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1.
《International Journal of Hydrogen Energy》2022,47(22):11658-11668
In an attempt to optimize the properties of FeCoNi coating for planar solid oxide fuel cell (SOFC) interconnect application, the coating composition is modified by increasing the ratio of Fe/Ni. An Fe1·5CoNi0.5 (Fe:Co:Ni = 1.5:1:0.5, atomic ratio) metallic coating is fabricated on SUS 430 stainless steel by magnetron sputtering, followed by oxidation in air at 800°C. The Fe1·5CoNi0.5 coating is thermally converted to (Fe,Co,Ni)3O4 and (Fe,Co,Mn,Ni)3O4 without (Ni,Co)O particles. After oxidation for 1680 h, no further migration of Cr is detected in the thermally converted coating region. A low oxidation rate of 5.9 × 10?14 g2 cm?4 s?1 and area specific resistance of 12.64 mΩ·cm2 is obtained for Fe1·5CoNi0.5 coated steels. 相似文献
2.
《Advanced Powder Technology》2022,33(12):103879
Heat transfer within ceramic feedstock powders is still unclear, which impedes optimization of the thermal and mechanical properties of the thermal sprayed coatings. The microspheres (yttria-stabilized zirconia YSZ and lanthanum zirconate LZO) were prepared via the electro-spraying assisted phase inversion method (ESP). The thermal properties of the two ESP microspheres and a commercial hollow spherical powder (HOSP) were investigated by using theoretical, experimental, and simulation methods. Thermal conductivity of the single microsphere was estimated via a novel nest model that was derived from the Maxwell-Eucken 1 and the EMT model. Thermal conductivity of a single YSZ/LZO-ESP microsphere prepared at 1100–1200 °C was within 0.36–0.75 W/m K, which was ~ 20 % lower than that of a single YSZ-HOSP microsphere with a similar porosity. Heat flux simulation showed that high tortuosity around the multi-scaled voids of the ESP microsphere led to a more efficient decrease in thermal conductivity compared with total porosity. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(70):30291-30302
Fuel cells (PEMFCs) are considered a clean alternative for the production of electricity. To improve their efficiency, it is necessary to understand the transport phenomena that determine their performance. This work analyzes the effective diffusion coefficients in the gas diffusion and catalyst layers (GDL and CL, respectively) based on theories such as effective medium approximation and percolation theory of a 3D multiphase nonisothermal model of a single channel PEMFC. We calculate polarization curves with different effective diffusion models and tortuosity factors m, n using OpenFOAM. The best model that approaches to experimental data is the Tomadakis-Sotirchos model with n = 4.0. The exponent m that represents the tortuosity due to the geometry has a high impact on the polarization curve construction compared to the exponent n. High values of diffusibility do not mean high values of current densities showing that there are other phenomena involved, such as water flooding. 相似文献
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5.
针对热液白云岩展布非均质性强的问题,开展基底断裂与茅三段沉积演化关系研究,分析断裂样式与白云岩分布关系,建立沉积演化模式,预测白云岩的分布。研究结果表明:茅三段可划分为5个小层,1~3小层为白云岩发育主要时期,4~5小层为台地均一化时期,不发育白云岩;15-1、15-2和16号基底断裂控制了早期“台-洼”相间的沉积地貌,断裂附近的地貌高部位为生屑滩发育有利部位,为白云岩的发育提供物质基础;15-1、15-2号基底断裂样式为花状,周边生屑滩白云石化程度高,为白云岩发育最有利区;16号基底断裂为直立状,附近白云石化发育程度较低,为白云岩发育较有利区。研究成果可为热液白云岩领域的进一步勘探提供指导依据。 相似文献
6.
Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature. The effect of varied zone size, temperature difference between the melt and ambient frozen environment, number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining. The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%-0.2% than that with constant zone size. The product purity increases with temperature difference between the melt and ambient frozen environment. The appropriate temperature difference is adopted 50℃. The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%-0.43% than that with 1 molten zone. In addition, the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined. 相似文献
7.
Tianqi Hou Zirui Jia Ailing Feng Zehua Zhou Xuehua Liu Hualiang Lv Guanglei Wu 《材料科学技术学报》2021,68(9):61-69
To solve the electromagnetic pollution,herein,a CoFe2O4/C/PANI composite was developed by a green route,which was constructed with spinel of metal oxide,graphitized carbon and conductive polymer composites.Benefiting from the designable interfaces and increased dipoles,the microwave dielectric response capability can be boosted significantly and resulted in the enhanced microwave absorbing performance.As revealed by the reflection loss curve,the minimum reflection loss(RLmin) reached-51.81 dB at 12.4 GHz under a matched thickness of 2.57 mm.At 2.5 mm,the effective absorbing band covered 8.88 GHz,suggesting the desirable wideband feature.In our case,the method of utilization of a novel green way to fabricate multiple-component EM absorber can be a promising candidate for high-performance EM absorber. 相似文献
8.
《Journal of Great Lakes research》2022,48(6):1498-1504
This paper describes the creation of an environmentally conscious community group, the Great River Network, and the role that it has played in the remediation and restoration process as part of one of the Great Lakes environmental programs. Community engagement was initiated in the region as part of the Remedial Action Plan for the Area of Concern at Cornwall/Akwesasne/Massena within the Upper St. Lawrence River. The community group formalised as a network representing 50+ organisations in response to perceived inadequacies in the agency of the community to respond to new environmental concerns outside of the scope of the existing programs. As a grass-roots initiative, the Great River Network has successfully completed remediation and restoration actions of significant value to the environment. These include a series of river clean ups (>42 tonnes of garbage removed), fish habitat restoration, and addressing shoreline erosion issues. Success has been achieved through partnering with a range of organisations, including Indigenous, non-profit, governmental, Conservation Authorities, businesses and industry partners. The action-oriented approach showcases how remediation and restoration led by, and embedded in, the community can result in true revitalization. A simplified framework for adaptive management practices for remediation and restoration efforts that lead to revitalization, including knowledge translation, is proposed. This case study highlights the transformational opportunities that remediation and restoration initiatives can bring. In this instance, the process is intensely local and cooperative and lays the foundation for moving towards a collective impact approach for the region. 相似文献
9.
《Egyptian Journal of Petroleum》2019,28(4):377-382
Four hydrocarbon-base gasolines (BG) were formulated from the local refinery streams; isomerate, reformate, and light naphtha. The formulations were enriched in reformate. Each of these BG formulations was blended with 10 vol% of anhydrous ethanol. From ASTM-D86 distillation data, eight distillation curves were constructed and the trend line equations of these distillation curves were developed. Also, the area under each distillation curve (AUDC) was calculated through calculus definite integration technique. Subsequently, the area due to azeotrope formation (ADAF) for each BG-ethanol blend was estimated. In this paper, the influence of increasing reformate proportions on the created positive azeotrope, was studied. Also the influence of increasing reformate proportions on vapor pressure, Temperature for the vapor-liquid ratio of 20, T50 and octane number was studied. The results show that the R2 values of the distillation curve equations prove the reliability of the fits. Also, increasing reformate proportion in the fuel blend improves the octane number while increasing reformate proportion decreases the volatility of the fuel formulation. 相似文献
10.
通过于都县黄麟地区1:5万土地质量地球化学调查,基本査明该地区农作物中硒元素及其他元素的地球化学特征,综合分析岀绿色富硒土壤分布,并优选出绿色富硒地块,为特色农产品基地建设的开发与利用提供理论依据。 相似文献