首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   60919篇
  免费   6296篇
  国内免费   3984篇
电工技术   3904篇
技术理论   11篇
综合类   7300篇
化学工业   7763篇
金属工艺   2015篇
机械仪表   3089篇
建筑科学   4885篇
矿业工程   1891篇
能源动力   2199篇
轻工业   4447篇
水利工程   1639篇
石油天然气   2157篇
武器工业   872篇
无线电   5301篇
一般工业技术   7719篇
冶金工业   3019篇
原子能技术   895篇
自动化技术   12093篇
  2024年   52篇
  2023年   1130篇
  2022年   1495篇
  2021年   1972篇
  2020年   2157篇
  2019年   1849篇
  2018年   1813篇
  2017年   2043篇
  2016年   2147篇
  2015年   2164篇
  2014年   3321篇
  2013年   4118篇
  2012年   3920篇
  2011年   4525篇
  2010年   3432篇
  2009年   3528篇
  2008年   3653篇
  2007年   4085篇
  2006年   3660篇
  2005年   3192篇
  2004年   2651篇
  2003年   2242篇
  2002年   1828篇
  2001年   1519篇
  2000年   1236篇
  1999年   1105篇
  1998年   840篇
  1997年   755篇
  1996年   686篇
  1995年   642篇
  1994年   544篇
  1993年   437篇
  1992年   385篇
  1991年   300篇
  1990年   259篇
  1989年   260篇
  1988年   198篇
  1987年   106篇
  1986年   131篇
  1985年   106篇
  1984年   100篇
  1983年   76篇
  1982年   74篇
  1981年   48篇
  1980年   44篇
  1979年   43篇
  1978年   33篇
  1977年   30篇
  1964年   28篇
  1955年   35篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
简述了矿用蓄电池机车控制器的发展历程以及机车逆变器的工作原理,分析现有机车逆变器所存在的电磁干扰、参数显示及机车司控室空间占用问题。针对以上问题进行了优化设计,改进了逆变器的电磁兼容性,改善了机车运行参数显示结构,集成了甲烷断电仪主机功能。通过对比分析可知,优化设计可有效减轻或抑制设备谐波干扰,增加了设备运行的稳定性,提高了现场安全操作性。  相似文献   
2.
In a narrow channel, the apparent relative viscosity of a suspension with finite-size particles is strongly dependent on its microscopic particle arrangement. Relative viscosity increases when suspended particles flow near the channel wall; thus, a suspension in a narrow channel does not always exhibit the same rheological properties even if the concentration is the same. In this study, we focus on the inertia and concentration of particles in a narrow channel and consider their effects on the microscopic particle arrangement and macroscopic suspension rheology. Two-dimensional pressure-driven suspension flow simulations were performed using a two-way coupling scheme, and normalized particle density distribution (PDD) were implemented to consider their particle arrangements. The results demonstrated that the velocity profiles for the particle suspension were changed by the Reynolds number and particle concentration because of the interactions between particles according to the power-law index. These changes affected the particle equilibrium positions in the channel, and the subsequent changes in solvent layer thickness caused changes in the macroscopic apparent viscosity. The behavior of microscopic particles played important roles in determining macroscopic rheology. Thus, we have confirmed that a normalized PDD can be used to estimate and assess the macroscopic rheology of a suspension.  相似文献   
3.
The ohmic resistance in solid oxide fuel cells (SOFCs) mainly comes from the electrolyte, which can be reduced by developing novel electrolyte materials with higher ionic conductivity and/or fabricating thin-film electrolytes. Among various kinds of thin-film fabrication technology, the physical vapor deposition (PVD) method can reduce the electrolyte thickness to a few micrometers and mitigate the issues associated with high-temperature sintering, which is necessary for wet ceramic methods. This review summarizes recent development progress in thin-film electrolytes fabricated by the PVD method, especially pulsed laser deposition (PLD) and magnetron sputtering. At first, the importance of the substrate surface morphology for the quality of the film is emphasized. After that, the fabrication of thin-film doped-zirconia and doped-ceria electrolytes is presented, then we provide a brief summary of the works on other types of electrolytes prepared by PVD. Finally, we have come to the summary and made perspectives.  相似文献   
4.
Electrolysis of water for producing hydrogen instead of traditional fossil fuels is one of the most promising methods to alleviate environmental pollution and energy crisis. In this work, Fe and F ion co-doped Ni3S2 nanoarrays grown on Ni foam substrate were prepared by typical hydrothermal and sulfuration processes for the first time. Density functional theory (DFT) calculation demonstrate that the adsorption energy of the material to water is greatly enhanced due to the doping of F and Fe, which is conducive to the formation of intermediate species and the improvement of electrochemical performance of the electrode. The adsorption energy of anions (F and S) and cations (Fe and Ni) to water in each material was also calculated, and the results showed that F ion showed the most optimal adsorption energy of water, which proved that the doping of F and Fe was beneficial to improve the electrochemical performance of the electrode. It is worth noting that the surface of Fe–F–Ni3S2 material will undergo reconstruction during the process of water oxidation reaction and urea oxidation reaction, and amorphous oxides or hydroxides in situ would be formed on the surface of electrode, which are the real active species.  相似文献   
5.
采用2mT低磁场(low magnetic field,LMF)冷冻、0mT磁场(no magnetic field,NMF)冷冻和常规冷冻(conventional freezing,CF)技术对3 组鲢鱼肌原纤维蛋白进行为期28 d的冷冻实验。通过表面疏水性、巯基含量、溶解度、浊度、热稳定性、傅里叶变换红外光谱、内源性荧光光谱和紫外吸收光谱各项指标考察蛋白的结构和功能性质变化。结果表明:施加低磁场冷冻可以抑制蛋白聚集和内部疏水基团的暴露,且能抑制α-螺旋的展开,减弱α-螺旋向β-折叠转变的能力,并维持良好的二、三级结构稳定性;CF组的蛋白总巯基含量、溶解度和浊度与NMF组相比无显著差异,由于冷冻温度较低,对蛋白聚集和内部疏水基团的暴露有一定的抑制作用,同时也使得蛋白结构变得松散不稳定;与CF组相比,LMF组同样显示出对蛋白的结构和功能有较好的保护和改善作用。总体来说,低磁场冷冻可以抑制肌原纤维蛋白变性并维持良好的结构和功能,且与常规冷冻(-30 ℃)相比,低磁场冷冻(-20 ℃、2 mT)可以节约10 ℃的冷冻温差,预测其具有一定的节能潜力。  相似文献   
6.
Classical Fourier's theory is well-known in continuum physics and thermal sciences. However, the primary drawback of this law is that it contradicts the principle of causality. To explore the thermal relaxation time characteristic, Cattaneo–Christov's theory is adopted thermally. In this regard, the features of magnetohydrodynamic (MHD) mixed convective flows of Casson fluids over an impermeable irregular sheet are revealed numerically. In addition, the resulting system of partial differential equations is altered via practical transformations into nonlinear ordinary differential equations. An advanced numerical algorithm is developed in this respect to get higher approximations for temperature and velocity fields, as well as their corresponding wall gradients. For validating our numerical code, the current outcomes are compared with the available literature results. Moreover, it is revealed that the velocity field is more prominent in the suction flow situation as compared with the injection flow case. It is also found that the Casson fluid is hastened in the case of lower yield stress. Larger values of thermal relaxation parameters create a lessening trend in the temperature distribution and its related boundary layer breadth.  相似文献   
7.
以青海的黑枸杞为主要原料,以植物乳杆菌(Lactobacillus plantarum)为发酵菌种,制备黑枸杞乳酸菌饮料,并采用单因素试验和响应面试验优化其发酵工艺条件。结果表明,最佳发酵工艺条件为固液比1∶25(g∶mL),植物乳杆菌接种量2.0%,发酵时间6 h,装液量40%。在此最佳条件下,黑枸杞乳酸菌饮料感官评分为9.3分,总糖含量为0.17 mg/mL,总酸含量为1.69 g/L,花青素含量为52.75 mg/L、总黄酮含量为0.07 mg/mL、总酚含量为0.99 mg/mL。  相似文献   
8.
Gelatin is one of the most important multifunctional biopolymers and is widely used as an essential ingredient in food, pharmaceutical, and cosmetics. Porcine gelatin is regarded as the leading source of gelatin globally then followed by bovine gelatin. Porcine sources are favored over other sources since they are less expensive. However, porcine gelatin is religiously prohibited to be consumed by Muslims and the Jewish community. It is predicted that the global demand for gelatin will increase significantly in the future. Therefore, a sustainable source of gelatin with efficient production and free of disease transmission must be developed. The highest quality of Bovidae-based gelatin (BG) was acquired through alkaline pretreatment, which displayed excellent physicochemical and rheological properties. The utilization of mammalian- and plant-based enzyme significantly increased the gelatin yield. The emulsifying and foaming properties of BG also showed good stability when incorporated into food and pharmaceutical products. Manipulation of extraction conditions has enabled the development of custom-made gelatin with desired properties. This review highlighted the various modifications of extraction and processing methods to improve the physicochemical and functional properties of Bovidae-based gelatin. An in-depth analysis of the crucial stage of collagen breakdown is also discussed, which involved acid, alkaline, and enzyme pretreatment, respectively. In addition, the unique characteristics and primary qualities of BG including protein content, amphoteric property, gel strength, emulsifying and viscosity properties, and foaming ability were presented. Finally, the applications and prospects of BG as the preferred gelatin source globally were outlined.  相似文献   
9.
Natural gas hydrate nucleation is a complex physical and chemical process that is not well understood presently. In this article, an improved thermodynamic model is proposed to analyze the effects of surface curvature and wettability on methane hydrate nucleation for the first time. The results indicate that methane hydrate nucleation is more difficult on hydrophilic curvature surfaces under the same conditions, with a larger critical nucleation radius and required energy barrier than on hydrophobic surfaces. Furthermore, a convex surface is more favorable for forming methane hydrate under the same conditions than a concave surface. The model's results are critical in elucidating the microscopic mechanism of methane hydrate nucleation and providing a theoretical foundation for developing technologies for strengthening and inhibiting hydrate formation.  相似文献   
10.
魏朋  陈珺  王志国  刘飞 《化工学报》2022,73(2):792-800
在模拟移动床的实际工作过程中,由于进料浓度和温度变化以及色谱柱填充不一致等因素影响,初始工艺参数作业下的分离性能可能会出现下降。首先对模拟移动床的机理模型进行了分析;然后在色谱分离平衡理论的基础上,使用有限元正交配置法求解模型得到新的工艺参数点;最后以果葡糖浆组分分离为对象,使用所提方法求解有扰动作用时的优化工艺参数,结果显示果糖纯度的合格率从81%提高到99%,证明其具有良好的鲁棒性。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号