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排序方式: 共有3807条查询结果,搜索用时 15 毫秒
1.
Spinels with the generic chemical formula AB2O4 have potential applications in nuclear energy and batteries. In both cases, their functionality is related to mass transport through the crystal. Here, using long-time atomistic simulations, we examine the impact of the cation structure on interstitial transport in two spinel chemistries, inverse MgGa2O4 and double MgAlGaO4. We emphasize two aspects of the transport properties: the unit mechanisms that are described by individual barriers, for which we introduce pole-figure-like plots, and the aggregate behavior of those unit mechanisms. Compared to previous work on normal spinels, we find that inversion significantly reduces the rate of interstitial transport in these structures and has an impact on the stability of defects as they move through the lattice. In particular, B cation interstitials are found to be kinetically stable only in the inverse MgGa2O4. These results provide new insight into relationship between structure, chemistry, and transport in spinels. 相似文献
2.
Monika Bosacka Anna Blonska-Tabero Elzbieta Filipek Jana Luxová Petra Šulcová 《Ceramics International》2021,47(17):24607-24614
A new pyrophosphate(V) of the formula Co5Cr2(P2O7)4 was obtained in the system Co2P2O7–Cr4(P2O7)3 as a result of solid-state reactions taking place between different reactants. The new compound crystallizes in the orthorhombic system and belongs to the family of pyrophosphates of the general formula M52+M23+(P2O7)4 and is probably isostructural with Fe52+Fe23+(P2O7)4. Powder diffraction pattern, infrared spectrum and SEM image of the new compound were presented. As a new potential inorganic pigment, Co5Cr2(P2O7)4 was tested for its thermal stability, particle size distribution and colour properties, which were studied both for powder and after introduction into organic matrix and leadless ceramic glaze. The colour of Co5Cr2(P2O7)4 powder was defined as deep grey with the colour coordinates L*/a*/b* = 60.63/-1.42/-3.41 and according to the hue angle (h° = 247.39°) it belongs to the blue region. Co5Cr2(P2O7)4, with its relatively high thermal stability (t m = 1230 ± 10 °C) and appropriate colour properties, is a good candidate to be used as inorganic pigment for colouring of acrylic paints. In the case of leadless glaze, the obtained compound acts as a dye. 相似文献
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4.
Wang Hay Kan Chenxi Wei Dongchang Chen Tao Bo Bao‐Tian Wang Yan Zhang Yangchao Tian Jun‐Sik Lee Yijin Liu Guoying Chen 《Advanced functional materials》2019,29(17)
Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li1.3Ta0.3Mn0.4O2 (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes. 相似文献
5.
主要论述了一种提纯盐湖锂矿和回收含氟碳酸锂的方法。工艺流程:盐湖锂矿(含氟碳酸锂)通过一次水洗涤除去其中所含的大部分可溶性杂质后,按一定配比将其投入到石灰乳料浆中加热到90~95 ℃反应4 h,过滤后得到氢氧化锂溶液,将氢氧化锂溶液在100~120 ℃下进行加压浓缩4 h精制得到钙镁离子和硅含量较低的氢氧化锂溶液;向精制后的氢氧化锂溶液中通入食品级二氧化碳沉锂得到工业级碳酸锂,或继续浓缩制备氢氧化锂;用以上工艺生产得到的工业级碳酸锂通过二次碳化、阳离子交换树脂除去钙镁离子、重结晶可得到硅含量为10×10-6以内的高纯碳酸锂,或浓缩得到钙含量为5×10-6、镁含量为2×10-6以内的单水氢氧化锂。 相似文献
6.
7.
Thanh Bao Nguyen Erwin van der Krabben Clément Musil Duc Anh Le 《International Planning Studies》2018,23(3):310-326
This paper explores how land-based financing mechanisms are currently used in Ho Chi Minh City as a public-private funding strategy. The Land-for-Infrastructure (LFI) mechanism appears as a solution to produce infrastructures. We found that the implementation of the LFI mechanism remains difficult, but eventually can lead to success. By ‘trial-error-transcend,’ the City managed to build two essential roads while the developers received attractive investment opportunities in urban development. This mechanism cannot, however, be seen as a panacea for the local authorities due to constraints to replicate it and potential undesired ‘side effects.’ 相似文献
8.
The efficiency of more than 25% in organic-inorganic hybrid perovskite solar cells has made them very attractive in the pursuit of cheaper alternatives to Si-based devices. However, the stability of the perovskite solar cells was challenging, given their high susceptibility to moisture. Very few reports have emerged in this regard that investigated the influence of introducing large cations into a triple cation perovskite (TC-PVS), with several studies limited to single and dual cation perovskites. Further, the crystallization of TC-PVS on a polymer surface such as PEDOT is not straightforward, and their inclusion in inverted solar cell devices was limited. In this work, we investigated the impact of incorporating Phenyl ethyl ammonium cation into FAMACs triple cation composition. We demonstrated improvements in the crystallinity and more uniform coverage with little to no pinholes and smooth morphology for an optimum PEA amount of 1.67% in the precursor solution. The superior morphology, along with a passivation effect from a quasi 2D phase, led to increased photoluminescence and minority carrier lifetimes. Corresponding inverted photovoltaic devices prepared with PEA showed increased open-circuit voltage from 0.89 V for a control sample to 0.95 V for 1.67% PEA and 0.98 V for 5% PEA, doped devices in an inverted configuration. The efficiency, as a result, increased from 11.27% for a control device to 14.85% for a 1.67% PEA doped device. Further, PEA doped devices showed improved operational and thermal stability attributed to the higher moisture tolerance and light-soaking ability of the PEA doped TC-PVS compared to the undoped TC-PVS. 相似文献
9.
10.
The proposed work involves the multiobjective PSO based adaption of optimal neural network topology for the classification of multispectral satellite images. It is per pixel supervised classification using spectral bands (original feature space). This paper also presents a thorough experimental analysis to investigate the behavior of neural network classifier for given problem. Based on 1050 number of experiments, we conclude that following two critical issues needs to be addressed: (1) selection of most discriminative spectral bands and (2) determination of optimal number of nodes in hidden layer. We propose new methodology based on multiobjective particle swarm optimization (MOPSO) technique to determine discriminative spectral bands and the number of hidden layer node simultaneously. The accuracy with neural network structure thus obtained is compared with that of traditional classifiers like MLC and Euclidean classifier. The performance of proposed classifier is evaluated quantitatively using Xie-Beni and β indexes. The result shows the superiority of the proposed method to the conventional one. 相似文献