全文获取类型
收费全文 | 848篇 |
免费 | 20篇 |
国内免费 | 11篇 |
专业分类
电工技术 | 4篇 |
综合类 | 62篇 |
化学工业 | 223篇 |
金属工艺 | 18篇 |
机械仪表 | 25篇 |
建筑科学 | 54篇 |
矿业工程 | 5篇 |
能源动力 | 24篇 |
轻工业 | 96篇 |
水利工程 | 10篇 |
石油天然气 | 11篇 |
无线电 | 141篇 |
一般工业技术 | 84篇 |
冶金工业 | 9篇 |
原子能技术 | 7篇 |
自动化技术 | 106篇 |
出版年
2023年 | 13篇 |
2022年 | 12篇 |
2021年 | 30篇 |
2020年 | 17篇 |
2019年 | 7篇 |
2018年 | 14篇 |
2017年 | 26篇 |
2016年 | 26篇 |
2015年 | 30篇 |
2014年 | 51篇 |
2013年 | 39篇 |
2012年 | 65篇 |
2011年 | 66篇 |
2010年 | 57篇 |
2009年 | 67篇 |
2008年 | 63篇 |
2007年 | 57篇 |
2006年 | 45篇 |
2005年 | 40篇 |
2004年 | 24篇 |
2003年 | 23篇 |
2002年 | 20篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 9篇 |
1996年 | 9篇 |
1995年 | 9篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有879条查询结果,搜索用时 17 毫秒
1.
Baobab fruit shell (BFS), a renewable bio-waste from Malawian baobab tree was used as a precursor for the production of a low-cost activated carbon to remove methylene blue (MB) from aqueous solution. Parameters such as contact time, initial methylene blue concentration, adsorbent dose and temperature were studied. The adsorption process can be well described by both Langmuir isotherm and the pseudo-second-order kinetics. The maximum monolayer adsorption capacity of MB dye was ca. 334.45 mg/g. The negative value of the Gibb’s free energy and positive value of adsorption enthalpy showed the spontaneous nature and endothermic nature of the adsorption process, respectively. 相似文献
2.
Minli Yu Ke Wang Harrie Vredenburg 《International Journal of Hydrogen Energy》2021,46(41):21261-21273
The primary aim of this study is to provide insights into different low-carbon hydrogen production methods. Low-carbon hydrogen includes green hydrogen (hydrogen from renewable electricity), blue hydrogen (hydrogen from fossil fuels with CO2 emissions reduced by the use of Carbon Capture Use and Storage) and aqua hydrogen (hydrogen from fossil fuels via the new technology). Green hydrogen is an expensive strategy compared to fossil-based hydrogen. Blue hydrogen has some attractive features, but the CCUS technology is high cost and blue hydrogen is not inherently carbon free. Therefore, engineering scientists have been focusing on developing other low-cost and low-carbon hydrogen technology. A new economical technology to extract hydrogen from oil sands (natural bitumen) and oil fields with very low cost and without carbon emissions has been developed and commercialized in Western Canada. Aqua hydrogen is a term we have coined for production of hydrogen from this new hydrogen production technology. Aqua is a color halfway between green and blue and thus represents a form of hydrogen production that does not emit CO2, like green hydrogen, yet is produced from fossil fuel energy, like blue hydrogen. Unlike CCUS, blue hydrogen, which is clearly compensatory with respect to carbon emissions as it captures, uses and stores produced CO2, the new production method is transformative in that it does not emit CO2 in the first place. In order to promote the development of the low-carbon hydrogen economy, the current challenges, future directions and policy recommendations of low-carbon hydrogen production methods including green hydrogen, blue hydrogen, and aqua hydrogen are investigated in the paper. 相似文献
3.
Degree based topological indices are being widely used in computer-aided modeling, structural activity relations, and drug designing to predict the underlying topological properties of networks and graphs. In this work, we compute the certain important degree based topological indices like Randic index, sum connectivity index, ABC index, ABC4 index, GA index and GA5 index of Book graph Bn and Stacked book graph Bm,n. The results are analyzed by using edge partition, and the general formulas are derived for the above-mentioned families of graphs. 相似文献
4.
为给纺织行业在纺织品贸易和质量控制等方面优选色差公式提供参考,研究了3个重要的和1个最新色差公式的色差均匀性,借助国际上色样多、视觉等距性好的汉风色典,利用X-Rite测色仪测试近2万个色样的色度参数,然后分别从向度、彩度、浓度3个方向选取3万多对相邻色样,采用MatLab编程计算4种色差并统计分析其均值、不匀率和性能因子。结果表明:不同方向不同评价指标所得结果不尽相同;在色差均匀性方面,CAM16-UCS最好,CIEDE2000(2∶1∶1)略优于CMC(2∶1),且二者明显优于CIELAB;在色差大小方面由小到大依次为CIEDE2000(2∶1∶1)、CMC(2∶1)、CAM16-UCS、CIELAB。 相似文献
5.
Y.F. Gomes Jun Li K.F. Silva A.A.G. Santiago M.R.D. Bomio C.A. Paskocimas M.A. Subramanian F.V. Motta 《Ceramics International》2018,44(11):11932-11939
In this paper, a new synthetic pathway is proposed for the system YIn1-xMnxO3, a bright blue inorganic pigment, discovered in 2009. Blue pigment samples with increasing concentration of Mn3+ (x?=?0.08, 0.12 and 0.16) were prepared using the complex polymerization method (CPM) and compared with those synthesized via solid state reaction. All powders, the amorphous precursor from CPM and the starting materials for solid state method, were calcined at 1000, 1100, 1200 and 1300?°C for 12?h, and the resulting blue pigments were characterized by X-ray diffraction (XRD), colorimetric system CIE L*a*b* and Near infrared (NIR) reflectance measurements. XRD patterns and Rietveld Refinement show that the lowest temperature at which single hexagonal phase (isostructural to YInO3) is formed is 1000?°C for CPM method and 1300?°C for conventional solid state method, respectively. The L*a*b* values demonstrate that the coloration of powders prepared by CPM exhibit temperature dependence below 1300?°C, a color shade shift from grayish blue to intense deep blue is observed when heating the samples from 1000 to 1300?°C. Blue pigments obtained by CPM have smaller particle size due to low temperatures and excellent near-infrared reflectance comparable to those by solid state method. Thus, providing advantages for application process and energy efficiency. 相似文献
6.
Philippe Colomban Marino Maggetti Antoine d’Albis 《Journal of the European Ceramic Society》2018,38(15):5228-5233
A Raman study of a Sèvres soft paste (frit) porcelain plate allowed the identification of both the crystalline and amorphous phases. Cristobalite and pseudowollastonite gave main Raman signatures in the body where also tridymite, amorphous alkali silicate glass and lead arsenate apatite were detected. Na0.4K0.1Ca0.5Pb4(AsO4)3 lacunar apatite is identified as opacifier in blue and green overglaze enamel. Pb-Sb-reach pyrochlore (Naples Yellow) pigment was found in yellow and green overglaze enamels. The orange hue is obtained by superposing a hematite bearing red paint stroke over the yellow. These results are compared to those previously obtained by detailed OM, SEM, XRD and XRF analyses. Some of the phases identified by XRD (quartz, tridymite) are hardly detected by Raman and vice versa cristobalite was not found by XRD, most probably due to its low amount. 相似文献
7.
《Ceramics International》2020,46(8):12138-12144
A new mechanoluminescent phosphor was developed from a sodium (Na) superionic conductor (NASICON)-structured Na3Sc2(PO4)3:Eu2+ phosphor that is known for its self-healing properties. The compound that crystalized assuming monoclinic C2/c symmetry was found to be blue-emitting, with no noticeable persistent luminescence. Thermoluminescence analysis showed that the phosphor had two prominent distinct thermal emission bands corresponding to the high-temperature β- and γ-phases of the composition. The mechanoluminescence properties of the material that does not have any persistent luminescence at room temperature were investigated by imparting impulsive strain. The compound on charging with 365 nm radiation was found to have significant mechanoluminescent emission originating from shallow defects present in the β-phase of composition that formed by the stress-induced phase transition process. Its emission characteristics and temporal behavior were investigated by varying the impact velocity. 相似文献
8.
Efficient and fully solution-processed blue organic light-emitting diodes (OLEDs) based on fluorescent small-molecule and methanol/water soluble conjugated polymer as electron-injection material are reported. The emitting layer is 3,6-bis(9,9,9′,9′-tetrakis (6-(9H-carbazol-9-yl)hexyl)-9H,9′H-[2,2′-bifluoren]-7-yl)dib-nzo[b, d]thiophene 5, 5-dioxide (OCSoC) with a blue-fluorescent small-molecule, and a methanol/water soluble polymer poly[(9,9-bis(30-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctyl-fluorene)] (PFN) acted as electron-injection layer (EIL). All the organic layers are spin-coated from solution. The multilayer device structure with emitting layer/electron-injection layer is achieved by solution-processed method without the dissolution problem between layers. The performances of the devices show that the maximum luminous efficiency of the multilayer device is increased about 43%, compared to the single-layer device. PFN acting as the EIL material plays a key role in the improvement of the device performance when used in solution-processed small-molecule OLEDs. 相似文献
9.
Conventional thermally activated delayed fluorescence (TADF) molecules achieve small energy differences between the lowest singlet and triplet excited states (ΔEST) by enhancing the intramolecular charge transfer, which inevitably leads to a wide emission spectrum and low fluorescence rate. Here, we prepared a deep blue TADF molecule via a small ΔEST pyridine-phenol fluoroboron complex as the acceptor. The small ΔEST is maintained when carbazole donors are attached to the 4-position of the phenyl rings in the fluoroboron complex. Benefiting from the strong electron coupling between the donor (D) and acceptor (A) moieties, the compound Cz-4-BF exhibits a high fluorescence rate of 4.8 × 108 s−1 and a small D-A dihedral angle change in the excited state. Consequently, a photoluminescence (PL) quantum yield of nearly 100% and a PL spectrum with full-width at half-maximum (FWHM) < 60 nm were obtained in solution and low-concentration doped films. A TADF-sensitized fluorescence (TSF) device containing Cz-4-BF achieves an external quantum efficiency of 21%, which is higher than the devices employing classical fluorescent emitters and multiple resonance-type TADF emitters. The Cz-4-BF-based TSF device shows significantly improved color coordinates of (0.14, 0.10) versus a control device without Cz-4-BF. 相似文献
10.
A strongly electron deficient and high triplet energy host for blue emitters was developed by decorating a dibenzofuran modified biphenyl backbone structure with multiple CN units. Two hosts, 6,6′-bis(6-cyanodibenzo[b,d]furan-4-yl)-[1,1′-biphenyl]-3,3′-dicarbonitrile(CNDBF1) and 2,2′-bis(6-cyanodibenzo[b,d]furan-4-yl)-[1,1′-biphenyl]-4,4′-dicarbonitrile(CNDBF2), were derived from the CN decoration strategy for application in blue organic light-emitting diodes requiring high triplet energy host. They showed high triplet energy above 2.79 eV and acted as the electron transport type host based on the strong electron deficiency. The mixture of the CNDBF1 and CNDBF2 hosts with a hole transport type 3,3′-di(9H-carbazol-9-yl)-1,1′-biphenyl host performed as the exciplex host of a blue phosphor and accomplished high external quantum efficiency of 22.7% in the blue phosphorescent organic light-emitting diodes. 相似文献