed coating derived by depositing tin oxide layer over tungsten oxide (SnO2/WO3) layer. Plasma sprayed SnO2/WO3 sensor showed maximum response of 90% at 150 °C in contrast to stand-alone WO3 (89% at 350 °C) and stand-alone SnO2 (89% at 250 °C). The lower operating temperature of SnO2/WO3 sensor without compromising gas response was attributed to the WO3–SnO2 hetero-junction. SnO2/WO3 sensor showed selective sensing towards hydrogen with respect to carbon monoxide and methane gases. This sensor also possessed repeatable characteristics after 39 days from the initial measurement. In a nut-shell, plasma spayed SnO2/WO3 sensor showed stability of base resistance, repeatability after successive response and recovery cycles, selective sensing towards 500 ppm H2 with significant magnitude of gas response of 90%, response time of 35 s and recovery time of 269 s at a temperature of 150 °C.  相似文献   
9.
《Ceramics International》2022,48(20):29959-29966
High-purity SiC ceramic devices are applied in semiconductor industry owing to their outstanding properties. Nevertheless, it is difficult to densify SiC ceramics without any sintering additive even by HP sintering. In this work, high-purity and dense SiC ceramics were fabricated by HP sintering with very low amounts of sintering aids. Residual B content was only 556 ppm and relative density was more than 99.5%. Furthermore, thermal conductivity of as-prepared SiC ceramics was improved from 155 W m?1 K?1 to 167 W m?1 K?1 by increasing holding time and their plasma corrosion resistance was promoted in the meantime. The as-prepared high-purity SiC ceramics have broad application prospects in the field of semiconductor industry.  相似文献   
10.
《Ceramics International》2022,48(5):6322-6337
To optimize the corrosion, bioactivity, and biocompatibility behaviors of plasma electrolytic oxidation (PEO) coatings on titanium substrates, the effects of five process variables including frequency, current density, duty cycle, treatment time, and electrolyte Ca/P ratio were evaluated. In our systematic study, a Taguchi design of experimental based on an L16 orthogonal array was used. For this, the coatings characteristics such as the surface roughness, wettability, rutile to anatase and Ca/P ratios, and corrosion polarization resistance were investigated. After determining the optimum process variables for each response, the apatite forming ability in SBF (bioactivity behavior) and MG63 cell attachment and flattening (biocompatibility behavior) for two groups of coatings were examined. The first group was optimized based on the maximum corrosion polarization resistance and the variables were set as the frequency of 2000 Hz, the current density of 5 A/dm2, the duty cycle of 30%, the treatment time of 5 min, and the Ca/P ratio of 0.65 at. % in the electrolyte. For the second group, the maximum surface roughness, greatest Ca/P ratio, and highest wettability as well as the minimum rutile to anatase ratio in coatings, could be obtained when the variables were set as the frequency of 10 Hz, the current density of 12.5 A/dm2, the duty cycle of 50%, the treatment time of 12.5 min, and the Ca/P ratio of 1.70 at. % in the electrolyte. The results showed that while both groups of coatings indicated a significant apatite forming ability and can serve as bioactive coatings, a proper attachment and flattening of cells and consequently, the favorable biocompatibility properties were seen only in the first group.  相似文献   
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