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1.
首次对茂金属聚丙烯(miPP)/齐格勒-纳塔聚丙烯(ziPP)共混体系的流动性进行了系统的研究。研究发现,在miPP/ziPP共混体系中,miPP含量的变化改变了共混体系的相结构,这种相结构会随着温度和剪切速率的变化而产生明显的变化,从而改变了体系的流动性能,且该共混体系在不同剪切速率下的流动曲线可以分别通过两个模型进行模拟。  相似文献   
2.
The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m?2 and 45 W m?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m?1 to 30.2 MPa and 158 J m?1, respectively. Copyright © 2003 Society of Chemical Industry  相似文献   
3.
HDPE/PS/HDPE-g-PS合金的相容性和力学性能研究   总被引:1,自引:0,他引:1  
用自制接枝共聚物GR-Ⅰ、GR-Ⅱ相容剂研究其对HDPE/PS共混物相容性和力学性能的影响。通过SEM、DMA、DSC和力学性能测试表征,表明在HDPE/PS共混中加入这些相容剂其相容性和力学性能有一定提高  相似文献   
4.
Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH2OH or -NH2, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases.  相似文献   
5.
A modified method is discussed that is based on Farooque and Deshpande's method to obtain polymer–polymer interaction parameters using inverse gas chromatography (IGC) data. In the Farooque and Deshpande method, the ratio of the difference of probe–polymer interaction parameters between two polymers and the probe volume [(χ12 ? χ13)/V1] is used as the abscissa. In the modified method, the ratio [(?2χ12 + ?3χ13)/V1] is used as the abscissa. Experimental data previously reported for a poly(?‐caprolactone)‐polyepichlorohydrin (PCL/PECH) blend and a poly(ethyl acrylate)‐poly(vinyl propionate) (PEA/PVPr) blend are analyzed. It is found that the slopes obtained by the new method had smaller deviations from the theoretical values than the Farooque and Deshpande method. The standard deviations of both slopes and intercepts obtained from the new method are also smaller. Using the new method, the polymer–polymer interaction parameters obtained from the intercept are negative numbers for the PCL/PECH system and very small positive numbers for PEA/PVPr. Explanations are given for the probe and concentration dependency of the polymer–polymer interaction parameters that are generally observed in IGC studies. A new method for selecting the best probe for calculating the interaction parameter is discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 671–680, 2003  相似文献   
6.
A series of polyurethane block copolymers based on hydroxy-terminated polydimethylsiloxane and poly(propylene glycol) soft segments of molecular weights 1818 and 2000, respectively, were synthesized. The hard segments consisted of 4,4′-diphenylnethane diisocyanate and 1,4-butanediol as the chain extender. Samples with different molar ratios were prepared. We tried to synthesize polydimethylsiloxane-based polyurethanes (PDMS-PU) containing a hard block as major fraction and a soft block as minor fraction for preparing toughened rigid systems. After a study of the pure polydimethylsiloxane-based polyurethane and poly(propylene glycol)-based polyurethane (PPG-PU), (mixed polyol)-based block copolymers and blends of PDMS-PU and PPG-PU were synthesized, and characterized by means of differential scanning calorimetry, tensile testing and scanning electron microscopy. In (mixed polyol)-based copolymers and lower hard-segment content blends, macro-phase separation occurred, but blends with higher hard-segment contents showed significant reduction in amounts of phase separation.  相似文献   
7.
综述了高聚物二元共混物及嵌段共聚物熔体的静态流变性,分析了不同共混体系的流动曲线,总结了共混物的流动特性及规律  相似文献   
8.
本文对代数曲面的几何连续拼接作了研究,给出了多个代数曲面的几何连续过渡方法,同时给出了一种基于分片的曲面过渡方法。  相似文献   
9.
电子型/离子型导电高分子共混物   总被引:1,自引:1,他引:0  
顾庆超  李乔钧 《功能材料》1996,27(2):135-138
用苯胺在酸性水溶液中的进行化学氧化聚合合成了能溶于N-甲基吡咯烷酮的高分子量聚苯胺(PAn),并用这种PAn与一种高分子固态离子导体--聚乙二醇聚醚氨酯脲(PEUU)和LiClO4的复合物(PEUU-LiClO4)进行溶液共混制得了具有电子型/离子型两种导电功能的新型高分子共混物。用差示扫描量热法、动态粘弹仪、应力-应变试验、四探针法和交流阻抗谱对这种高分子共混物进行研究。实验结果表明,上述PAn  相似文献   
10.
反应型相容剂含有反应基团,可与含相应基团的聚合物起化学反应,因而在混炼过程中增容。本文系统地介绍各种反应型相容剂的设计、合成、品种和应用。  相似文献   
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