全文获取类型
收费全文 | 4292篇 |
免费 | 384篇 |
国内免费 | 198篇 |
专业分类
电工技术 | 663篇 |
综合类 | 236篇 |
化学工业 | 759篇 |
金属工艺 | 548篇 |
机械仪表 | 86篇 |
建筑科学 | 67篇 |
矿业工程 | 140篇 |
能源动力 | 412篇 |
轻工业 | 44篇 |
水利工程 | 12篇 |
石油天然气 | 61篇 |
武器工业 | 19篇 |
无线电 | 530篇 |
一般工业技术 | 773篇 |
冶金工业 | 359篇 |
原子能技术 | 86篇 |
自动化技术 | 79篇 |
出版年
2024年 | 9篇 |
2023年 | 123篇 |
2022年 | 140篇 |
2021年 | 156篇 |
2020年 | 191篇 |
2019年 | 164篇 |
2018年 | 101篇 |
2017年 | 132篇 |
2016年 | 147篇 |
2015年 | 126篇 |
2014年 | 223篇 |
2013年 | 201篇 |
2012年 | 294篇 |
2011年 | 317篇 |
2010年 | 278篇 |
2009年 | 249篇 |
2008年 | 206篇 |
2007年 | 298篇 |
2006年 | 245篇 |
2005年 | 249篇 |
2004年 | 215篇 |
2003年 | 172篇 |
2002年 | 133篇 |
2001年 | 96篇 |
2000年 | 94篇 |
1999年 | 59篇 |
1998年 | 45篇 |
1997年 | 41篇 |
1996年 | 27篇 |
1995年 | 21篇 |
1994年 | 26篇 |
1993年 | 25篇 |
1992年 | 20篇 |
1991年 | 6篇 |
1990年 | 7篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1978年 | 1篇 |
1951年 | 3篇 |
排序方式: 共有4874条查询结果,搜索用时 62 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(64):27680-27689
The low performance of open-cathode proton-exchange-membrane fuel cells (OCPEMFCs) is attributed to the low-humidity ambient air supplied to the cathode using electric fans. To improve the OCPEMFC performance, this paper proposes a novel humidification method by collecting water purged from the anode and supplying it to the open cathode. The OCPEMFC performance is evaluated at various humidifier distances from the cathode inlet, and it is compared with that where no humidifier is used when the OCPEMFC operates under three different current levels of 1, 5, and 8 A. The results show that the novel design improves the stack power, and optimal performance is achieved at a humidifier distance of 2 cm. The energy efficiency achieves an improvement between 1.4% and 1.8% when a humidifier is used. 相似文献
2.
《Ceramics International》2022,48(7):9124-9133
The main obstacles in lithium-ion battery are limited by rate performance and the rapid capacity fading of LiNi0.8Co0.1Mn0.1O2 (NCM811). Herein, a novel three-dimensional (3D) hierarchical coating material has been fabricated by in situ growing carbon nanotubes (CNTs) on the surfaces of Ni–Al double oxide (Ni–Al-LDO) sheets (named as LDO&CNT) with Ni–Al double hydroxide (Ni–Al-LDH) as both the substrate and catalyst precursor. The resultant LDO&CNT nanocomposites are uniformly coated on the surfaces of NCM811 by the physical mixing method. The rate capability of the resultant cathode material retains to 78.80% at a current rate of 3C. Its capacity retention increases by 6.7–14.42% compared with pristine NCM811 after 100 cycles within a potential range of 2.75–4.3 V at 0.5C. The improved rate capability and cycle performance of NCM811 are assigned to the synergistic effects between Ni–Al-LDO and CNTs. The hierarchical LDO&CNT nanocomposites coating on the surface of NCM811 avoids the aggregation of conductive CNTs and the stacking of Ni–Al-LDO nanosheets. Furthermore, it accelerates Li+ and electrons shuttle and reduces the reaction of Li2O with H2O and CO2 in air, which results in Li2CO3 and LiOH alkali formation on the NCM811 surface. 相似文献
3.
4.
《Ceramics International》2022,48(14):20220-20227
A specially designed experimental device was used in laboratory to investigate the corrosion of mullite during the calcination of Li(NixCoyMnz)O2 (LNCM) materials. The anti-corrosion tests were carried out at 1000, 1100, 1200 and 1300 °C, and characterized with X-ray diffraction and scanning electron microscopy. The influence of temperature on the interactions between mullite insulation materials and LNCM materials was determined. In addition, the high-temperature creep properties of the mullite insulation materials before and after corrosion were tested. The laboratory scale tests, thermodynamic and kinetic calculations allowed a more comprehensive understanding of the evolution of the mullite insulation materials during serving for the roasting process of LNCM materials. Through this research, it is suggested that the upgrading of the kiln lining in the lithium battery industry should select materials with excellent resistance to alkali corrosion, especially excellent resistance to Li+ corrosion. 相似文献
5.
建立并优化一种基于高效薄层色谱和表面增强拉曼联用检测技术的方法,用于快速准确定性定量检测葡萄汁中的苏丹染料掺伪。使用石油醚/丙酮/乙酸(9/1/0.1,体积比)作为流动相在硅胶板上对目标物进行色谱分离,考察纳米银胶体浓度、外加电解质种类、浓度以及入射激光波长等参数对检测信号质量的影响。结果表明,10倍浓缩的纳米银胶体,633nm入射激光,辅以0.5~1.0mol/L NaCl最适合4种目标物的检测。优化检测条件后,检测灵敏度可达0.01~0.05mg/kg;在1~20 mg/kg浓度范围内,检测结果表现出良好的线性关系,R~20.996。不仅如此,对葡萄汁样品的测试中,该方法也表现出良好的准确性(添加回收率72%~104%)和精密度(RSD 4.5%~9.6%),因此特别适于大批量饮料和食品样品中非法色素添加的筛检。 相似文献
6.
 为探究双金属复合管Inconel625合金堆焊层表面局部出现黑斑的原因,通过对试样进行理化性能分析,结合堆焊工艺,对黑斑位置与正常位置进行了对比研究。结果表明,与正常位置相比,黑斑位置的基管Fe元素向堆焊层扩散程度加大,局部形成元素偏析,故堆焊层表面黑斑可能与较高热输入量下的高稀释率有关。另经检测分析,黑斑位置的化学成分、金相组织、弯曲性能、硬度、耐蚀性能均符合API 5LD—2015标准要求,但黑斑位置的晶间腐蚀与点腐蚀速率均高于正常位置,故黑斑现象对合金堆焊层的耐腐蚀性能存在不利影响。 相似文献
7.
Ali Sayir Marie-Hélène Berger Tyson C. Back Jonathan Mackey 《Journal of the American Ceramic Society》2021,104(11):5750-5763
Electron emission characteristic, electrical conductivity of polycrystalline mayenite (12CaO·7Al2O3) electride, formation of [Ca24Al28O64]4+(e−)4 framework as a function of phase content, and microstructure have been investigated. The mayenite microstructure was investigated using high-resolution transmission microscopy which revealed the type cage structure of 12CaO·7Al2O3 partially filled by extra-framework oxygen ions. Incorporation of electrons by means of carbon ion template 12CaO·7Al2O3 produces complex structure, and an incomplete ion template 12CaO·7Al2O3 structure consisting of mixture of a [Ca24Al28O64]4+(e−)4 and [Ca24Al28O64]4+(O2−)2 framework had a direct effect on the electron emission. Surface chemistry and stability of the 12CaO·7Al2O3 electride have been studied using x-ray photoelectron spectroscopy. The work function of phase pure 12CaO·7Al2O3 electride was determined from direct thermionic emission data and compared to the measurement from ultraviolet photoelectron spectroscopy (UPS). Depending on the extent of ion template of 12CaO·7Al2O3 structure, a work function of 0.9–1.2 eV and 2.1–2.4 eV has been measured and thermionic emission initiating at 600°C. 相似文献
8.
《Ceramics International》2022,48(16):23341-23347
In recent years, the rapid development of Li(NixCoyMn1-x-y)O2 (LNCM) materials for application in ternary lithium-ion batteries has led to an increased demand for refractory kiln saggars in industries. However, saggars used for firing ternary Li-ion battery cathode materials are often subjected to severe corrosion and spalling. To investigate the damage mechanism of the saggar materials, non-contact corrosion experiments were designed to study the effects of the precursor additions, calcination temperature, and number of calcinations during the interaction between mullite saggar and LNCM materials. The phase composition and microstructure of the mullite saggar specimens before and after corrosion were characterized using X-ray diffraction and scanning electron microscopy, respectively, to obtain a comprehensive understanding of the causes of the deterioration of mullite saggar materials during corrosion. 相似文献
9.
10.
Dispersion of nanocrystalline (94–350 nm) Ce0.9Gd0.1O2-δ in superfine (260–312 nm) Sm1.5Sr0.5NiO4+δ using modified precipitation technique is established using X-ray powder diffraction, scanning electron microscopy and transmission electron microscopy. Presence of Ce0.9Gd0.1O2-δ grains inhibits grain growth of Sm1.5Sr0.5NiO4+δ, which provides morphological stability (up to 1100 °C). Ce0.9Gd0.1O2-δ concentration dependent behaviours of ionic conductivity, surface exchange rate and electrode polarization resistance (Rp) of composites (determined using electrochemical impedance spectroscopy) are comprehended using percolation model. Three oxygen reduction reaction mechanisms are considered to understand electrochemical performance. Minimum Rp (0.81 Ω cm2 at 700 °C) for 70Sm1.5Sr0.5NiO4+δ:30Ce0.9Gd0.1O2-δ is correlated to percolation threshold (optimum (i) electrochemically active sites (ii) oxygen reduction reaction kinetics, (iii) O2- conductivity and (iv) charge transfer rate). Nano crystallite size of Ce0.9Gd0.1O2-δ is crucial for enhancement in electrochemical performance. Oxygen partial pressure dependent electrochemical impedance spectroscopy studies reveal dominance of coexisting non-charge transfer oxygen adsorption/desorption and bulk O2- diffusion. 相似文献