首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   78152篇
  免费   8552篇
  国内免费   3248篇
电工技术   1275篇
技术理论   1篇
综合类   3763篇
化学工业   25348篇
金属工艺   12200篇
机械仪表   2907篇
建筑科学   2542篇
矿业工程   1062篇
能源动力   1651篇
轻工业   8827篇
水利工程   357篇
石油天然气   1433篇
武器工业   478篇
无线电   2888篇
一般工业技术   20146篇
冶金工业   3405篇
原子能技术   334篇
自动化技术   1335篇
  2024年   90篇
  2023年   1802篇
  2022年   2501篇
  2021年   3423篇
  2020年   3354篇
  2019年   2760篇
  2018年   2990篇
  2017年   3442篇
  2016年   3378篇
  2015年   3620篇
  2014年   4361篇
  2013年   5560篇
  2012年   5041篇
  2011年   6148篇
  2010年   4162篇
  2009年   4546篇
  2008年   3776篇
  2007年   4205篇
  2006年   3997篇
  2005年   3194篇
  2004年   3088篇
  2003年   2618篇
  2002年   2127篇
  2001年   1516篇
  2000年   1311篇
  1999年   1043篇
  1998年   881篇
  1997年   820篇
  1996年   708篇
  1995年   616篇
  1994年   476篇
  1993年   371篇
  1992年   361篇
  1991年   282篇
  1990年   329篇
  1989年   296篇
  1988年   142篇
  1987年   83篇
  1986年   74篇
  1985年   101篇
  1984年   104篇
  1983年   68篇
  1982年   88篇
  1981年   10篇
  1980年   42篇
  1979年   6篇
  1978年   6篇
  1976年   5篇
  1975年   6篇
  1974年   7篇
排序方式: 共有10000条查询结果,搜索用时 19 毫秒
1.
Dense pressure-sintered reaction-bonded Si3N4 (PSRBSN) ceramics were obtained by a hot-press sintering method. Precursor Si powders were prepared with Eu2O3–MgO–Y2O3 sintering additive. The addition of Eu2O3–MgO–Y2O3 was shown to promote full nitridation of the Si powder. The nitrided Si3N4 particles had an equiaxial morphology, without whisker formation, after the Si powders doped with Eu2O3–MgO–Y2O3 were nitrided at 1400 °C for 2 h. After hot pressing, the relative density, Vickers hardness, flexural strength, and fracture toughness of the PSRBSN ceramics, with 5 wt% Eu2O3 doping, were 98.3 ± 0.2%, 17.8 ± 0.8 GPa, 697.0 ± 67.0 MPa, and 7.3 ± 0.3 MPa m1/2, respectively. The thermal conductivity was 73.6 ± 0.2 W m?1 K?1, significantly higher than the counterpart without Eu2O3 doping, or with ZrO2 doping by conventional methods.  相似文献   
2.
《Ceramics International》2021,47(19):27535-27544
In this paper, we present an efficient and effective method to predict the pressure dependence and temperature dependence of second-order elastic constants (SOECs) by introducing third-order elastic constants (TOECs) in the monocarbide ultrahigh temperature ceramics. The method is validated by comparing with experiments and previous calculations in four TMCs (TM = Nb, Ti, V, Zr). Using this method, we investigate the derivatives of SOECs against pressure and temperature as well as the anisotropic properties of polycrystalline modulus. In addition, we fit the SOECs with pressure and temperature under the framework of CALPHAD for practice usage.  相似文献   
3.
In this work, we designed a magnetically-separable Fe3O4-rGO-ZnO ternary catalyst, ZnO anchored on the surface of reduced graphene oxide (rGO)-wrapped Fe3O4 magnetic nanoparticles, where rGO, as an effective interlayer, can enhance the synergistic effect between ZnO and Fe3O4. The effects of three operational parameters, namely irradiation time, hydrogen peroxide dosage, and the catalyst dosage, on the photo-Fenton degradation of methylene blue and methyl orange were investigated. The results showed that the Fe3O4-rGO-ZnO had great potential for the destruction of organic compounds from wastewater using the Fenton chemical oxidation method at neutral pH. Repeatability of the photocatalytic activity after 5 cycles showed only a tiny drop in the catalytic efficiency.  相似文献   
4.
《Ceramics International》2021,47(21):30349-30357
Mesoporous glass 58S (60SiO2, 36CaO, 4P2O5 mol.%) has excellent bioactivity, biocompatibility, and forms strong bonds with bone making it attractive for implants. Mesoporous bioactive glass 58S powder is typically consolidated through sintering in order to produce an implant with sufficient strength to withstand the in vivo loads. However, heating the glass often leads to crystallinity, which is undesirable because it can reduce bioactivity. Hence, there is a trade-off between minimising crystallinity and maximising glass strength. Even at relatively low temperatures, it has been suggested that segregation of calcium and phosphate from silica within the glass can lead to crystallization. In this work, we confirm the occurrence of low temperature segregation in bioactive glass 58S using electron microscopy with elemental mapping. We probe how segregation affects the material properties of post-sintered glasses via comparison to a glass where phase separation is prevented via addition citric acid to the parent sol.  相似文献   
5.
为了减轻汽车重量,提高燃油消耗,研制了高强度钢帘线用线材。然而,开发高强度钢帘线的难点是必须同时获得高强度和良好的塑性。为了解决这一问题,通过分析拉丝过程中钢丝组织和力学性能的变化,研究了拉丝过程中的分层机理,提高了拉丝的塑性。采用1.0%C过共析钢和优化的拉拔工艺,在实验室可获得4400 MPa级钢帘线。  相似文献   
6.
差速器是汽车变速箱的核心部件,其质量直接影响着汽车的工作稳定性。以实际项目为研究背景,设计了用在机器人上的差速器壳体(简称"差壳")抓取装置,并利用有限元法对夹具的胀套进行了强度和疲劳分析,得到其应力和寿命结果,以此评估胀套的综合特性。得到结论:对于304、Q235和65Mn三种材料的胀套,其最大应力均远小于屈服应力,最大损伤处均在胀片尾部处;疲劳分析中,65Mn的最小循环次数为4.3×105次左右,满足装置的强度和寿命设计要求。  相似文献   
7.
Based on the 3 factors and 3 levels orthogonal experiment method, compositional effects of Mg, Si, and Ti addition on the microstructures, tensile properties, and fracture behaviors of the high-pressure die-casting Al-x Mg-y Si-z Ti alloys have been investigated. The analysis of variance shows that both Mg and Si apparently infl uence the tensile properties of the alloys, while Ti does not. The tensile mechanical properties are comprehensively infl uenced by the amount of eutectic phase(α-Al + Mg_2Si), the average grain size, and the content of Mg dissolved into α-Al matrix. The optimized alloy is Al-7.49 Mg-3.08 Si-0.01 Ti(wt%), which exhibits tensile yield strength of 219 MPa, ultimate tensile strength of 401 MPa, and elongation of 10.5%. Furthermore, contour maps, showing the relationship among compositions, microstructure characteristics, and the tensile properties are constructed, which provide guidelines for developing high strength and toughness Al–Mg–Si–Ti alloys for high-pressure die-casting.  相似文献   
8.
海上风电作为可再生清洁能源之一,受到世界各国的高度重视与大力发展。我国将海上风电提升至解决能源危机、减缓气候变化、调整能源结构的国家战略高度,到2030年我国单位国内生产总值二氧化碳排放将比2005年下降65%以上,非化石能源占一次能源消费比重将达到25%左右。安装平台不足将是我国海上风电场无法如期建成投产的主要障碍。对自升自航式海上风电安装平台系列高端装备及其设计制造的三大技术难题——腿站立作业易“失稳”、大平台大跨距大倾覆力矩自升易“失控”、高空吊装巨型叶片逾百螺栓精准定位易“失准”,以及焊缝缺陷修复和局部裂纹损伤的激光锻造修复再制造进行了介绍,研制的具有不同规格的系列装备在中国、英国、丹麦、德国等国家的著名海上风电场建设应用情况良好。  相似文献   
9.
Chameleonic properties, i. e., the capacity of a molecule to hide polarity in non-polar environments and expose it in water, help achieving sufficient permeability and solubility for drug molecules with high MW. We present models of experimental measures of polarity for a set of 24 FDA approved drugs (MW 405-1113) and one PROTAC (MW 1034). Conformational ensembles in aqueous and non-polar environments were generated using molecular dynamics. A linear regression model that predicts chromatographic apparent polarity (EPSA) with a mean unsigned error of 10 Å2 was derived based on separate terms for donor, acceptor, and total molecular SASA. A good correlation (R2=0.92) with an experimental measure of hydrogen bond donor potential, Δlog Poct-tol, was found for the mean hydrogen bond donor SASA of the conformational ensemble scaled with Abraham's A hydrogen bond acidity. Two quantitative measures of chameleonic behaviour, the chameleonic efficiency indices, are introduced. We envision that the methods presented herein will be useful to triage designed molecules and prioritize those with the best chance of achieving acceptable permeability and solubility.  相似文献   
10.
研究Nb元素对Cr-Ni-Mo系合金在不同渗碳热处理工艺下组织和性能的影响。结果表明,不同渗碳工艺下Nb元素对表面硬度及表面残留奥氏体含量、非马组织影响不大。但是,通过Nb元素细化晶粒的试验钢,在较长的渗碳工艺下能使得有效硬化层深加深10%且获得更细的表层马氏体片层组织。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号