首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9996篇
  免费   601篇
  国内免费   326篇
电工技术   296篇
综合类   559篇
化学工业   4812篇
金属工艺   679篇
机械仪表   177篇
建筑科学   251篇
矿业工程   387篇
能源动力   318篇
轻工业   711篇
水利工程   33篇
石油天然气   136篇
武器工业   5篇
无线电   339篇
一般工业技术   1521篇
冶金工业   523篇
原子能技术   78篇
自动化技术   98篇
  2024年   21篇
  2023年   139篇
  2022年   210篇
  2021年   291篇
  2020年   233篇
  2019年   208篇
  2018年   201篇
  2017年   374篇
  2016年   336篇
  2015年   291篇
  2014年   439篇
  2013年   515篇
  2012年   659篇
  2011年   857篇
  2010年   601篇
  2009年   574篇
  2008年   490篇
  2007年   648篇
  2006年   535篇
  2005年   433篇
  2004年   440篇
  2003年   352篇
  2002年   333篇
  2001年   238篇
  2000年   258篇
  1999年   245篇
  1998年   159篇
  1997年   121篇
  1996年   113篇
  1995年   119篇
  1994年   91篇
  1993年   71篇
  1992年   79篇
  1991年   55篇
  1990年   47篇
  1989年   22篇
  1988年   27篇
  1987年   24篇
  1986年   21篇
  1985年   14篇
  1984年   8篇
  1983年   9篇
  1982年   7篇
  1981年   6篇
  1980年   4篇
  1978年   1篇
  1977年   2篇
  1976年   1篇
  1951年   1篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Aluminum-doped zinc oxide (ZnO:Al, AZO) electrodes were covered with very thin (∼6 nm) Zn1−xMgxO:Al (AMZO) layers grown by atomic layer deposition. They were tested as hole blocking/electron injecting contacts to organic semiconductors. Depending on the ALD growth conditions, the magnesium content at the film surface varied from x = 0 to x = 0.6. Magnesium was present only at the ZnO:Al surface and subsurface regions and did not diffuse into deeper parts of the layer. The work function of the AZO/AMZO (x = 0.3) film was 3.4 eV (based on the ultraviolet photoelectron spectroscopy). To investigate carrier injection properties of such contacts, single layer organic structures with either pentacene or 2,4-bis[4-(N,N-diisobutylamino)-2,6-dihydroxyphenyl] squaraine layers were prepared. Deposition of the AMZO layers with x = 0.3 resulted in a decrease of the reverse currents by 1–2 orders of magnitude and an improvement of the diode rectification. The AMZO layer improved hole blocking/electron injecting properties of the AZO electrodes. The analysis of the current-voltage characteristics by a differential approach revealed a richer injection and recombination mechanisms in the structures containing the additional AMZO layer. Among those mechanisms, monomolecular, bimolecular and superhigh injection were identified.  相似文献   
2.
Undoped and fluorine doped ZnO thin films were deposited onto glass substrates using successive ionic layer adsorption and reaction (SILAR) technique and then annealed at 350 °C in vacuum ambience. The F doping level was varied from 0 to 15 at% in steps of 5 at%. The XRD analysis showed that all the films are polycrystalline with hexagonal wurtzite structure and preferentially oriented along the (002) plane. Crystallite sizes were found to increase when 5 at% of F is doped and then decreased with further doping. It was seen from the SEM images that the doping causes remarkable changes in the surface morphology and the annealing treatment results in well-defined grains with an improvement in the grain size irrespective of doping level. All the films exhibit good transparency (>70%) after vacuum annealing. Electrical resistivity of the film was found to be minimum (1.32×10−3 Ω cm) when the fluorine doping level was 5 at%.  相似文献   
3.
4.
测算了由二(2-乙基己基)磷酸钠,金属盐(CoSO4,NiSO4,ZnSO4,MgCl2或Cr(NO3)3)水溶液,正辛醇和正辛烷组成的微乳液中正辛醇从连续油相到界面的ΔGo→i^o和水的极限增容量φ'H2O。用金属萃取络合物反胶束的形成及其亲油性解释了金属离子对φ'H2O和ΔGo→i^o的影响。  相似文献   
5.
JFC磷酸酯的合成和应用   总被引:2,自引:0,他引:2  
杨俊玲 《染整技术》2002,24(4):35-36
详述了JFC磷酸酯的合成工艺路线,以及它在织物前处理精练工艺中的应用。与其它磷酸酯类精练剂性能对比,证明它可作为一种性能优良的精练剂中的添加剂。  相似文献   
6.
简述国内磷酸二铵的建设情况及不同的生产工艺、原有磷酸二铵装置改造选用的工艺及生产情况 ,重点介绍 Incro工艺在云南红河州磷肥厂年产 12万吨磷铵装置中的改造情况 ,经过比较认为原采用预中和槽流程磷酸二铵装置增产改造时选用 Incro工艺比较合适  相似文献   
7.
Atmospheric corrosion of reference metals in Antarctic sites   总被引:1,自引:0,他引:1  
This paper presents the results obtained at three Antarctic test sites participating in the “Ibero-American Map of Atmospheric Corrosiveness” (MICAT), a project on atmospheric corrosion carried out during the period 1988–1994 at some 70 sites distributed across 12 countries of the Latin-American region, Spain and Portugal. The three Antarctic sites are located near the coastline.The singular climatic characteristics of Antarctic regions are related with the purity of the air, the absence of rainfall and the formation of ice on the metallic surface during an important part of the exposure time. However, electrochemical activity is possible below ice layers. This situation affects the structure and morphology of corrosion product films and the resulting corrosion rates of metallic surfaces.  相似文献   
8.
1Introduction Reconstructivesurgeryisoneofthehottestre searchedsubjectsthatdealingwithbonedefects.Thetra ditionalmethodisimplantationoffreshautograftbonebe causeofitsnon immunoreactiveproperty.Butautologousbonewasnotabundantinsomecases.Sowefoundbeta trica…  相似文献   
9.
锌电积的节电探讨   总被引:1,自引:0,他引:1  
分析厂影响锌电积电能消耗的因素,提出了锌电积的节电对策与展望。  相似文献   
10.
A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO4-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P2O5-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO4-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO4-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn3(PO4)2 · 4H2O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO4-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号