Intramolecular crosslinking of poly(vinyl alcohol)

Poly(vinyl alcohol) is crosslinked in dilute solution (c=0.1 wt%) with glutaraldehyde. The reaction product is characterized by viscometry and gel permeation chromatography (g.p.c.). The intrinsic viscosity decreases with increasing degree of crosslinking and does not depend on temperature. G.p.c. reveals that the reaction product is not homogeneous, but consists of a mixture of particles with different sizes, possibly both intra- and intermolecularly crosslinked molecules. The intramolecularly crosslinked molecules are smaller in size than the initial polymer molecules and their size depends on the degree of crosslinking. They possess a narrow particle size distribution even if the initial polymer sample had a broad molecular weight distribution.     

交联透明质酸的降解及其释药性能

用己二酸二酰肼（ADH）对透明质酸（HA）进行化学修饰，制备交联透明质酸（HA-ADH）薄膜。粘度法测试表明HA-ADH是一种可降解的生物材料，并且与HA相比，HA．ADH的降解速率减慢。在此基础上，研究了以疏水性的替硝唑（TDZ）和亲水性的头孢唑啉钠（CEZ）为模拟药物的HA-ADH药物载体薄膜的释药性能。紫外-可见（UV-Vis）吸收光谱检测表明，HA-ADH是一种疏水性药物TDZ的优良缓释制荆，这是由于TDZ的疏水性和HA-ADH薄膜的缓慢溶胀和降解性能的结合而得到的，药物的释放主要受扩散机制控制。     

高温稀土永磁Sm2(Co,Cu,Fe,Zr)17 的制备和性能

制备了高温稀土永磁材料Sm(Coba1Fe0．26Cu0．05Zr0．026)7．0，研究了磁性能与工艺条件的关系．结果表明：提高烧结温度可使材料的Br和(BH)max增大，但是使Hci降低；适当提高真空预烧温度，可使材料在较低烧结温度下致密化，具有较高的Hci和(BH)max和温度稳定性．真空预烧温度过高使性能的急剧降低，其主要原因是Sm的析出．在最佳工艺条件下材料的磁性能参数分别为：Br1．08T3Hci2286kA／m，Hcb932kA／m，(BH)max220．8kJ／m^3；β20-200℃为-0．19％／℃．     

高能球磨FeCo+MnO的结构与磁性研究

用高能球磨采用两种方案制备了FeCo MnO体系,并用X射线衍射和振动样品磁强计对其结构和磁性质做了分析.发现采用直接氧化Mn而得到MnO的方法,所得体系的MnO较纯;而通过分解MnCO3得到MnO的体系,MnO纯度较低,有较多Mn3O4杂质,两种方法制备的FeCo MnO体系的矫顽力和剩磁比都比单纯FeCo体系的增加很多,且前一种方法比后一种方法制备的FeCo MnO体系的矫顽力和剩磁比较大.然后研究了球磨时间及退火处理对FeCo MnO体系矫顽力及剩磁比的影响,发现球磨时间为120h体系的矫顽力和剩磁比最大;经过退火处理后,体系的矫顽力和剩磁比都有较大幅度的增加.     

架空乘人装置用隔爆兼本安型控制箱的研制

针对采用继电器控制方式控制架空乘人装置存在维护困难、工作效率低、安全性能差等问题,提出了一种基于PLC控制的架空乘人装置用控制箱的研制方案,介绍了该控制箱的硬件、软件设计及功能特点。该控制箱采用PLC作为控制核心、MT6070I系列触摸屏作为人机界面,实现了架空乘人装置及时停车、急停闭锁、状态及时显示、保护等功能。实际应用表明,该控制箱运行稳定,实现了全自动无人值守运行,提高了架空乘人装置的安全性和可靠性。     

防爆变频器在煤矿应用中的关键技术

分析了防爆变频器在煤矿井下使用过程中存在的电压等级、散热、电磁兼容性、逆变器转换效率等问题,详细介绍了解决这些问题的方法,即通过采用隔爆兼本质安全型技术和热管散热技术解决变频器的防爆和散热问题,使防爆变频器具有性能高、功能强、噪音低等特点;通过改变变频器的电路拓扑结构、改进控制策略等技术手段解决变频器的电磁兼容性和能耗问题,使防爆变频器满足煤矿生产的现代化要求。     

矿用隔爆兼本安型计算机信号隔离器设计

针对煤矿井下电气设备要求本质安全的特点,设计了一种矿用隔爆兼本安型计算机信号隔离器,主要介绍了该隔离器的硬件电路设计。该隔离器主要用于矿井中本质安全型计算机主机与外部输入输出设备的连接,能够实时地传送键盘输入的数据,具有良好的信号隔离功能和抗干扰性能。     

矿用隔爆兼本质安全型不间断直流稳压电源的设计

基于本质安全型电源的原理及特点,提出了一种矿用隔爆兼本质安全型不间断直流稳压电源的设计方案,详细介绍了该电源主要电路的设计。该电源采用LM317可调稳压芯片实现稳压功能,具有使用方便、电路简单、变换效率高、成本低等优点。测试结果表明,该电源达到了本安标准,满足了安全型电气设备的需求。     

Photovoltaic effect and carrier transport mechanisms in Hg1-Mnxtdiodes

Hg_1-xMn_xTe semiconducting semimagnetic alloy has been examined in the context of its possible applications in infrared detectors. For analysis of detector properties the intrinsic carrier concentration has been calculated as a function of temperature and crystal composition. The starting material was In-doped Hg_1-xMn_xTe grown by the modified Bridgman method. The as-grown crystals with manganese content of 12-19% were p-type with carrier concentration and mobility of 100 cm²/ Vs at 77 K. An-type layer was formed on the surface by the annealing process in saturated Hg-vapour at 270-320° for 2 hrs. Capacitance-voltage curves have C^-3 dependence on applied voltage indicating that the junction is linearly graded. From standard electrical measurements and spectral characteristics the main detector parameters were determined and compared to those of Hg_1-xCd_xTe devices. The influence of material properties on detector parameters was analyzed. In order to estimate the carrier transport mechanisms, differential resistivities and current-voltage curves were measured over a wide range of temperaturesi.e. 25 to 300 K. From the temperature dependence of the R₀A product, it was established that at high temperatures (150-300 K) the carrier transport is dominated by a recombination-generation mechanism. In low temperature region the excess current at forward bias is probably attributed to carrier tunneling via energy states distributed randomly within the forbidden gap. At reverse bias the leakage surface or volume currents dominate in the carrier transport.