首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   18948篇
  免费   1215篇
  国内免费   1060篇
电工技术   851篇
综合类   770篇
化学工业   4606篇
金属工艺   4519篇
机械仪表   857篇
建筑科学   390篇
矿业工程   517篇
能源动力   1041篇
轻工业   363篇
水利工程   81篇
石油天然气   357篇
武器工业   122篇
无线电   1133篇
一般工业技术   2686篇
冶金工业   1850篇
原子能技术   397篇
自动化技术   683篇
  2024年   20篇
  2023年   365篇
  2022年   518篇
  2021年   636篇
  2020年   718篇
  2019年   543篇
  2018年   466篇
  2017年   542篇
  2016年   502篇
  2015年   537篇
  2014年   814篇
  2013年   958篇
  2012年   1080篇
  2011年   1332篇
  2010年   1018篇
  2009年   1125篇
  2008年   963篇
  2007年   1178篇
  2006年   1140篇
  2005年   862篇
  2004年   744篇
  2003年   726篇
  2002年   752篇
  2001年   643篇
  2000年   566篇
  1999年   477篇
  1998年   358篇
  1997年   322篇
  1996年   244篇
  1995年   223篇
  1994年   169篇
  1993年   117篇
  1992年   112篇
  1991年   112篇
  1990年   131篇
  1989年   102篇
  1988年   31篇
  1987年   14篇
  1986年   11篇
  1985年   8篇
  1984年   8篇
  1983年   4篇
  1982年   7篇
  1981年   8篇
  1980年   3篇
  1978年   7篇
  1977年   1篇
  1976年   2篇
  1975年   4篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
The H2 storage properties of isoreticular metal-organic framework materials (IRMOFs), MOF-5 and IRMOF-10, impregnated with different numbers and types of heterogeneous C48B12 molecules were investigated using density functional theory and grand canonical Monte Carlo (GCMC) calculations. The excess hydrogen adsorption isotherms of IRMOFs at 77 K within 20 bar indicate that suitable number and type of C48B12 molecules play a crucial role in improving the H2 storage properties of IRMOFs. Among the studied pure and nC48B12 (n = 1, 2, 4, 8) in Ci symmetry impregnating into MOF-5, at 77 K under 6 bar, MOF-5-4C48B12 with a 3.5 wt% and 29.9 g/L hydrogen storage density, and at 77 K under 12 bar, the pure MOF-5 with a 4.9 wt% and 31.0 g/L hydrogen storage density has the best hydrogen storage properties. Whereas, among the studied pure and nC48B12 (n = 1, 2, 4, 8) in S6 symmetry impregnating into IRMOF-10, IRMOF-10-8C48B12 always shows the best hydrogen storage properties among the pure and C48B12-impregnated IRMOF-10 at 77 K within 20 bar. IRMOF-10-8C48B12 has a 6.0 wt% and 34.6 g/L hydrogen storage density at 77 K under 6 bar, and has a 7.1 wt% and 41.4 g/L hydrogen storage density at 77 K under 12 bar. The confinement effect of IRMOFs on C48B12 molecules, and steric hindrance effect of C48B12 molecules on IRMOFs mainly affects the H2 uptake capacity by comparing the absolute H2 molecules in individual IRMOFs units, C48B12 molecules, and IRMOFs-nC48B12 compounds. The absolute hydrogen adsorption profiles show that eight C48B12 molecules impregnating into MOF-5 can exert obvious steric effects for H2 adsorption. The saturated gravimetric and volumetric H2 densities of IRMOF-10-8C48B12 higher than those of MOF-5-8C48B12 due to with larger free volume.  相似文献   
2.
采用脉冲电流方法制备电镀镍层,并利用扫描电镜、光学轮廓仪、硬度计等测试方法研究了电镀参数中的溶液温度和pH对电镀镍层的表面形貌、粗糙度、显微硬度和SiC/Ni刻蚀选择比的影响。结果表明:当镀液温度在45~60℃时,镀镍层表面形貌变化不大,但是随着镀液温度的升高和镀液pH的增大,粗糙度呈先减小后增大的趋势,显微硬度和SiC/Ni刻蚀选择比均呈先增大后减小的趋势。电镀液温度为55℃,pH在4.0~4.4时,可获得具有良好的质量、显微硬度且SiC/Ni刻蚀选择比的镍镀层。  相似文献   
3.
To tackle the dissolution problem of boron carbide particles in silicon infiltration process, carbon-coated boron carbide particles were fabricated for the preparation of the reaction-bonded boron carbide composites. The carbon coating can effectively protect the boron carbide from reacting with liquid Si and their dissolution, thus maintaining the irregular shape of boron carbide particles and preventing the growth of boron carbide particles and reaction formed SiC regions. Furthermore, the nano-SiC particles, originated from the reaction of the carbon coating and the infiltrated Si, uniformly coated on the surfaces of boron carbide particles, thus forming a ceramic skeleton of the nano-SiC particles-coated and -bonded boron carbide particles. The Vickers hardness, flexural strength and fracture toughness of the composites can be increased by 26 %, 45 %, and 37 % respectively, by using carbon-coated boron carbide particles as raw materials.  相似文献   
4.
搭建了鼓泡床碳酸化反应器,研究常温常压下电石渣直接液相碳酸化矿化封存CO2的能力,揭示了重要操作参数表观气速、液固比和CO2浓度对电石渣矿化封存CO2能力和碳酸化效率的影响规律。同时构建响应面模型,分析各参数对电石渣碳酸化效率的影响强度,优化获得最大碳酸化效率及相应操作工况。结果表明,增加气速有利于钙离子溶解和CO2吸收,但反应器中过高气速易导致气相通道效应,不利于气液充分接触。当液固比降低,溶液中钙离子浓度提高,更有利于碳酸化反应,但液固比过低会影响固液间传质。适当增加CO2浓度有利于提高碳酸化效率,但CO2浓度增至到一定值后,对碳酸化效率影响降低。响应面建模分析发现,各因素对碳酸化效率影响顺序为:液固比>CO2浓度>表观气速。优化结果发现碳酸化效率最高为93.58%,工况为表观气速0.07m/s,液固比为8.26mL/g和CO2体积分数为20.91%。研究可知,鼓泡床中常温常压下电石渣直接液相加速碳酸化反应,具有较大的CO2固定量和高的碳酸化效率,实验结果为电石渣加速矿化封存CO2技术的发展提供了基础数据。  相似文献   
5.
根据涠洲10-3单点的结构特点,提出对其采用整体拆除的拆除思路。针对该单点整体吊装需求,借鉴钢桩吊装方案创新性地设计吊桩器吊装方案,借鉴隔水套管吊装方案创新性地设计套筒镗孔吊装方案。此外,还分别开展调平吊耳吊装方案、盲板吊装方案和吊耳吊装方案等3种吊装方案设计。通过对上述5种吊装方案的技术可行性分析,在综合考虑项目多方面因素后,涠洲10-3单点拆除项目最终选用吊耳吊装方案。在吊耳吊装方案应用实例中,分析吊点板式吊耳安装在套筒外侧的原因,论述所选用的吊点板式吊耳结构形式及其采用环形筋板的优点,并通过对该单点整体吊装强度的有限元分析,证明选用吊耳吊装方案设计的可行性。  相似文献   
6.
一步骤胶结充填体为二步骤矿柱回采提供支撑,充填体由三轴受力转为单轴受力状态,其稳定性对采场安全至关重要。为此对比分析了单次(单轴)和二次(三轴加单轴)压缩对不同灰砂比胶结充填体的应力-应变曲线、强度特征、能耗特征及破坏模式。结果表明:单次比二次具有更明显压密阶段、更高线弹性阶段,增大围压使二次充填体压密阶段减小、线弹性阶段和屈服阶段延长、弹模增大;灰砂比1∶12直接进入线弹性变形阶段,但低围压各阶段水平大于高围压。1∶12峰值强度随围压增大而下降、1∶8先增后降、1∶4峰值强度与围压呈正相关,1∶8存在强度最优值;1∶4和1∶12两次充填体受围压影响较小,强度占比在26.05%~58.79%,1∶8则高达89.92%和93.51%。二次压缩和灰砂比降低造成充填体能量值下降,增大围压使峰前总能量占比上升、峰前应变能缓慢增加;1∶4和1∶8增大围压提高峰前储能极限,1∶12则先降后增。试样裂纹表现为平行和竖直,二次压缩使充填体破碎程度提高,增大围压维持完整性,试样二次压缩破坏路径沿首次路径发生,破坏位置发生在上部。  相似文献   
7.
Compositional analysis of boron carbide on nanometer length scales to examine or interpret atomic mechanisms, for example, solid-state amorphization or grain-boundary segregation, is challenging. This work reviews advancements in high-resolution microanalysis to characterize multiple generations of boron carbide. First, ζ-factor microanalysis will be introduced as a powerful (scanning) transmission electron microscopy ((S)TEM) analytical framework to accurately characterize boron carbide. Three case studies involving the application of ζ-factor microanalysis will then be presented: (1) accurate stoichiometry determination of B-doped boron carbide using ζ-factor microanalysis and electron energy loss spectroscopy, (2) normalized quantification of silicon grain-boundary segregation in Si-doped boron carbide, and (3) calibration of a scanning electron microscope X-ray energy-dispersive spectroscopy (XEDS) system to measure compositional homogeneity differences of B/Si-doped arc-melted boron carbides in the as-melted and annealed conditions. Overall, the improvement and application of advanced analytical tools have helped better understand processing–microstructure–property relationships and successfully manufacture high-performance ceramics.  相似文献   
8.
Using spark plasma sintering (SPS), >98.5 % dense boron carbide (B4C) samples were made from commercially available and lab-synthesised powders made via a low temperature synthesis (LTS) process. The work showed that the LTS powder can be produced in batches of tens to hundreds of grams whilst maintaining a high purity material with lower levels of residual free carbon (20.6–21.3 wt.% C) than commercially available samples (22.4 wt.% C). The LTS material was seen to exhibit higher hardness values (37.8 GPa) than the commercial grade material (32.5 GPa) despite featuring a coarser average grain size (10.8 μm and 2.4 μm respectively). This is largely thought to be due to the influence of ZrO2 and AlB2 impurities introduced to the material during micronising milling of the powder after synthesis, as opposed to the influence of the materials lower carbon content.  相似文献   
9.
In this study, silicon carbide (SiC) composites reinforced with pitch-based carbon fibers and composed of heat transfer channels were fabricated by combining chemical vapor infiltration and reactive melting infiltration method. It was observed that the internal heat conduction skeleton of pitch-based carbon fibers was sequentially formed. The thermal conductivities from room temperature to 500 °C along through-thickness direction and in-plane direction were investigated. The results showed that Cpf/SiC composites with heat transfer channels possessed excellent thermal conductvity in two directions, and the thermal conductivity increased with increasing volume content of heat transfer channels. The thermal conductivity in through-thickness direction reached 38.89 W/(m·K), and that for in-plane direction reached 112.42 W/(m·K). Theoretical calculations were empolyed to study the temperature dependence of the Cpf/SiC composites. The variations in slope A′ and intercept B′ values of fitted curves were in good agreement with the experimental results. To verify the reliablilty of the theoretical model, the Cpf/SiC composites were heated at 1650 °C for 2 h and the thermal conductivity exhibited further improvement due to the formation of more perfect crystalline structure. Thermal conductivity through thickness direction improved to 43.49 W/(m·K), and that in in-plane direction improved to 142.49 W/(m·K), which could be identified by the theoretical model. Finally, the leading edge model was established by using ABAQUS finite element analysis software to evaluate the potential application of the composites. Owing to the outstanding thermal conductivity, the leading edge obtained by using Cpf/SiC composites in this study exhibited lower temperature gradient and a more uniform temperature distribution. Moreover, less thermal stress and displacement were generated during heating process.  相似文献   
10.
为提高煤炭开采、洗选和煤化工的煤机装备耐冲蚀性能,利用雾化造粒和激光熔覆技术制备高WC含量Ni/WC复合熔覆层,通过组织观察、力学性能检测、腐蚀及磨损实验对比研究了雾化造粒和激光熔覆过程中Ni/WC复合熔覆层的组织、结构演变,并基于射流式冲蚀分析了材料的冲蚀行为。结果表明:喷雾干燥Ni/WC团聚复合粉末的球形度与粘结剂含量成正比,而粒径则与雾化器转速成反比。激光熔覆后,Ni/WC熔覆层由Ni、WC和W2C相组成。其中,在熔覆过程中WC出现了熔解与析出变化,形成了层状共晶→棒状、针状→块状结构的富W和富Ni相。在冲蚀磨损工况下,WC有效改善了Ni/WC熔覆层冲刷磨损性能,磨损率为0.097 g/(m2·h),相比Q235A钢降低约23%。此时,细小的WC均匀镶嵌在磨损表面的粘结相中起到强化作用。同时,Ni/WC熔覆层的剥落处表现出明显的塑性特征,为典型的韧性破坏。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号