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1.

Fe-based bulk metallic glasses (BMGs) with high boron content have potential application as a coating material used in the framework for storing spent nuclear fuels to support their safe long-term disposal. The high glass forming ability (GFA) and large supercooled liquid region are therefore required for such Fe-based BMGs in either the glassy powder fabrication or the subsequent coating spraying. In order to meet these requirements, the influence of Nb content on the GFA of Fe57Cr10Zr8B18Mo7−xNbx (x=1–5, at.%) alloys was investigated, as Nb has positive roles in GFA and thermal stability of BMGs. The results indicate that a fully amorphous phase in the as-cast samples with 3 mm in diameter is obtained for both the Fe57Cr10Zr8B18Mo5Nb2 and Fe57Cr10Zr8B18Mo4Nb3 alloys. The corresponding supercooled liquid regions of the two BMGs are 78 K and 71 K, respectively. The mechanism for improving their GFA was analyzed based on the principle of metal solidification, the parameters for glass formation and thermal properties of the alloys. The compression strength and Vicker’s hardness of the two BMGs are 1,950 MPa and 1,310 HV, 2,062 MPa and 1,180 HV, respectively. The developed BMGs with high B content, good GFA, and very high hardness can be used as coating materials to the framework for spent nuclear fuels.

  相似文献   
2.
杨硕  张文梦  陈栋阳 《精细化工》2021,38(4):749-756
以聚二甲基硅氧烷(PDMS)和纳米SiO2掺杂聚芴醚酮(PFEK),采用溶液喷涂法在纸张表面构筑了耐用的超疏水涂层.考察了PDMS和SiO2用量(以PFEK和N-甲基吡咯烷酮的质量为基准,下同)对纸张水接触角的影响.结果表明,当PDMS和SiO2用量均为2%时,纸张表面的水接触角达到最大值170?,滚动角最小值为1?,聚合物将SiO2固定在纸张纤维上,使其表面呈现微纳米粗糙结构.超疏水性源于这种疏水粗糙表面下积蓄的空气对液滴浸润的抑制.制得的PFEK/PDMS/SiO2喷涂纸经过40个摩擦周期或12次对折测试后,其水接触角仍达到150°以上,能够维持超疏水性能,并具有较好的机械稳定性.拉伸测试表明,涂层将普通纸张的拉伸强度从10.1 MPa增强到37.8 MPa,在水中浸泡15 min后,该喷涂纸的拉伸强度为25 MPa,仍具有较好的力学性能.另外,PFEK/PDMS/SiO2喷涂纸能够抵抗黏稠泥土的污染,表现良好的自清洁性能.  相似文献   
3.
Barium strontium alumino silicate (BSAS); (Ba0.6Sr0.4Al2Si2O8) was synthesized through solid state reaction between BaCO3, SrCO3, Al2O3 and SiO2 subjected to wet milling in isopropanol for about 24 h. The sequence of the solid state reaction was studied by subjecting to DG/DTG from room temperature to 1550 °C. The crystallographic phase evolution was confirmed by X-ray diffraction of the powders calcined in the range 1000 to 1300 °C for 2 h. The monoclinic celsian phase obtained at 1300 °C, pelletized through uniaxial pressing was sinterable to 67 to 78% density in the temperature range of 1300 to 1500 °C. The density improved to 75 to 94% after ball milling for 76 h, while ZrO2 addition further improved the density by 2%. The celcian phase of BSAS was dispersed in isopropyl alcohol, milled for about 24 h and spray coated on to plain SiC and mullite precoated SiC substrates. Sintering of coated samples and characterization for weight gain/loss, microstructure, scratch test prove that mullite + BSAS coating is more effective than single layer coating of BSAS on SiC substrates.  相似文献   
4.
本文在环氧涂料中添加玄武岩鳞片,提高其防腐蚀性能。针对玄武岩鳞片的团聚问题,通过机械力化学改性工艺,采用正硅酸四乙酯、HY-311型钛酸酯偶联剂、E-44型环氧树脂对玄武岩鳞片进行杂化包覆,结果表明,杂化包覆后玄武岩鳞片的沉降时间从2h提高至96 h。杂化包覆玄武岩鳞片添加量为20%涂层的性能最优,附着力为13.40 MPa,耐盐雾时间为2000 h,在3.5%NaCl溶液中浸泡2000 h后,0.01 Hz的阻抗模值仍然有5.15×109 Ω·cm2。  相似文献   
5.
A numerical model is developed for surface crack propagation in brittle ceramic coatings, aiming at the intrinsic failure of rare-earth silicate environmental barrier coating systems (EBCs) under combustion conditions in advanced gas turbines. The main features of progressive degradation of EBCs in such conditions are captured, including selective silica vaporization in the top coat due to exposure to water vapor, diffusion path-dependent bond coat oxidation, as well as crack propagation during cyclic thermal loading. In light of these features, user-defined subroutines are implemented in finite element analysis, where surface crack growth is simulated by node separation. Numerical results are validated by existing experimental data, in terms of monosilicate layer thickening, thermal oxide growth, and fracture behaviors. The experimentally observed quasi-linear oxidation in the early stage is also elucidated. Furthermore, it is suggested that surface crack undergoes rapid propagation in the late stage of extended thermal cycling in water vapor and leads to catastrophic failure, driven by both thermal mismatch and oxide growth stresses. The latter is identified as the dominant mechanism of penetration. Based on detailed analyses of failure mechanisms, the optimization strategy of EBCs composition is proposed, balancing the trade-off between mechanical compliance and erosion resistance.  相似文献   
6.
Shape memory polyurethanes (SMPUs) have generated great attention because of their unique properties. These properties are result of a particular molecular structure consisting of flexible molecular chains with low glass transition temperatures alternating with hard urethane segments. In this field, bisphenol A (BA) has been used for a long time as chain extender due to the good properties of the obtained SPMU materials. Nevertheless, the high toxicity of this compound has caused a high decrease on its use. For this reason, it has been selected a lower toxicity compound, bisphenol A ethoxylate (BAE). In this work, it is described a new SMPUs based on BAE and the influence of the hard segment on the thermo-mechanical properties and shape memory capacity. For that, both the proportion of the components and the diisocyanate employed (2,4-toluene diisocyanate (TDI), 4,4′-methylene bis(phenylisocyanate) (MDI) or a TDI/MDI mixture) have been modified. Then, depending on the molecular architecture achieved, the polyurethanes present different properties, which were studied by different techniques, such as thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and dynamic-mechanical thermal analysis (DMTA). It has been observed that glass transition temperature (Tg) increases as the hard phase content in the PU samples increases. In addition, Tg-MDI > Tg-MDI-TDI > Tg-TDI, so it is possible to control the Tg of the material, that is, shape memory transition temperature varying the diisocyanate. Finally, the shape memory capacity of the PUs was evaluated by thermo-mechanical analysis (TMA). All the synthesized PUs have shown good shape memory effect with fixation ratios up to 80% and recovery ratios close to 100%.  相似文献   
7.
Up to now, it is a major challenge to protect leading edge of the blades from solid particle erosion. Herein, we propose a structure optimization strategy to fabricate non-woven (NW) enhanced thermoplastic polyurethane nanocomposite films (thermoplastic polyurethane [TPU] - NW@G/Cx) with “sandwich - like” structure by hot pressing technology. TPU NW/graphene nanoplates/carbon nanotube (NW@G/Cx) interlayer film were first fabricated by spraying method. Then the interlayer film was laminated between TPU films to fabricate nanocomposite films. Such prepared TPU - NW@G/Cx film shows excellent solid particle erosion resistance and high-tensile strength. For example, the “steel-and-mortar” structure of NW fabric in TPU film results in high-tensile strength of 45 MPa and storage modulus of 21.2 MPa for TPU - NW@G/C1.0, increasing by 25% and 171% compared with original TPU film (35 MPa, 8 MPa), respectively. In addition, compared with pure TPU film, the “sandwich - like” structure endows TPU - NW@G/C1.2 with excellent solid particle erosion resistance and the thermal conductivity (0.251 W/m·K). These superior properties extends application of the TPU - NW@G/Cx film on wind turbine blades.  相似文献   
8.
为研究轴表面类金刚石(DLC)涂层对滑动轴承承载性能的影响,利用滑动轴承实验台测试轴线对中及倾斜工况下灰铸铁、铝合金和聚酰亚胺(PI)涂层轴承分别与40Cr钢轴和DLC涂层轴配合时的轴心轨迹和极限载荷,并测试3种材料与40Cr钢和DLC涂层的摩擦因数。结果表明:相较与40Cr钢配合,灰铸铁和铝合金与DLC涂层配合时摩擦因数减小,重载下轴承偏心率减小,轴线对中工况下灰铸铁轴承的极限载荷超过10 MPa,铝合金轴承的极限载荷增大到7.8 MPa(增大1.1倍),轴线倾斜工况下轴承抱死失效时边缘变形增大;但重载下PI涂层与DLC涂层配合时摩擦因数增大,轴线对中工况下轴承极限载荷减小至3.6 MPa(减小44%),轴线倾斜工况下轴承抱死失效时边缘变形减小。  相似文献   
9.
In this study,nano-sized SnO_2 decorated on carbon cloth(SnO_2/CC) is prepared through a simple and facile solid method.The nano-sized SnO_2 is uniformly distributed on the surface of carbon fibers in carbon cloth,providing sufficient free space to relieve volume expansion and reduce electrode pulverization during cycling.The as-prepared SnO_2/CC as a flexible,self-supporting and additive-free anode electrode for sodium-ion/lithium-ion batteries(SIBs/LIBs) can demonstrate outstanding electrochemical performance.SnO_2/CC after annealing at 350℃(SC-350) as an anode for SIBs can deliver a reversible capacity of 0.587 mA h cm~(-2) at the current density of 0.3 mA cm~(-2) after 100 cycles.In addition,when cycling at 1.5 mA cm~(-2),SC-350 can maintain 1.69 mA h cm~(-2) after 500 cycles when used as LIB anode.These results illustrate that the as-prepared SnO_2/CC can be a promising flexible anode material for flexible SIBs/LIBs and provide a simple and practical method for designing new flexible electrode materials.  相似文献   
10.
姬梅梅  朱时珍  马壮 《表面技术》2021,50(1):253-266
高温合金材料凭借其优异的综合性能而广泛应用于航空航天领域热端部件.近年来,随着航空航天技术的不断发展,飞行器的热端部件正逐渐面临着更为严峻和复杂的服役环境,因此对高温合金的耐高温、抗氧化等使用性能提出了更高的要求.表面涂层技术由于具有约束条件少、可设计性强、技术类型和材料的选择空间大、经济环保等优点,成为目前最常用的热防护技术手段之一,具有广阔的应用前景和良好的发展潜力.综述了热障涂层、抗氧化涂层材料的研究进展,主要包括YSZ、稀土锆酸盐、稀土六铝酸盐、氧化物、金属间化合物等,并在此基础上探讨了多种热防护涂层的制备方法、工作原理、适用范围.  相似文献   
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