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1.
《Ceramics International》2021,47(19):27386-27394
In order to control the pore characteristics and macroscopical performance of porous ceramics, roles of the freeze casting parameters are the key points. Herein, aligned dendritic porous SiC was fabricated by freeze casting of PCS-camphene solutions with different solid loading, freeze front velocity, temperature gradient, and freezing temperature. Influence of these parameters on the microstructure and compressive strength of porous SiC was investigated. With increasing the PCS content, freeze temperature, freeze front velocity or temperature gradient, degree of undercooling of the camphene was increased, resulting in the formation of smaller pore size, decreased porosity and increased compressive strength. Compared to variables of freeze temperature and temperature gradient, increased freeze front velocity was more efficiency in improving the compressive strength of porous SiC, owing to the formation of smaller pore size and longer secondary dendritic crystals. Promising micron-sized porous SiC with high porosity (79.93 vol%) and satisfactory strength (15.84 MPa) was achieved for 10% PCS-camphene solution under optimized freezing conditions.  相似文献   
2.
Coupling of side chain dynamics over long distances is an important component of allostery. Methionine side chains show the largest intrinsic flexibility among methyl-containing residues but the actual degree of conformational averaging depends on the proximity and mobility of neighboring residues. The 13C NMR chemical shifts of the methyl groups of methionine residues located at long distances in the same protein show a similar scaling with respect to the values predicted from the static X-ray structure by quantum methods. This results in a good linear correlation between calculated and observed chemical shifts. The slope is protein dependent and ranges from zero for the highly flexible calmodulin to 0.7 for the much more rigid calcineurin catalytic domain. The linear correlation is indicative of a similar level of side-chain conformational averaging over long distances, and the slope of the correlation line can be interpreted as an order parameter of the global side-chain flexibility.  相似文献   
3.
采用热重分析法研究了经KOH浸渍的甲壳素的热解特性,并考察了不同浸渍比对热解过程的影响;同时采用Coats-Redfern积分法拟合计算出热解动力学参数,探究了KOH对甲壳素主要热解过程中活化能的影响。热重分析结果表明:KOH的加入改变了甲壳素的热解行为,降低了热解所需的活化能,加快了反应速率,促进了甲壳素热解;当浸渍比即m(65% KOH)∶m(甲壳素)=2∶1或3∶1时,KOH浸渍后能使甲壳素在140℃左右开始迅速热解。热解动力学参数计算结果表明:无论反应级数选择多大,其线性拟合效果均比较好,相关系数基本都高于0.95;KOH作用下甲壳素热解是一个复杂的化学反应,而不是单一的某一级反应。  相似文献   
4.
田应祥  张义平 《中国矿业》2021,30(7):171-175
为解决传统预裂爆破与光面爆破技术难以满足现如今高质量、高标准施工要求的难题,根据切缝药包的作用机理,对切缝药包在边坡预裂爆破中的应用进行研究。根据现场施工情况,设计相应爆破参数,进行切缝药包预裂爆破参数优化试验,并对切缝药包预裂爆破和传统预裂爆破的工程应用进行对比研究。试验结果表明:在中硬岩、90 mm直径预裂孔的条件下,采用外径40 mm、内径36 mm,切缝长度0.8m,切缝宽度10mm的PVC管作为切缝管进行切缝药包预裂爆破,其爆破效果较好;通过与传统预裂爆破相比,切缝药包预裂爆破后预裂缝宽度增加了1.12倍,预裂面不平整度减少了52.8%,半孔率提高了21%,振动速度峰值降低了29.02%,有效减少了爆破能量对保留边坡与周边构建筑物的损害,显著提高了爆破施工的质量。  相似文献   
5.
《Ceramics International》2021,47(19):27351-27360
A series of xPbO–(45-x)CuO–55B2O3 glasses (5 ≤ x ≥ 40 mol %) were prepared by the melt-quenching technique. The X-ray diffraction (XRD) patterns of the prepared glasses are found to have amorphous structure. An extensive ultrasonic study has been made to explore the structural role of PbO and CuO in the borate network. Various elastic properties were calculated from the measured data of density and ultrasonic velocity. Ultrasonic velocity and elastic moduli revealed broad humps at about 20 mol % PbO, which are attributed to the borate anomaly. Below 20 mol % PbO, all Pb2+ ions are considered to be entering the borate network as a glass modifier. This results in the transforms the borate network from an open structure to a denser three-dimensional structure due to BO3 → BO4 conversion. Beyond 20 mol, addition of PbO results in the formation of metaborate, pyroborate, and orthoborate units with NBOs. This weakness the glass structure and decrease both ultrasonic velocity and elastic moduli. The elastic properties were predicted and quantitatively analyzed by taking into account the effect of boron coordination number on the compositional and structural parameters involved in Makishima–Mackenzie's theory, ring deformation model and bond compression model. An excellent agreement between the computed theoretical and experimental elastic moduli, micro-harness and Poisson's ratio was achieved for majority of samples.  相似文献   
6.
利用有限元分析软件ABAQUS研究微织构PCBN刀具车削Cr12MoV的过程,采用田口法进行正交试验设计,通过信噪比分析方法研究刀?屑实际接触面积、切削力和切削温度随织构参数的变化规律,并获得织构参数的最优组合。结果表明,刀?屑实际接触面积分别随织构槽宽和织构刃边距的增大而减小,织构槽宽和织构刃边距对刀具的切削性能影响最显著;与无织构刀具对比,选取最优织构参数组合的微织构PCBN刀具可使切削力降低5.2%,切削温度降低4.7%。  相似文献   
7.
Ferrites are materials of interest due to their broad applications in high technological devices and a lot of research has been focused to synthesize new ferrites. In this regard, an effort has been devoted to synthesize spinel Pr–Ni co-substituted strontium ferrites with a nominal formula of Sr1-xPrxFe2-yNiyO4 (0.0 ≤ x ≤ 0.1, 0.0 ≤ y ≤ 1.0). The cubic structure of pure and Pr–Ni co-substituted strontium ferrite samples calcinated at 1073 K for 3 h has been confirmed through X-ray diffraction (XRD). Average sizes of crystallites (18–25 nm) have been estimated from XRD analysis and nanometer particle sizes of synthesized ferrites have been further verified by scanning electron microscopy (SEM). SEM results have also shown that particles are mostly agglomerated and all the samples possess porosity. It has been observed that at 298 K, the values of resistivity (ρ) increase, while that of AC conductivity, dielectric loss, and dielectric constants decrease with increasing amounts of Pr3+ and Ni2+ ions. The values of dielectric parameters initially decrease with frequency and later become constant and can be explained on the basis of dielectric polarization. Electrochemical impedance spectroscopy (EIS) studies show that the charge transport phenomenon in ferrite materials is mainly controlled via grain boundaries. Overall, synthesized ferrite materials own enhanced resistivity values in the range of 1.38 × 109–1.94 × 109 Ω cm and minimum dielectric losses, which makes them suitable candidates for high frequency devices applications.  相似文献   
8.
The effect of an external electric field on laser-generated plasma has been studied. It is observed that the laser-generated plasma can be used for the ignition of a spark in the presence of a low voltage external electric field. An eight-fold emission intensity enhancement in Cu Ⅰ spectral lines are measured as compared to the signal intensity in the absence of an external electric field.The plasma parameters remain the same initially, up to a few microseconds after the generation of plasma, and this feature makes it more interesting for the quantitative analysis of any sample using laser induced breakdown spectroscopy(LIBS). In the presence of an external electric field,fluctuations(contraction and expansion) in the laser-generated plasma are observed which increase the plasma decay time and consequently result in enhanced signal intensity.  相似文献   
9.
研究了常化温度对无取向电工钢组织及性能的影响。结果表明:常化板织构特征呈现织构梯度分布,中心层分布的主要是{100}〈021〉、{114}〈481〉、{112}〈421〉等α*取向晶粒,Goss和黄铜等取向晶粒则主要分布于表层及次表层区域。经5 min常化处理,常化温度由840 ℃提升到920 ℃,常化板晶粒尺寸增加,成品板晶粒尺寸增加,铁损值P1.5/50降低约0.106 W/kg,成品板中心层{100}取向晶粒体积分数增加,{111}和{112}取向晶粒体积分数降低,织构得以改善,磁感B5000升高约0.016 7 T。  相似文献   
10.
根据某核电厂址的现场示踪试验采样结果,结合网格自适应直接搜索算法(MADS),比较了基于单次采样平均、单次释放平均、单次采样一次优化以及单次释放一次优化4种数据处理方法对大气扩散参数结果的影响。研究结果表明,应用该优化方法获得的计算扩散因子与测量结果总体上很相近,结果可信且能够反映厂址的大气扩散参数环境特征。基于单次采样的数据处理方法的结果可信度不如基于单次释放的数据处理结果。在基于单次释放数据的处理方法中,单次释放平均和单次释放一次优化的结果相近,优化结果均较为可信,可根据厂址其他环境特征或者从弥散结果保守性方面进行选择。  相似文献   
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