金沙江上游水电站应对白格堰塞湖灾害的措施及经验

2018年10月、11月,西藏自治区昌都市江达县白格村两次发生山体滑坡造成金沙江断流并形成白格堰塞湖,给金沙江上游沿岸人民生产生活设施造成巨大安全威胁和超过百亿元的经济损失。华电金沙江上游水电开发有限公司组织所属企业及参建单位快速应对,采取撤离避让、工程防护、人工干预、生产恢复,推动后续处置、风险评估等措施,最大限度减轻了对金沙江上游叶巴滩、拉哇、巴塘、苏洼龙等在建水电站的灾害损失和后续影响,为类似灾害的处置提供借鉴经验。     

西藏水电开发是应对治理揠塞湖的重要举措

西藏区域地质构造发育,又属于高震区,在局部强降雨强降雪等恶劣小气候条件下,自然灾害频发,在高山深谷的江河上尤其容易发生堰塞湖。2018年10月17日凌晨5:00左右,西藏林芝加拉村下游约6km处(大峡谷核心区、无人区)雅鲁藏布江(以下简称“雅江”)左岸发生大规模泥石流,造成干流断流,形成影响很大的雅江加拉村堰塞湖。堰塞湖的治理一直是个世界难题,本文从2018年10月17日治理分析加拉堰塞湖的实践,阐述从水电开发角度,在灾害区上游建设高坝大库拦水调蓄,水库下游再采取截弯取直方式引走来水,作为防治雅江大峡谷河段今后可能出现大型堰塞湖重要治理手段,防止大型堰塞湖造成水淹城乡和溃堰水淹下游灾难的发生,从而达到既推进雅江水电开发,又较好治理了大峡谷河段自然灾害,实现把水电开发建成“功在当代,利在千秋”的减灾防灾工程。     

Anaerobic methane oxidation and aerobic methane production in an east African great lake (Lake Kivu)

We investigated CH₄ oxidation in the water column of Lake Kivu, a deep meromictic tropical lake with CH₄-rich anoxic deep waters. Depth profiles of dissolved gases (CH₄ and N₂O) and a diversity of potential electron acceptors for anaerobic CH₄ oxidation (NO₃^?, SO₄^2?, Fe and Mn oxides) were determined during six field campaigns between June 2011 and August 2014. Denitrification measurements based on stable isotope labelling experiments were performed twice. In addition, we quantified aerobic and anaerobic CH₄ oxidation, NO₃^? and SO₄^2? consumption rates, with and without the presence of an inhibitor of SO₄^2?-reducing bacteria activity. Aerobic CH₄ production was also measured in parallel incubations with the addition of an inhibitor of aerobic CH₄ oxidation. The maximum aerobic and anaerobic CH₄ oxidation rates were estimated to be 27?±?2 and 16?±?8?μmol/L/d, respectively. We observed a difference in the relative importance of aerobic and anaerobic CH₄ oxidation during the rainy and the dry season, with a greater role for aerobic oxidation during the dry season. Lower anaerobic CH₄ oxidation rates were measured in presence of molybdate in half of the measurements, suggesting the occurrence of linkage between SO₄^2? reduction and anaerobic CH₄ oxidation. NO₃^? consumption and dissolved Mn production rates were never high enough to sustain the measured anaerobic CH₄ oxidation, reinforcing the idea of a coupling between SO₄^2? reduction and CH₄ oxidation in the anoxic waters of Lake Kivu. Finally, significant rates (up to 0.37?μmol/L/d) of pelagic CH₄ production were also measured in oxygenated waters.     

First genetically verified occurrence of Ligula pavlovskii outside its native range and characteristics of its infection in Neogobius fluviatilis

In this study, we provide the first genetically verified distribution record beyond its native range of Ligula pavlovskii, a high-impact endoparasite of Ponto-Caspian gobies. According to parasitological surveys, ligulosis was detected for the first time in monkey goby individuals collected from Lake Balaton in 2004, 34 years after the first record of monkey goby in the lake. During a Lake Balaton survey in 2018, we detected tapeworms in 44.4% of the sampled monkey gobies. This prevalence is about two to ten times higher than it was reported from within the native range of the fish hosts. The same survey revealed an uneven spatial distribution of the ligulosis in the monkey gobies inhabiting different shoreline sections of the lake. We assume that the occurrence and recent distribution data of this high-impact endoparasite may provide useful information for potential biocontrol measures of invasive Ponto-Caspian gobies in the future.     

歧口凹陷西南缘沙河街组一段下亚段古环境特征与沉积模式

沙河街组一段下亚段是歧口凹陷重要的页岩油发育层系，为进一步了解该段细粒沉积岩沉积环境、旋回特征和沉积模式，利用地震、测井、录井和系统取心分析资料对目的层位展开综合研究。研究区细粒沉积岩包括长英质页岩、碳酸盐质页岩（白云岩、灰质页岩、白云质页岩）、黏土质页岩和混合质页岩4种类型，混合质页岩、长英质页岩和碳酸盐质页岩占优势；总体为还原-强还原沉积环境，水体盐度较高，主要受陆源碎屑沉积和生物化学沉积作用控制；宽缓湖湾与歧口主凹之间形成高盐度带，受准同生期蒸发浓缩作用，滨-浅湖带高密度富Mg²⁺超咸水在重力作用下，沿着湖底向湖盆内部流动，早期形成的方解石发生白云石化，形成准同生白云岩；岩性组合受旋回控制作用明显，短期反-正旋回转换面之下位置发育一层稳定白云岩或白云质页岩，碳酸盐岩（甜点段）发育于长期旋回内的下降期半旋回，上升期长期旋回主要发育黏土质混合页岩和黏土质页岩（隔板层），进一步可以总结出强陆源碎屑供给区细粒沉积模式和弱陆源碎屑供给区细粒沉积模式。     

离子液体体系卤水提锂的洗涤工艺研究

溶剂萃取法是盐湖提锂的重要工艺方法。采用磷酸三丁酯（TBP）/1-丁基-3-甲基咪唑双三氟甲基磺酰亚胺盐（[C₄mim][NTf₂]）离子液体体系对高镁锂比盐湖卤水中的锂进行萃取分离提取实验,对负载有机相的洗涤和反萃过程进行了研究。萃取实验：在TBP与[C₄mim][NTf₂]体积比为9∶1、相比（有机相与水相的体积比）为2∶1条件下,锂离子与其他离子的分离系数分别为β（锂/钠）=94.70、β（锂/钾）=148.85、β（锂/镁）=131.81。洗涤实验：系统考察了洗涤剂种类及浓度、相比、洗涤次数等因素对杂质离子洗脱率的影响,结果发现氯化锂和盐酸的混合溶液是从负载有机相中洗涤除去杂质离子的有效洗涤剂。洗涤过程适宜条件：洗涤剂中氯化锂浓度为4 mol/L、盐酸浓度为0.5 mol/L,相比为5∶1,洗涤次数为2次。反萃实验：用稀盐酸（1.0 mol/L）对负载有机相进行反萃取,在相比为1∶1条件下,单级反萃率达到97.81%。研究表明,离子液体体系作为一种新型萃取体系,在高镁锂比盐湖卤水中提取锂具有较好的应用前景。     

陶瓷超滤膜用于盐湖卤水提锂合格液的中试研究

为解决纳滤膜用于盐湖卤水镁锂分离中长时间运行后出现通量下降、膜污染和分离效率下降的问题,开展了将陶瓷超滤膜作为纳滤预处理措施用于盐湖卤水提锂合格液的中试研究。中试设在吸附提锂车间,进水为提锂工序中的合格液。结果表明,在冬天低温环境合格液浊度<50 NTU的条件下,以及在合格液浊度上升至50~170 NTU的极端进水水质条件下,陶瓷超滤膜均可在300 L/（m ²·h）的测试通量下稳定运行,过滤时间为30~50 min/周期。产水浊度稳定<0.1 NTU,优于后续纳滤系统进水要求。     

Corrosion Behavior of 304 Stainless Steel Exposed to a Simulated Salt Lake Atmosphere

The corrosion behavior of stainless steel exposed to a simulated salt lake atmosphere has been investigated by analyzing the evolution of surface morphologies and corrosion products, the initiation and development of pits, and the electrochemical characteristics. The results indicated that(Mg_6Fe_2(OH)_(16)(CO_3)(H_2O)_(4.5))_(0.25), a layered double hydroxide, has been detected for the first time in the corrosion products formed on stainless steel exposed to a simulated salt lake atmosphere. The specimens exposed to MgCl_2 deposit conditions were corroded more severely than those exposed to NaCl deposit conditions, which was attributed to the differences in the deliquescence relative humidity and efflorescence relative humidity values of MgCl_2 and NaCl. In addition, a special corrosion morphology consisting of a concentric circle of yellowish material was observed on the specimens exposed to MgCl_2 deposit conditions, which was attributed to the formation of Mg(OH)_2, inhibiting the diffusion and migration of OH~- ions to the anode region. The maximum pit depth followed a power function with respect to corrosion time. The corrosion mechanism of stainless steel exposed to a simulated salt lake atmosphere is also discussed.     

3D-modelling of Lake Kivu: Horizontal and vertical flow and temperature structure under spatially variable atmospheric forcing

With the increasing extraction of methane from Lake Kivu, there is a growing need to evaluate the effect of such operations on the lake’s permanent density stratification. This requires understanding of the spatial structure and variability of flow velocities and constituents in Lake Kivu. In this study, we develop a 3D hydrodynamic model of Lake Kivu, set-up within DELFT3D at a 750 m grid spacing and forced by COSMO-CLM atmosphere model results at a 2.8 km grid spacing. Validation shows that the model correctly reproduces the generation and breakdown of the temperature stratification in the upper mixed layer and predicts flow velocity magnitudes and directions similar to measurements both at the surface and at greater depth. Analysis of currents reveals a surface current pattern with two clockwise circulations, one around the whole lake and a smaller one in the northern part, with velocities around 0.1 m/s. This pattern is consistently present over an (ensemble-)averaged day, both in the wet and in the dry season, while day-by-day variations are large. Time-averaged deep currents are found to be a few mm/s at maximum. However, the variations can be substantial, with standard deviations up to 2 cm/s for the currents at 220 m depth, attributed to internal seiches. The temperature stratification, present during the entire wet season, is found to first break down in the dry season in the southern part of the lake. This is explained by the spatial differences in the wind stress and the evaporation heat fluxes during the dry season.     

潜江凹陷潜江组盐湖地层演化与层序发育特征

结合盐湖层序地层分析，在系统测试了潜江凹陷潜江组碳、氧同位素后，对其演化规律与层序地层的关系进行了探讨，研究结果表明：潜江组内δ^13C和δ^18O值的变化范围分别是-7.37‰～2.35‰。和-6.42‰～0．23‰(PDB)。在低位体系域的初期和高位体系战的末期，由于湖水范围较小，这对如果降雨量小于蒸发量就会有盐岩的沉积，所以其碳、氧同位素的值偏大；而在水进体系战时期，由于湖平面上升，湖水的注入量大于蒸发量，所以这一对期没有盐岩的沉积，碳、氧同位素的值也偏低。然而在对潜江组的潜四段进行研究时，却发现碳、氧同位素的分布不具上述规律。在潜四段盐岩不仅分布于低位体系战的初期和高位体系战的末期，而且在水进体系域中也可见盐岩。作者认为潜江凹陷潜江组可能存在另一种成盐模式一深水事件性成盐。