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1.
大排田岩体位于粤北澜河铀矿集区内,对研究区内大排田岩体粗中粒斑状黑云母花岗岩进行了详细的岩相学和地球化学分析,以探讨其岩石成因、岩浆源区及与铀成矿的关系。结果表明,大排田岩体中粗粒斑状黑云母花岗岩具有高SiO2(73.6%~76.5%),富Al2O3(12.4%~13.5%)、富碱(K2O=5.21%~5.63%,Na2O=2.44%~2.76%),且钾大于钠,贫MgO(0.23%~0.52 %)、铝饱和指数(A/CNK)为1.30~1.56,FeOt/MgO为3.21~6.61,属于高钾钙碱性过铝质花岗岩。大排田岩体微量元素显示了Rb、Th、U、Ta相对富集, Ba、Nb、Sr等元素相对亏损特征。稀土元素配分模式总体呈右倾型,轻重稀土分馏明显,轻稀土相对富集(112×10-6~245×10-6),重稀土相对亏损(26.7×10-6~53.3×10-6),Eu显示了负异常特征。上述地球化学特征指示其具有A2型花岗岩特征。推测其形成于拉张构造背景下,由变泥质沉积岩发生部分熔融形成的。  相似文献   
2.
To explore the feasibility and related mechanism of MFC biosensor for wastewater detection under the action of combined heavy metals. Cyclic voltammetry (CV) and scanning electrochemical impedance spectroscopy (EIS) were used to explore the related bioelectrochemical process. The response of the reactor to single/combined heavy metals, low/high heavy metal concentrations, and the differences in ohmic resistance (Rs) and charge transfer resistance (Rct) were investigated using Ni as the core heavy metal and the combined action of Cd, Cu and Zn. The results indicated that there was a linear relationship between the concentration and output voltage of the MFC biosensor under the action of combined heavy metals (R2 = 0.8803–0.973). However, the internal resistance (Rint) of the MFC biosensor under the action of single heavy metal was far less than that of the combined heavy metal group, and the power density (19.849 W m?3) was 4 times that of the combined heavy metal group (3.109–4.589 W m?3). The Rs of the biosensors in the combined heavy metal group were 0.868Ω and 0.860, which were higher than 0.768Ω of the single heavy metal sensor. With the increase of the concentration of heavy metals in the influent, the increase of Rct was more obvious in the combined group, while the Rs in the single group significantly increased (P < 0.05). The results imply that it is possible for MFC biosensors to be used in the detection of actual water polluted by various heavy metals, but the biosensor performance is mainly limited by Rct, which needs to be further improved.  相似文献   
3.
Thermal action in extraction process had effects on characteristic tryptic peptides identification and gelling properties of porcine gelatin. SDS-PAGE, HPLC-LTQ/Orbitrap high-resolution mass spectrometry, texture analyser and rheometer were used to evaluate collagen depolymerisation degree, characteristic tryptic peptides and gelling properties of gelatins prepared in various thermal actions. Results showed that with increasing temperature and time, depolymerisation degree enlarged, while gel strength, gelling and melting temperature decreased. Mass spectra showed that 47 and 49 common characteristic tryptic peptides were identified in gelatins extracted at 50 °C and 100 °C with various times, respectively. Moreover, 34 common characteristic tryptic peptides were identified in all gelatin samples. Further comparison between this work and our previous investigations yielded 20 common characteristic tryptic peptides, which stably exist in various thermal actions. These common characteristic tryptic peptides may be very helpful for the accurate authentication of porcine gelatin.  相似文献   
4.
Hybrid nanofluid boundary layer flow past a stretching surface with zero mass flux boundary condition is explored in this article. The main aim of this article is to analyze the electromagnetohydrodynamic role in a hybrid nanofluid containing silver and molybdenum disulfide nanoparticles. The self-similar solution is embedded to reduce the governing partial differential equation into algebraic equations and a shooting algorithm is applied to obtain the solution of the resultant boundary value problem. Variation in momentum, energy, and nanoparticle concentration is explained through graphical profiles. Nusselt number and drag force coefficients are computed for various flow parameters and their impact on the nanofluid and hybrid nanofluid is computed and presented and explained in a comparative fashion. It is observed that the velocity profile shows the opposite nature with respect to the electric field and magnetic field. For electric field parameter velocity accelerates whereas for magnetic parameter velocity diminishes. Nusselt number increases with electric field parameter and nanoparticle volume fraction.  相似文献   
5.
In the present paper, therapeutic treatment of infected tumorous cells has been studied through mathematical modeling and simulation of heat transfer in tissues by using a nonlinear dual-phase lag bioheat transfer model with Dirichlet boundary condition. The components of volumetric heat source in this model such as blood perfusion and metabolism are assumed experimentally validated temperature-dependent function, which gives more accurate temperature distribution in tissues through this model. We have used the finite difference and RK (4, 5) techniques of numerical methods to solve the proposed problem and obtained the exact solution in a particular case. After comparison, we got a good agreement between them. We have used dimensionless quantities throughout this paper. The effect of relaxation and thermalization time with respect to dimensionless temperature distribution has been analyzed in the treatment process.  相似文献   
6.
张健  路源 《热科学与技术》2022,21(2):130-135
搭建了内径约600mm的空气湿化塔性能实验台,以塑料阶梯环散装填料塔为研究对象,实验并分析了气速、水气比、填料总高度对湿化塔的压力损失、加湿效果和传质单元高度的影响,以及进水温度对后两者的影响,同时获得了空气湿化填料塔精细设计数据,并对结果进行了拟合,得到填料的传质单元高度经验关联式。  相似文献   
7.
本文采用193 nm紫外激光解离质谱(UVPD-MS)研究非变性电喷雾条件下,超电荷试剂环丁砜对蛋白质序列、结构表征的影响。UVPD可在5 ns内对保持高级结构和非共价相互作用的不同价态碳酸酐酶进行快速激发解离,解离序列覆盖率达79.8%,具有较高的解离结构选择性。超电荷试剂环丁砜的引入可显著增加非变性电喷雾产生的碳酸酐酶离子的电荷数目,UVPD解离序列覆盖率提升至87.2%,实现对难解离区域的位点覆盖和序列、结构表征。加入环丁砜后,碳酸酐酶仍能保持高级结构谱学特征及与锌离子的非共价结合,锌离子结合区域等大部分结构区域的UVPD位点解离效率未见显著变化。但是,电荷数目的增加存在引起蛋白质局部结构变化的风险。  相似文献   
8.
由于色谱分离需要耗费大量的时间,导致传统LC-MS研究中药成分的分析通量较低,而多级质谱全扫描(MS/MSALL)采用了气态分段技术(GPF),可以在直接注射(DI)模式下,采集每个表观质量数MS1信号的MS2图谱,实现MS1-MS2数据列表的高通量构建。为快速表征枸杞子化学成分组,本研究采用DI-MS/MSALL全面采集枸杞子提取物中各化学成分的多级质谱数据,根据高分辨MS1和MS2碎片离子信息推导质谱裂解途径,结合数据库检索以及相关文献,从枸杞子中初步鉴定了38个化学成分,包括1个氨基酸类、19个有机酸类、2个糖脂类、6个苯丙素类、1个黄酮类、6个生物碱类以及3个酰胺类化合物。DI-MS/MSALL可作为中药等复杂体系快速全面定性分析的有力工具。  相似文献   
9.
We present the Onsager–Stefan–Maxwell thermodiffusion equations, which account for the Soret and Dufour effects in multicomponent fluids. Unlike transport laws derived from kinetic theory, this framework preserves the structure of the isothermal Stefan–Maxwell equations, separating the thermodynamic forces that drive diffusion from the force that drives heat flow. The Onsager–Stefan–Maxwell transport-coefficient matrix is symmetric, and the second law of thermodynamics imbues it with simple spectral characteristics. This new approach allows for heat to be considered as a pseudo-species and proves equivalent to both the intuitive extension of Fick's law and the generalized Stefan–Maxwell equations popularized by Bird, Stewart, and Lightfoot. A general inversion process facilitates the unique formulation of flux-explicit transport equations relative to any choice of convective reference velocity. Stefan–Maxwell diffusivities and thermal diffusion factors are tabulated for gaseous mixtures containing helium, argon, neon, krypton, and xenon. The framework is deployed to perform numerical simulations of steady three-dimensional thermodiffusion in a ternary gas.  相似文献   
10.
朱孟帅  王子龙  孙向昕  周翔 《化工进展》2022,41(6):3203-3211
基于石蜡和高孔密度的泡沫铜制备了复合相变蓄热材料,设计并搭建了一套可视化蓄热实验装置,分析了高孔密度下泡沫铜填充率对石蜡相变过程的强化传热机理,得到了复合相变蓄热材料的综合传热系数。实验结果表明,当泡沫铜填充率为0、0.43%、1.29%和2.15%时,复合相变材料的综合传热系数先减小后增大,分别为1.26W/(m·K)、1.18W/(m·K)、1.44W/(m·K)和1.88W/(m·K),因此随着泡沫铜填充率的增加,复合相变材料的融化时间先增长后缩短。此外,随着泡沫铜填充率从0.43%增至2.15%,复合相变材料融化时传热机制中导热占比从17.26%上升到86.01%,自然对流占比从82.74%下降到13.99%。  相似文献   
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