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《中国稀土学报(英文版)》2022,40(7):1134-1147
In this study, the Bayan Obo rare earth concentrates mixed with Na2CO3 were used for roasting research. The phase change process of each firing stage was analyzed. The kinetic mechanism model of the continuous heating process was calculated. This study aims to recover valuable elements and optimize the production process to provide a certain theoretical basis. Using X-ray diffraction (XRD), Fourier infrared spectroscopy, scanning electron microscopy with energy dispersive spectrometry, the reaction process and the existence of mineral phases were analyzed. The variable temperature XRD and thermogravimetric method were used to calculate the roasting kinetics. The phase transition results show that carbonate-like substances first decompose into fine mineral particles, and CaO, MgO, and SiO2 react to form silicates, causing hardening. Further, REPO4 and NaF can directly generate CeF3 and CeF4 at high temperatures, and a part of CeF4 and NaF forms a solid solution substance Na3CeF7. Rare earth oxides calcined at a high temperature of 750 °C were separated to produce Ce0.6Nd0.4O1.8, Ce4O7, and LaPrO3+x. Then, BaSO4, Na2CO3, and Fe2O3 react to form barium ferrite BaFe12O19; the kinetic calculation results show that during the continuous heating process, the apparent activation energy E reaches the minimum in the entire reaction stage in the temperature range of 440–524 °C, and the reaction order n reaches the maximum, which indicates that the decomposition product REFO significantly impacts the reaction system and reduces the activation energy. The mechanism function is F(α) = [?ln (1?α)]1/3. The reaction order n reaches the minimum in the temperature range of 680–757 °C, and the apparent activation energy E is large. The difficulty of the reaction increases during the final stage. The reaction mechanism function is F(α) = [1?(1?α)1/3]2. Observing the entire reaction stage, the step of controlling the reaction rate changes from random nucleation to three-dimensional diffusion (spherical symmetry). 相似文献
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《Ceramics International》2021,47(23):32641-32647
Multi-components and equimolar rare earth monosilicates, (Y1/3Dy1/3Er1/3)2SiO5, (Y1/3Dy1/3Lu1/3)2SiO5, (Y1/4Dy1/4Ho1/4Er1/4)2SiO5 and (Yb1/4Dy1/4Ho1/4Er1/4)2SiO5, were prepared by solid-state reactions and the following hot-pressing. Dense microstructures with uniform elemental distributions were obtained for all samples. These investigated multi-components monosilicates exhibit low thermal conductivities and similar coefficients of thermal expansion with SiC. Moreover, they exhibit high corrosion resistances in 1400 °C water vapor, especially, four-components (Y1/4Dy1/4Ho1/4Er1/4)2SiO5 and (Yb1/4Dy1/4Ho1/4Er1/4)2SiO5 experienced almost invariable weights after small weight losses during the initial 0.5 h. All those results indicate that multi-components rare earth monosilicates are promising candidates of environmental barrier coatings for SiC/SiC composites. 相似文献
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《Ceramics International》2021,47(24):34721-34731
A series of Sr9Y(PO4)7:Eu3+ and Sr9Y(PO4)7:Eu3+, Gd3+ red-emitting phosphors were prepared via a high-temperature solid-state method, Gd3+ ion was co-doped in Sr9Y(PO4)7:Eu3+ as sensitizer to enhance the luminescence property. The X-ray diffraction results verify that the structure of the as-prepared samples is consistent with the standard Sr9Y(PO4)7 phase. All the Sr9Y(PO4)7:Eu3+ samples show both characteristic emission peaks at 594 nm and 614 nm under near-ultraviolet excitation of 394 nm. The co-doping of Gd3+ significantly improves the luminescence intensity of the Sr9Y(PO4)7:Eu3+ phosphors due to the crystal field environment effect and energy transfer of Gd3+→Eu3+ caused by the introduction of Gd3+, especially Sr9Y(PO4)7:0.11Eu3+, 0.05Gd3+, which emission intensity is higher than that of Sr9Y(PO4)7:0.11Eu3+ by 1.21 times. The color purity and lifetime of Sr9Y(PO4)7:0.11Eu3+, 0.05Gd3+ phosphor are 88.26% and 3.7615 ms, respectively. A w-LED device was packaged via coating the as-prepared phosphor on n-UV chip of 395 nm with commercial phosphors. These results exhibit that the Sr9Y(PO4)7:Eu3+, Gd3+ red-emitting phosphor can be used as a red component in the w-LEDs application. 相似文献
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《Ceramics International》2022,48(2):1642-1658
The conditions for the preparation of the solid solutions of a binary system of barium-strontium titanates with the substitutions in the A-sublattice with the rare-earth elements (REE), including the solid-phase synthesis, mechanical activation and sintering of dispersed-crystalline products by the conventional ceramic technology, were optimized. The presence (absence) of the impurity phases was established depending on the size effect of the REE. The precision X-ray diffraction analysis revealed the features of the phase formation in the studied solid solutions and showed that the “behavior” of the structural characteristics of the solid solutions with the participation of the REE is determined by the limiting conditions of the isomorphism and anion excess of the media under study. An assumption is made about the nature of the formation of a fine-grained landscape of the modified solid solutions, associated with the multicluster structure of the crystallite structure and the formation of the ballast phases during their synthesis. The dependences of the dielectric properties of the solid-state solution on the external influences – temperature, frequency of an alternating electric field and strength of a constant field – have been established. The possibility of choosing on the basis of the obtained data, promising for practical applications of the compositions is shown. 相似文献
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Xiaowu Hu Hua Yang Tiantong Guo Dehua Shu Wenfei Shan Guizhi Li Dongcai Guo 《Ceramics International》2018,44(7):7535-7544
The long afterglow nanomaterials of strontium aluminate co-doped by Eu and Dy have been synthesized by co-precipitation combined hydrothermal method. The effects of hydrothermal time, calcination time, pH value, the amount of aluminum nitrate, activator, co-activator and flux H3BO3 on the fluorescence properties of the product were investigated by means of single factor optimization experiment. Then the orthogonal experiment was employed to obtain the optimal synthesis conditions that are as follows: nDy/nEu = 2.5, tc = 2.5?h, nEu/nSr = 0.02, th = 8?h. Subsequently, the optimal synthesis conditions were verified by three repeated experiments, and the obtained products were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and fluorescence spectrometer. The results showed that the synthesized target products all were the mixed crystal phase of SrAl2O4 and Sr4All4O25. The particles presented regular spherical-like with size ~ 100?nm. The dopants Eu and Dy were confirmed existed in the SrAl2O4 powders. The fluorescence and afterglow data of the target products were better than that in the orthogonal experiment scheme. The primary emission spectra band was in the range of 400–600?nm with characteristic peak located at ~ 460?nm corresponding to the transitions of Eu2+ ions from 4f65d→4f7, and the blue light can be observed by naked eyes. The similar fast-decaying and slow-decaying processes were displayed in all the afterglow curves, and the initial afterglow brightness of the target product is apparently higher than that of products synthesized by the orthogonal experiment. The synthesized target products, which show excellent long afterglow performance, present a great application prospects in the aspects of ceramics, plastics, arts and crafts, ink and coating. 相似文献
10.
针对地震发生后亟需对土石坝群体震害进行快速评估的问题,基于统计数据和MSA方法,提出了土石坝群体震害易损性分析方法。通过分析土石坝群体震害数据,对震损大坝进行等级划分,结合地震破坏损失比和破坏比建立土石坝地震易损性矩阵。并引入MSA方法,建立土石坝群体震害易损性评估模型,计算出四种烈度下易损性参数及易损性曲线和概率,为土石坝群体震害快速评估提供了依据。 相似文献