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1.
《International Journal of Hydrogen Energy》2022,47(69):29925-29944
Lithium iron phosphate battery (LIPB) is the key equipment of battery energy storage system (BESS), which plays a major role in promoting the economic and stable operation of microgrid. Based on the advancement of LIPB technology and efficient consumption of renewable energy, two power supply planning strategies and the china certified emission reduction (CCER) model are proposed respectively. Based on it, the multi-objective planning optimization model with economic benefits, environmental benefits and power supply stability as the objective function is established for the first time, and the Newton Weighted Sum Frisch method (NWSFA) solution model is adopted. In the planning process, rain flow counting method is used to research the life of BESS, which improves the accuracy of energy storage annual cost calculation. A park in northern China is taken as a case study to demonstrate the application of this model. The simulation results show that the annual economic operating cost of BESS is decreased by 18.81%, the energy supply reliability is increased by 0.15%, and the optimal electricity price adjustment ratio of the system is 15%. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(65):27973-27985
Metal-support interaction and catalyst pretreatment are important for industrial catalysis. This work investigated the effect of supports (SiO2, CeO2, TiO2 and ZrO2) for Cu–Pd catalyst with high Cu/Pd ratio (Cu/Pd = 33.5) regarding catalyst cost, and the reduction temperatures of 350 °C and 550 °C were compared. The activity based on catalyst weight follows the order of Si > Ce > Zr > Ti when reduced at 350 °C. The reduction temperature leads to the surface reconstruction over the SiO2, CeO2 and TiO2 catalysts, while results in phase transition over Cu–Pd/ZrO2. The effect of reduction temperature on catalytic performance is prominent for the SiO2 and ZrO2 supported catalysts but not for the CeO2 and TiO2 ones. Among the investigated catalysts, Zr-350 exhibits the highest methanol yield. This work reveals the importance of the supports and pretreatment conditions on the physical-chemical properties and the catalytic performance of the Cu–Pd bimetallic catalysts. 相似文献
3.
《Geotextiles and Geomembranes》2022,50(3):535-544
Soil column is often investigated in the improvement of dredged slurries. Different from the smear zone, the soil column forms gradually and has extremely low permeability. This study presents an analytical solution for soil consolidation considering the increasing radius of the soil column and time-dependent discharge capacity. Based on the solution, the influence of the radius' increase on the consolidation behavior is found significant when the soil column has low permeability and large final radius, and the increase of formation time can lead to the increase of consolidation speed and final consolidation degree. 相似文献
4.
Babak Jaleh Mahmoud Nasrollahzadeh Bahareh Feizi Mohazzab Mahtab Eslamipanah Mohaddeseh Sajjadi Hossein Ghafuri 《Ceramics International》2021,47(8):10389-10425
In both developing and industrialized/developed countries, various hazardous/toxic environmental pollutants are entering water bodies from organic and inorganic compounds (heavy metals and specifically dyes). The global population is growing whereas the accessibility of clean, potable and safe drinking water is decreasing, leading to world deterioration in human health and limitation of agricultural and/or economic development. Treatment of water/wastewater (mainly industrial water) via catalytic reduction/degradation of environmental pollutants is extremely critical and is a major concern/issue for public health. Light and/or laser ablation induced photocatalytic processes have attracted much attention during recent years for water treatment due to their good (photo)catalytic efficiencies in the reduction/degradation of organic/inorganic pollutants. Pulsed laser ablation (PLA) is a rather novel catalyst fabrication approach for the generation of nanostructures with special morphologies (nanoparticles (NPs), nanocrystals, nanocomposites, nanowires, etc.) and different compositions (metals, alloys, oxides, core-shell, etc.). Laser ablation in liquid (LAL) is generally considered a quickly growing approach for the synthesis and modification of nanomaterials for practical applications in diverse fields. LAL-synthesized nanomaterials have been identified as attractive nanocatalysts or valuable photocatalysts in (photo)catalytic reduction/degradation reactions. In this review, the laser ablation/irradiation strategies based on LAL are systematically described and the applications of LAL synthesized metal/metal oxide nanocatalysts with highly controlled nanostructures in the degradation/reduction of organic/inorganic water pollutants are highlighted along with their degradation/reduction mechanisms. 相似文献
5.
Alinda Samsuri Mohd Nor Latif Mohd Razali Shamsuddin Fairous Salleh Maratun Najiha Abu Tahari Tengku Shafazila Tengku Saharuddin Norliza Dzakaria Mohd Ambar Yarmo 《International Journal of Hydrogen Energy》2021,46(48):24831-24844
Temperature programmed reduction (TPR) analysis was applied to investigate the chemical reduction progression behavior of molybdenum oxide (MoO3) catalyst. The composition and morphology of the reduced phases were characterized by X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). The reduction progression of MoO3 catalyst was attained with different reductant types and concentration (10% H2/N2, 10% and 20% CO/N2 (%, v/v)). Two different modes of reduction process were applied. The first approach of reduction involved non-isothermal mode reduction up to 700 °C, while the second approach of reduction involved the isothermal mode reduction for 60 min at 700 °C. Hydrogen temperature programmed reduction (H2-TPR) results showed the reduction progression of three-stage reduction of MoO3 (Mo6+ → Mo5+ → Mo4+ → Mo0) with Mo5+ and Mo4+. XRD analysis confirmed the formation of Mo4O11 phase as an intermediate phase followed by MoO2 phase. After 60 min of isothermal reduction, peaks of metallic molybdenum (Mo) appeared. Whereas, FESEM analysis showed porous crater-like structure on the surface cracks of MoO2 layer which led to the growth of Mo phase. Meanwhile, the reduction of MoO3 catalyst in 10% carbon monoxide (CO) showed the formation of unstable intermediate phase of Mo9O26 at the early stage of reduction. Furthermore, by increasing 20% CO led to the carburization of MoO2 phase, resulted in the formation of Mo2C rather than the formation of metallic Mo, as confirmed by XPS analysis. Therefore, the presented study shows that hydrogen gave better reducibility due to smaller molecular size, which contributed to high diffusion rate and achieved deeper penetration into the MoO3 catalyst compared to carbon monoxide reductant. Hence, the reduction of MoO3 in carbon monoxide atmosphere promoted the formation of Mo2C which was in agreement with the thermodynamic assessment. 相似文献
6.
Kaihui Ma Junyi Deng Gang Wang Qi Zhou Jian Xu 《International Journal of Hydrogen Energy》2021,46(52):26646-26664
Hydrogen (H2) energy is a promising candidate to replace carbon monoxide (CO) as a reductant for iron oxide reduction in revolutionary ironmaking industrial processes, and numerous studies have been conducted to intensively study the utilization and impact of H2 in ironmaking processes. Therefore, this review first collects and compares the H2-assisted reduction mechanism and kinetics. The impacts of H2 on the reduction accompanying behaviors, such as the disintegration, swelling, sticking, softening, and melting of iron ores, are then summarized. Third, the performance of H2 predicted by either mass and heat balance models or numerical simulation models in various ironmaking processes is highlighted. Finally, the different applications of hydrogen-rich materials in blast furnace and non-blast furnace ironmaking processes are further compared to illuminate H2 utilization before our outlook on the use of H2 in the ironmaking industry. 相似文献
7.
Sang-Chae Jeon Jae-Won Lee Joo-Young Yoon Yung-Zun Cho Dong-Joo Kim Dong Seok Kim Keon Sik Kim Jong Hun Kim Jae Ho Yang 《Ceramics International》2019,45(6):6863-6868
A reduction process in the head-end for pyroprocessing has been adopted to avoid oxidation attack on the molybdenum crucible during sintering. The reduction process is employed to reduce U3O8 pellets to UO2 prior to sintering. This allows elimination of the oxygen source, which causes oxidation attack during sintering, thereby permitting the use of a metallic crucible. However, little densification occurs due to the low reduction temperature limited by the INCONEL crucible. Consequently, the amount of material scraps from the pellets increases, thus creating an additional processing burden due to its high radioactivity. To reduce the amount of scraps, densification should be enhanced. This study suggests a simple atmospheric control strategy and clarifies its effects. With the atmospheric control, a higher bulk density and better attrition resistance were obtained in comparison to without this strategy. This can be explained in terms of O/U ratio dependent diffusion kinetics during the reduction of U3O8 to UO2. 相似文献
8.
The electrochemical behavior of lanthanide elements deposited on liquid zinc cathodes was studied using cyclic voltammetry (CV) and open circuit chronopotentiometry (OCP). We observed a "bimodal effect" in the equilibrium deposition potentials of zinc with lanthanides. A mathematic equation is derived to illustrate the relationship between the equilibrium potential of the intermetallic compounds formed by lanthanide elements and zinc and their atomic radius. This equation is not only applicable to lanthanide elements but also hold for other elements such as alkali metal lithium, alkaline earth metal magnesium, calcium and transition metal niobium, which have crucial theoretical significance for the electrolysis of intermetallic compounds, the separation, and extraction of metals. 相似文献
9.
10.
将新开发的高效前处理、染色助剂应用于针织物实用高效漂染工艺,探讨其应用工艺、产品质量及节能减排效果。分析各类前处理碱氧一浴工艺的特点、应用特性及节能减排效果;阐述涤棉针织物练染一浴工艺,免还原清洗工艺,棉针织物活性染色与抛光一浴工艺及活性染色后皂洗酶后处理工艺。并与相应的传统工艺对比其工艺曲线、质量水平、节能减排效果及污染物浓度降低情况。客观评价各类工艺的优缺点,建议生产厂家根据产品质量要求,选用相应高效助剂,并结合实际生产设备优化工艺后使用,节能减排效果将更加显著。 相似文献