Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.     

Non-steady-state model for kinetics of free radical polymerization, 4. Direct thermal initiation

This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided.     

Effects of mastication on the distribution of molecular weights and on the mechanical properties of native and commercial dental gutta percha (trans-polyisoprene)

Mastication of gutta percha (trans-polyisoprene) resulted in the selective scission of molecules, producing a narrower distribution of lower molecular weights. The mechanical properties of the samples also underwent a significant change due to mastication. The greater the content of incompatible substances (salts and oxides) in commercial gutta percha. the more substantial were these effects. The atmosphere (air, N₂, O₂) in which the experiments were conducted yielded significantly different results. The decrease in molecular weight was far greater in an O₂ atmosphere than under a current of nitrogen or air, owing to the combination of double bonds with O₂.     

The weight vector theory of Coriolis mass flowmeters

In this paper a fuller and clear derivation of the weight vector theory of Coriolis mass flowmeters is given indicating its potential for the prediction of velocity profile effects in both the traditional kind of meter (vibrating tube) and the compact kind (vibrating element inside a duct).     

Study on early warning index of spatial deformation for high concrete dam

Owing to the deficiency in early warning for high concrete dam,a formula was established to characterize the deformation behavior of high concrete dam as a whole.The early warning index of spatial deformation was calculated by low probability principle on the basis of the deformation entropy formula proposed.The steps were as follows.Firstly,the probability method was utilized to define the degree of order and degree of chaos for each survey point.Secondly,the weight distribution among the survey points was...     

因子分析法和熵值法在高校科技创新评价中的应用

在已有研究的基础上总结出了一套科学合理并具有可行性的高校科技创新评价指标体系,并把因子分析法和熵值法应用于高校科技创新评价.首先对高校科技创新评价体系的5个一级指标分别进行因子分析,然后运用熵值法对其确定权重.分析结果表明两种方法的结合使用能够简化分析对象的结构,使评价结果更具科学性、客观性.     

Analogy and duality of texture analysis by harmonics or indicators

According to the classic harmonic approach, an orientation density function (odf)f is expanded into its corresponding Fourier orthogonal series with respect to generalized spherical harmonics, and a pole density function (pdf) into its corresponding Fourier orthogonal series with respect to spherical harmonics. While pdfs are even (antipodally symmetric) functions, odfs are generally not. Therefore, the part of the odf which cannot be determined from normal diffraction pdfs can be mathematically represented as the odd portion of its series expansion. If the odff is given, the even part can be mathematically represented explicitly in terms off itself. Thus, it is possible to render maps ofharmonic orientation ghosts, and to evaluatevariants of mathematical standard odfs resulting in identical pdfs independent of pdf data. However, if only normal diffraction pdfs are known, the data-dependentvariation width of feasible odfs remained unaccessible, and within the harmonic approach a measure of confidence in a solution of the pdf-to-odf inversion problem does not exist.According to any discrete approach, an odff defined on some setG of orientations is expanded into its corresponding Fourier orthogonal series with respect to indicator functions of the elements of a partition ofG, and a pdf defined on the upper (lower) unit hemisphereS ₊ ^{3 3} into its corresponding Fourier orthogonal series with respect to indicator functions of the elements of a partition ofS ₊ ³ . The ambiguity of the pdf-to-odf inversion problem is discussed in terms of column-rank deficiency of the augmented projection matrix. The implication of the harmonic approach to split an odf into auniquely determined and anundetermined part does no longer seem to be reasonable. However, it is possible to numerically determine data-dependent confidence intervals for the Fourier coefficients with respect to the indicator functions which can be immediately interpreted as mean orientation densities within the elements of the partition ofG. Doing so for all Fourier coefficients in the finite series expansion, i.e. for all elements of the partition of the setG, eventually results in the data-dependent variation width of odfs feasible with respect to given pdf data, and to the partitions ofG andS ₊ ³ .Thus it is confirmed that the appearance of orientation ghosts, in particular correlations oftrue andghost orientation components, depends on the representation of an odf. It may be questioned whether in practical applications the implicit assumption of the harmonic method that the even part can be determined uniquely and free of error is generally a reasonable initial condition to develop ghost correction procedures.     

亚麻针织产品的酶整理工艺探讨

为改善亚麻针织物的舒适性能，探讨用生物酶整理工艺来提高其柔软性。选取酶剂浓度、pH值、温度和时间4个因素作为正交实验的因子，进行了四因素四水平的正交实验。通过对实验结果的分析，确定了合理的生物酶整理工艺条件。工艺参数分别为：酶整理温度为50℃，整理液pH值为5，酶剂浓度为2%，整理时间为60min,亚麻针织坯布经过这种优化的酶整理后柔软性改善效果十分显著。     

FEM for evaluation of weight functions for SIF, COD and higher-order coefficients with application to a typical wedge splitting specimen

In the evaluation of accurate weight functions for the coefficients of first few terms of the linear elastic crack tip fields and the crack opening displacement (COD) using the finite element method (FEM), singularities at the crack tip and the loading point need to be properly considered. The crack tip singularity can be well captured by a hybrid crack element (HCE), which directly predicts accurate coefficients of first few terms of the linear elastic crack tip fields. A penalty function technique is introduced to handle the point load. With the use of these methods numerical results of a typical wedge splitting (WS) specimen subjected to wedge forces at arbitrary locations on the crack faces are obtained. With the help of appropriate interpolation techniques, these results can be used as weight functions. The range of validity of the so-called Paris equation, which is widely used in the evaluation of the COD from the stress intensity factors (SIFs), is established.     

高聚物中渗入C_(60)/C_(70)后计算内阻的压力函数法

应用宏观力学模型对高聚物渗入Ｃ６０／Ｃ７０后的微观内阻机理进行力学分析,提出分子滚珠轴承的设想,得出计算内阻的压力函数法和滚滑内阻权函数的概念。