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1.
化学镀非晶态Ni—B合金的研究 总被引:1,自引:0,他引:1
本文通过化学镀方法在铜和钢上沉积非晶态Ni-B合金。着重讨论了还原剂浓度、络合剂浓度对化学镀沉积速率的影响;分析了它的耐蚀原因和其显微硬度随退火温度的变化情况并就其应用和发展略作说明。 相似文献
2.
Hitoshi Kurokawa Taku Nakayama Yasunori Kobayashi Ken Suzuki Mutsumi Takahashi Seiichi Takami Momoji Kubo Naotsugu Itoh Parasuraman Selvam Akira Miyamoto 《Catalysis Today》2003,82(1-4):233-240
A modified Monte Carlo (MC) simulation was performed to investigate the hydrogen absorption behavior in Pd and Pd–Ag alloys of the composition PdxAg1−x (x=0.7–0.8) under H2 pressure (0.1 MPa) at different temperatures. The present method employed can consider the dissociative adsorption of hydrogen molecule and the subsequent absorption of hydrogen atom by formalizing the relationship between the pressure of hydrogen molecule and hydrogen atom. The potential parameters were determined to reproduce the solution enthalpy of hydrogen in pure metals. The results are in good agreement with experimental findings as well as previous theoretical studies. We confirmed that our method is useful to simulate the absorption of hydrogen in metals and alloys. 相似文献
3.
4.
The influence of NaCl and CO2 on the atmospheric corrosion of magnesium alloy AZ91 is studied in the laboratory. Samples were exposed under carefully controlled air and flow conditions; the relative humidity was 95%, the temperature was 22.0°C and the concentration of CO2 was < 1 ppm or 350 ppm. Different amounts of sodium chloride (0–70 μg/cm2) were added before exposure. The corrosion products were analyzed by gravimetry, ion chromatography, X‐ray diffraction and scanning electron microscopy. Mass gain and metal loss results are reported. The combination of high humidity and NaCl is very corrosive towards AZ91. However, the NaCl‐induced corrosion is inhibited by ambient concentrations of CO2. Exposure in the absence of CO2 gives rise to heavy pitting, with brucite, Mg(OH)2, being the dominant corrosion product. In the presence of CO2 a layer of hydrated magnesium hydroxy carbonate, Mg5(CO3)4(OH)2 · 5 H2O forms. A tentative corrosion mechanism is presented that explains the behavior in the two environments. 相似文献
5.
Dental amalgams are based on a broad spectrum of materials differing in their chemical composition, metallurgical treatment, and in the way the initial alloys powders are prepared. In addition to their chemical composition, amalgams based on various powders differ in both their microstructure and the amount of mercury needed for preparation. All these facts may affect electrochemical processes occurring during their interaction with oral fluids, and also mercury release. While verifying the effect of the technology used for the preparation of the high‐copper ternary alloy powder on the properties of resulting amalgams, this study aimed at the mechanism of their interaction with a model saliva solution as well as mercury release was included. Measurements were done in a model saliva solution using standard electrochemical methods and exposition measurements. The interaction of individual types of amalgams with artificial saliva did not reveal any significant differences. The free corrosion potential of all these amalgams in an aerated solution settled in the range of values in which tin oxidation, resulting in a layer of insoluble corrosion producsts, turned out to be the dominant anodic process. The rate of mercury release was the lowest for amalgams based on a gas‐atomized alloy. The highest rate of mercury release, and also its dependence on time, was exhibited by lathe‐cut powder based amalgam. In addition to different volume fraction of the Ag‐Hg phase and the level of its tin alloying, this different behaviour may be explained by differences in the rate at which a layer of tin corrosion products acting as a barrier to mercury release is formed. 相似文献
6.
J. D. Parry J. M. Winterbottom 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1991,50(1):67-80
Silica-supported Ni-Ag catalysts with a loading of 2·1·0.6% (w/w) total metal have been prepared using the precursors nickel dimethylglyoxime and silver nitrate by means of a simple impregnation method. The resulting catalysts were activated by calcination at 260°C in air, followed by hydrogen reduction at 450°C. They were then employed for soyabean oil hydrogenation at 1 bar H2 pressure and 160°C in a stirred batch reactor. Characterisation of the catalysts using temperature-programmed reduction and electron microscopy indicated that alloying of nickel and silver had occurred, but metal particle composition, for a given overall composition, varied with metal particle size and smaller metal particles were nickel rich. The hydrogenation activity and selectivity measurements revealed that the catalysts were more active and selective than a commercial nickel catalyst. Furthermore, the specific activities of the alloy catalysts were a maximum for alloys in the range 70–90 at. % Ni. However, the supported alloy catalysts also gave rise to greater trans isomerisation than the commercial catalyst. This is attributed to hydrogen deficiency caused by large triglyceride molecules blocking hydrogen chemisorption on small nickel particles (10–50 Å in diameter), leading to enhanced cis-trans isomerisation. 相似文献
7.
化学镀Ni—P镀层的X射线衍射研究 总被引:2,自引:0,他引:2
根据X射线衍射分析结果,对化学镀高P(含P>11wt%或19at%)Ni-P镀层加热时效时,镀层成分和加热温度对结构转变的影响作了研究,结果表明,高P共晶、过共晶(含P>11wt%或19at%)合金的结构转变有如下特征:(1)相同加热时效条件下,Ni-P合金的结构转变与成分有密切关系:(2)对同一成分的过共晶合金,Ni-P合金的结构转变与时效温度密切相关;(3)过共晶合金在290~360℃温度范围内时效处理,出现Ni_xP_y介稳相,X射线衍射分析认为Ni_xP_y为Ni_(12)P_5。 相似文献
8.
PC/ABS合金的研制及其在汽车上的应用 总被引:6,自引:0,他引:6
对PC/ABS合金开发和研制及其在汽车上的应用作了评述。介绍了上海杰事公司在该领域的进展。 相似文献
9.
Carlson Steadman Dancila & Kardomateas 《Fatigue & Fracture of Engineering Materials & Structures》1998,21(4):403-409
Results of an experimental investigation of the fatigue growth of small corner cracks emanating from small flaws are presented. Growth-arrest behaviour was observed, and increases in crack length during growth periods were of the order of the transverse grain size. For the test material, the corner crack front intersects, on average, only three–six grains in the small crack regime monitored, so only a small number of constrained, interior grains is encountered. It is suggested that the presence of partially constrained surface grains may contribute to the 'anomalous' growth behaviour which has been observed by a number of investigators.
The crack growth histories of the test data presented exhibit considerable scatter. It is shown that a Student's t -test can be used to estimate confidence intervals in order to provide a measure of the observed scatter. The variation in confidence intervals in the transition from small to long fatigue crack growth is discussed. 相似文献
The crack growth histories of the test data presented exhibit considerable scatter. It is shown that a Student's t -test can be used to estimate confidence intervals in order to provide a measure of the observed scatter. The variation in confidence intervals in the transition from small to long fatigue crack growth is discussed. 相似文献
10.
介绍铝及铝合金阳极氧化膜颜色的概念和描写,对颜色的儿种测量方法进行了比较,重点分析观察法及其在各国标准中的异同。在此基础上,提出了GB8013中的对颜色进行观察的条件和理论根据。 相似文献