Process parameters influence on zone refining and thermodynamics analysis of 1,2-diphenylethane

Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature. The effect of varied zone size, temperature difference between the melt and ambient frozen environment, number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining. The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%-0.2% than that with constant zone size. The product purity increases with temperature difference between the melt and ambient frozen environment. The appropriate temperature difference is adopted 50℃. The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%-0.43% than that with 1 molten zone. In addition, the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined.     

矿山深部卸压技术研究现状及展望

随着国内外矿山进入深部开采阶段，高应力特征显现，岩爆、冲击地压等地质灾害频发，增加了深部矿产资源开采的难度。卸压技术能够有效解决矿山深部局部高应力集中并防治矿山动力地质灾害，因而受到国内外学者的广泛关注。通过梳理国内外卸压技术研究现状，归纳总结了主要卸压技术（包括水力卸压、钻孔卸压、卸压槽/卸压巷道和爆破卸压等）及常用的研究手段（相似材料模拟和数值模拟），对比分析了各类卸压技术的优缺点。结合当前金属矿山深部开采的实际需求，提出未来卸压技术理论研究的若干重要方向：（1）深化理论研究，通过经验公式来确定合理的卸压参数，从而指导生产实践；（2）相比其他卸压技术，爆破卸压的应用前景广阔，同时多种卸压方法相结合是未来深部矿山开采的有效措施；（3）数值模拟在卸压技术及参数确定方面的优势显著，未来卸压技术研究应充分了解现场复杂地质条件，结合相似模拟、数值模拟与现场试验，提出一套适用于金属矿山深部开采实际的卸压技术方案。     

缓冲套对停止器挡杆防撞性能影响的测试与分析

对停止器挡杆的碰撞力进行了计算,在此基础上,对缓冲套对停止器挡杆防撞性能的影响进行测试与有限元分析。通过测试与分析确认,带聚氨酯缓冲套的停止器挡杆,碰撞力小,碰撞时间短,强度满足要求,且挡杆中铜套的变形小。在不考虑其它因素的前提下,优先选用带聚氨酯缓冲套的停止器挡杆。     

热稳定处理时间对TNM合金糊状区组织的影响

利用真空非自耗电弧炉制备了TNM(Ti-44Al-4Nb-1Mo-0.1B at.%)合金锭,研究其铸态组织形貌,并利用Bridgeman定向凝固装置对TNM合金进行热稳定处理实验,分析热稳定处理时间对合金定向凝固糊状区的影响。实验结果显示,其铸态组织是以(α₂+γ)片层团为主体,网络状B2相、细小的γ相及硼化物分布于片层团间的近片层组织。热稳定处理时,热稳定时间越长、TNM合金固/液界面越平整,界面前沿温度场和溶质场趋向均匀,但从减少坩埚对熔体的污染的角度考虑,热稳定处理时间不宜过长,30~60 min的热稳定时间即可提供平整的定向凝固启动界面。 热稳定处理影响着TNM合金固/液界面附近固液两相中Al元素的分布,进而影响硼化物的分布。     

Efficiency improvement of CIGS solar cells using RF sputtered TCO/Ag/TCO thin-film as prospective buffer layer

In this paper, TCO (Transparent Conductive Oxide) incorporating ultrathin Ag intermediate film is proposed as a new buffer layer to enhance the efficiency of CIGS thin-film solar cells (TFSCs). In this regard, versatile multilayer thin-films based on ZnO/Ag/ZnO and ITO/Ag/ITO structures were deposited on glass using RF magnetron sputtering technique to determine the optoelectronic parameters of the multilayer structures. The elaborated samples were then characterized using SEM, EDS, XRD, and UV–Visible absorption spectroscopy techniques to investigate the structure morphological, optical, and electronic properties. The deposited multilayer thin-films showed amorphous-like structure and exhibited a broadband absorbance over the visible and even NIR spectrum ranges, indicating its potential application as alternative buffer layers for thin-film solar cells. In this context, TCO/Ag/TCO/CIGS solar cells have been numerically investigated using the deposited multilayer optoelectronic properties. It was revealed that the estimated efficiency of the ZnO/Ag/ZnO/CIGS-based solar cell could reach 18.5% with an open circuit voltage of 0.7 V and a short-circuit current density of 34.8 mA/cm². The performances exhibited by the investigated solar cell demonstrated that ZnO/Ag/ZnO multilayer can be used as an alternative to the conventional CdS buffer layer for developing high-performance non-toxic CIGS solar cells.     

“武汉永清商务综合区（一期）”规划方案国际征集综述

介绍“武汉永清商务综合区(一期)”规划设计方案国际征集的背景、组织工作、应征方案及评选结果,并从整体功能定位、交通组织、历史保护和城市设计4方面对方案进行点评。指出,作为体现新世纪武汉城市形象的窗口地区,永清商务综合区规划应深入挖掘该地区的历史和环境资源,强调土地开发与建设项目的有效衔接。     

新城市主义居住模式——大连环宇阳光科技广场规划设计

在把大连建设成“现代化国际城市”的大目标指导下，经济技术开发区的建筑形式日渐多样和新颖，但目前给人们的印象与理想还有很大距离，尤其在大连环宇阳光科技广场所赴的工业厂区，建筑物比较低接平板，从城市更新和发展的角度，这里需要出现突破性的改现。新城市主义的设计观念在于强调邻里感、场所精神，整体、有机、持续发展，主张恢复城市人文价值以提高城市生活品质。这个理论为我们建设新型城市提供了有力的依据和方法。     

浅析淮海经济区发展

本文首先界定了淮海经济区的范围,从经济、产业发展等多个方面分析了淮海经济区在我国的重要地位及其发展中存在的主要问题．在此基础上分别探讨了构建徐州都市圈与淮海省的可能性与条件,最后提出了加速淮海经济区发展的一些具体措施。     

Density effects on activated sludge zone settling velocities

A recently developed method to manipulate biomass density based on the addition of synthetic microspheres was used to isolate density effects on zone (hindered) settling velocities in samples from full-scale activated sludge plants over a range biomass densities and concentrations. Settling velocities increased by as much as a factor of five as density was increased by microsphere addition. The effects of density on the Vesilind sedimentation model parameters (V=V(o)e(-kX) , where V is the settling velocity, X is the biomass concentration, and V(o) and k are constants) were evaluated. The parameter V(o) was positively correlated with density for values greater than approximately 1.02 g/mL, while k values were approximately constant in this range. New models were developed for settling velocity as a function of both density and biomass concentration, and these may be useful for future incorporation with clarifier models to improve predictions of system performance, particularly when biomass characteristics known to affect density are variable, such as polyphosphate and nonvolatile suspended solids content.     

开放性带状生态旅游区规划研究——以西藏尼洋河生态观光旅游带为例

随着生态旅游的发展，生态旅游区规划越来越需要新理论的支持和指导。西藏尼洋河生态观光旅游带的规划运用生态系统健康理论，把河流、植被、村镇、交通等作为整体规划关注对象，注重自然生态系统与人文生态系统的健康，在空间布局的基础上注重各个生态子系统的协调平衡，力求实现生态健康与旅游发展并重的目标。