Cobalt oxide nanocomposites and their electrocatalytic behavior for oxygen evolution reaction

In this work, we have described the simple preparation method of cobalt oxide nanocomposites where cobalt oxide nanoparticles were grown on the surface of carbon nanotube, graphene oxide and graphene (Co₃O₄@CNT, Co₃O₄@GO, Co₃O₄@G). The as-grown Co₃O₄@CNT, Co₃O₄@GO, Co₃O₄@G were investigated for H₂O oxidation. The nanoparticles displayed high activity toward oxygen evolution. Further, the stability of the catalysts were tested in alkaline solution, which exhibited good stability. Among all nanoparticles, Co₃O₄@G exhibited higher current density at lower overpotential and also exhibited lower Tafel slope (157.1 mV dec⁻¹) as compared to Co₃O₄@CNT and Co₃O₄@GO. The Co₃O₄@G delivered a current density of 10 mAcm⁻² at 0.8 V (overpotential 535 V versus Ag/AgCl) in 0.1 M KOH solution, which is superior than many electrocatalysts reported for oxygen evolution so far. The good electrocatalytic performance might be due to the structural features of Co₃O₄@G, which cause enhancement of oxygen evolution activity.     

基于改进正弦余弦算法的无线传感器节点部署优化

为了提高无线传感器网络（WSN）的性能，提出了一种基于改进正弦余弦算法（ESCA）的节点部署优化方法。首先，引入双曲正弦调节因子和动态余弦波权重系数，以平衡算法的全局探索与局部开发能力；然后，提出了一种基于拉普拉斯和高斯分布的变异策略，避免算法陷入局部最优。对于基准函数的优化实验结果表明，ESCA相比引力搜索算法、鲸鱼优化算法、基本正弦余弦算法（SCA）及其改进算法具有更高的收敛精度和收敛速度。最后，将ESCA应用于WSN节点部署优化，结果表明其优化覆盖率相比改进粒子群优化算法、外推人工蜂群算法、改进灰狼优化算法和自适应混沌量子粒子群算法分别提高了1.55个百分点、7.72个百分点、2.99个百分点和7.63个百分点，用更少节点便可达到相同目标精度。     

基于正弦高斯混合模型的磁目标通用快速检测

在诸如潜艇等磁目标的探测问题中,被测磁目标信号可能表现出参数待定的磁异信号或极低频磁信号的特征。提出了一种可同时检测参数待定的微弱磁异信号和微弱极低频磁信号的通用快速检测方法。通过抓住磁异信号和极低频磁信号在统计上共同具有的分段类正弦特征,建立了正弦高斯混合模型,实现了对参数待定的磁异信号和极低频磁信号的通用建模。基于正弦高斯混合模型和序贯检测理论构建了一种累积和检测器,实现了对微弱磁异信号和微弱极低频磁信号的通用快速检测,给出了未知模型参数的确定方法,分析了所构建检测器的序贯检测性能。并进一步研究了所构建检测器对不同的微弱磁异信号和微弱极低频磁信号的检测性能。在以地磁为背景的磁目标探测系统实验中,验证了所构建检测器对微弱磁异信号和微弱极低频磁信号的通用性和快速性。实验表明,所构建检测器的信噪比可低至-8 dB,计算量相比于传统检测方法降低4个量级。     

Silicon-silver dendritic nanostructures for the enhanced photoelectrochemical splitting of natural water

We report on the photoelectrochemical (PEC) splitting of natural water (pH 7) using silicon (Si) nanowires fitted with silver (Ag) dendrites (dendritic nanostructures) as working electrodes (photoanodes). A detailed study of the PEC water splitting process was carried out using linear sweep voltammetry, electrochemical impedance spectroscopy (EIS) and Mott-Schottky (M-S) measurements. The measured photocurrent density of 1.7 mA/cm² at an external voltage of ?0.6 V under white light illumination demonstrates the efficient decomposition of natural water using dendritic nanostructures as working electrodes. This decomposition is mainly attributed to a significant strengthening of the effective interface between working electrode surface/water and to a decline in the recombination of photoinduced carriers in the presence of Ag dendrites. We propose that the Schottky barrier between Si and Ag dendritic nanostructures favors enhanced photoinduced charge carrier separation. Photoinduced holes in Si are transferred to Ag dendrites (nano branches and leaves) that serve as a charge sink to effectively carry out the PEC oxidation of water. Photoinduced charge carrier separation enhancement was corroborated by the kinetics of our carrier recombination study. We obtained a reasonably long transient period of 80 s for the photoinduced carriers. EIS results show that the charge transfer resistance (150 Ω) of the dendritic nanostructure surface is low enough to promote interfacial charge transfer. This resistance generated a large carrier concentration of ～1.1 × 10²⁰ cm^?3 at the working electrode/water interface according to an M-S analysis. An applied bias-photon-to-current-conversion efficiency level of roughly 4% is reported, demonstrating the efficient PEC splitting of natural water.     

双级正弦活齿传动系统效率计算与实验研究

通过对双级正弦活齿传动活齿啮合副进行受力分析，推导出了活齿传动系统输出力矩表达式，进而建立了系统传动效率计算公式。运用效率公式对系统传动效率进行分析，得到了参数变化时系统传动效率的变化规律。结果表明：为了提高传动效率，应增大正弦滚道幅值、活齿中心圆周方向旋转半径以及合理分配传动比。研制出了双级正弦活齿传动样机，并进行了传动效率实验，测得实验效率与计算效率接近，验证了理论分析的正确性。     

An investigation of the elastic properties of viscoelastic clusters of particles: A comparison between two methods

Most industrial process lines involve mixing complex dispersions, which can include non-Newtonian liquids and viscoelastic particles. Knowledge of the parameters of these components may provide a key for understanding how dispersions are formed and how equipment should be designed. One parameter is the shear modulus, which describes the ability of particles to resist mechanical stresses. This parameter may play the main role in the mixing process, when a dispersion is formed by the mechanical influence of a rotor (slice or shear in a rotor-stator mixer). In this work, two methods were chosen for measuring the shear modulus: the evaluation method, based on the Warner-Bratzler cut test, and the oscillatory method. Both methods were used for measuring viscoelastic clusters of particles, and the results were adjusted for the purposes of the comparison. The comparison shows that the shear modulus values obtained from Warner-Bratzler are higher than the values obtained from the oscillatory test for the same conditions. This difference can be explained by differences in the mechanical processes during the experiments.     

Pb~(2+)在掺硼金刚石膜电极上的电化学行为

为了充分发挥掺硼金刚石膜(BDD)电极在分析检测工业废水中重金属离子的优势,利用BDD电极作为工作电极,采用线性扫描阳极溶出伏安法测定水溶液中的铅离子,考察了硝酸、硫酸、高氯酸、盐酸4种酸体系对铅离子分析测试的影响。结果发现,在实验室条件下检测铅离子最优的支持电解质体系是硫酸,并且与其他3种酸(硝酸、盐酸、高氯酸)相比,硫酸更加稳定,不具挥发性。     

多反馈有源带通滤波器的分析与设计

本文用线性系统理论对多反馈有源带通滤波器进行了深入的分析,提出了它的传递函数、频率特性以及它对脉冲正弦波信号的零状态响应,并提出了设计方法。     

低分辨率位置传感器永磁同步电机精确位置估计方法综述

伺服电机在装备制造、新能源和家电等领域有着广阔的应用,为得到高精度转子位置信息,通常采用旋转变压器或光电编码器等高分辨率位置码盘,但其价格普遍较高,增加了系统设计成本。而无传感器技术当前还很难全面满足工业及家电等领域的应用要求。低分辨率位置传感器永磁同步电机驱动技术是一种能够保证电机运行性能,同时能有效控制系统成本、提高系统可靠性的转子位置检测技术,受到国内外产业界的广泛关注。介绍开关型霍尔位置传感器的使用方法与工作原理,总结原始霍尔位置信息误差的来源与校正方法;重点讨论基于插值法、同步坐标系滤波器法和观测器法的转子位置/转速估算策略,从提高低分辨率位置传感器电机系统低速性能等方面分析和比较不同估算策略的原理、优缺点、适用范围及应用情况;最后,总结现有研究成果及有待解决的问题。