PAM-粉煤灰体系在煤泥水絮凝沉降过程中的作用及机理

以煤泥水COD、SS、动电位、污泥比阻为切入点,分析了煤泥水的特点及难以絮凝沉降的原因,并研究了PAM-粉煤灰体系在混凝沉降作用中的机理。研究结果表明:PAM-粉煤灰法在最优条件下,清水分离率47%、沉降速度0.357 mm/s;上清液:pH=7.35,SS=55.57 mg/L,COD=37.72 mg/L;污泥比阻为0.062×10^15 m/kg,满足煤泥水循环标准。     

Effect of cutting process on the stress corrosion susceptibility of AISI 304L stainless steel

During manufacturing of a component, cutting, turning, grinding, and milling operations are inevitable and these operations induce surface residual stresses. In this study, it is shown that, depending on the process employed for cutting, residual stresses generated at the cut surfaces can vary widely and they can, in turn, make the cut surfaces of austenitic stainless steel (SS) prone to stress corrosion cracking (SCC). An austenitic SS 304L plate was cut using three different procesess: bandsaw cutting, cutting using the cut-off wheel, and shearing. Surface residual stress measurement using the X-ray diffraction (XRD) technique is carried out close to the cutting edges and on the cross-section. SCC susceptibility studies were carried out as per ASTM G36 in 45% boiling magnesium chloride solution. Optical microscopic examination showed the presence of cracks, and confocal microscopy was used to measure the depth of cracks. The study confirmed that high tensile residual stresses present in the cut surfaces produced by cut-off wheel and shear cutting make the surfaces susceptible to SCC while the surfaces produced by bandsaw cutting are resistant to SCC. Hence, it is shown that there is a definite risk of SCC for product forms of austenitic SS with cut surfaces produced using cutting processes that generate high tensile residual stresses stored for a long period of time in a susceptible environment.     

Tribocorrosion and corrosion behavior of stainless steel coated with DLC films in ethanol with different concentrations of water

There has been a recent increase in both the production and consumption of ethanol due to the numerous environmental advantages that it offers, such as the fact that it can be produced from a variety of renewable materials, for instance corn and cellulose, or it can be obtained from sugarcane bagasse and biomass (2nd and 3rd generation ethanol). The result of this is that nowadays ethanol is widely seen as the dominant biofuel – or as a blend component in gasoline or pure fuel - in many countries.However, one disadvantage of the use of ethanol is the high corrosive behavior that occurs when its hygroscopic properties are exposed to a large number of materials. Xiaoyuan Lou and Preet Singh showed that the increase of water concentration in ethanol induces pitting and metal loss. Diamond-Like Carbon (DLC) films may be a solution to this problem due to the fact that they can be deposited inside tubes, offer good protection levels against corrosion, and reduce the friction coefficient and wear.This paper shows the tribocorrosion and corrosion studies of DLC films deposited on stainless steel grade 304 (SS304) substrates in order to gauge its appropriateness usage in the construction of pipelines and fuel storage tanks. The surface morphology was analyzed before and after 14 days of immersion. The tribocorrosion, friction coefficient, and wear rate were studied in ethanol to see the effects of water concentration. The films showed good adherence to the substrates. Corrosion and tribocorrosion results showed that for bare Stainless Steel 304 the increase of the water content increases the corrosion and the friction coefficient. DLC coated samples presented few points of delamination, and the friction coefficient and open circuit potentials were very low compared with the bare sample which was water concentration independent.     

Omics Analysis of Blood-Responsive Regulon in Bordetella pertussis Identifies a Novel Essential T3SS Substrate

Bacterial pathogens sense specific cues associated with different host niches and integrate these signals to appropriately adjust the global gene expression. Bordetella pertussis is a Gram-negative, strictly human pathogen of the respiratory tract and the etiological agent of whooping cough (pertussis). Though B. pertussis does not cause invasive infections, previous results indicated that this reemerging pathogen responds to blood exposure. Here, omics RNA-seq and LC–MS/MS techniques were applied to determine the blood-responsive regulon of B. pertussis. These analyses revealed that direct contact with blood rewired global gene expression profiles in B. pertussis as the expression of almost 20% of all genes was significantly modulated. However, upon loss of contact with blood, the majority of blood-specific effects vanished, with the exception of several genes encoding the T3SS-secreted substrates. For the first time, the T3SS regulator BtrA was identified in culture supernatants of B. pertussis. Furthermore, proteomic analysis identified BP2259 protein as a novel secreted T3SS substrate, which is required for T3SS functionality. Collectively, presented data indicate that contact with blood represents an important cue for B. pertussis cells.     

Influence of heat treatment on corrosion behaviors of 316L stainless steel in simulated cathodic environment of proton exchange membrane fuel cell (PEMFC)

The influences of two types of heat-treatments on the corrosion behavior of 316L SS in the simulated cathodic environment of PEMFC, are investigated using potentiodynamic curve, electrochemical impedance spectroscopy (EIS), Mott-Schottky plot and auger electron spectroscopy (AES), respectively. The results show that 316L SS is in the passive state within the potential region from −0.1V_SCE to 0.8V_SCE in the simulated cathodic environment of PEMFC, and a passive film can be formed on 316L SS. The passivity of 316L SS in the simulated cathodic environment of PEMFC firstly increases and then degrades with the increased solid solution temperature or time, and the best passivity corresponds to the solid solution temperature at 1050 °C for 40 min among other solid solution treatments. While 316L SS heat-treated with the solid solution treatment at 1050 °C for 40 min plus aging treatment at 900 °C for 4 h, also has the best passivity in the same solution among other solid solution plus aging treatments. The best corrosion protection, lowest donor density and the highest thickness of the passive film corresponding to the solid solution temperature at 1050 °C for 40 min among other solid solution or solid solution plus aging heat treatments, and this treatment is mostly suitable for improving the anti-corrosion property of 316L SS in the simulated cathodic environment of proton exchange membrane fuel cell (PEMFC).     

A novel method for determining effects of fire damage on the safety of the Type I pressure hydrogen storage tanks

Consumption of the fossil fuels causes greenhouse gas effect and environmental pollution, which are two basic problems of our age. As a result of this problem, clean and renewable alternative energy sources are beginning to replace fossil fuels. Nowadays, the use of hydrogen energy, which is one of the clean energy, is increasing in transportation and industrial areas. Increasing of hydrogen energy usage, scientists are attempting to solve the many safety problems (such as fire, burst, impact and hydrogen embrittlement) that can occur during the storage and consumption of hydrogen energy. In this study, during the event of fire, the safety of metallic Type I pressure hydrogen storage tanks is investigated by using a novel approach. In this new approach, the mechanical strength drops of the tank materials that is related with temperature rising are added to the safety calculations. In the study, 6061 T6 aluminum and SS 316L stainless steel alloys were used as hydrogen tank material. The safety of hydrogen tanks modelled using these alloys was investigated under different temperature conditions (22, 100, 200 and 300 °C) and internal pressure (15, 20 and 25 MPa).     

Evaluation of anticorrosion and contact resistance behavior of poly(orthophenylenediamine)- coated 316L SS bipolar plate for proton exchange membrane fuel cell

The present work was focused on the corrosion properties and contact resistance behavior of poly(orthophenlyenediamine) (PoPD) coating on 316L SS bipolar plates. To reduce the corrosion rate and increase the interfacial conductivity of 316L SS bipolar plates, PoPD coating was deposited using an electropolymerization technique by the various monomer concentration of orthophenlyenediamine (oPD) on its surface. The presence of 1, 2, 4, 5- tetra substituted benzene nuclei of phenazine units in the polymer coating was confirmed by infrared spectroscopy. X-ray photoelectron spectroscopy analysis has confirmed the (%) of chemical composition in PoPD coating. The results of scanning electron microscopy analysis revealed that the uniform and compact coating with complete cover on 316L SS. The corrosion properties were investigated in 0.5 M H₂SO₄ and 2 ppm HF solution at 80 °C. The polarization test results showed that the PoPD coating reduced the corrosion current density both in the PEMFC anode and cathode environments. The charge transfer resistance values were in the order of 316L SS ? 0.02 M PoPD ? 0.06 M PoPD ? 0.04 M PoPD. A very low interfacial contact resistance and good adhesion strength was observed for 0.04 M PoPD coating. The higher contact angle of 0.04 M PoPD coating explained the hydrophobic property and more benefit of water management in the PEMFC environment. The results of the analysis of total metal ion releases clearly explained that the low level of metal ions released for 0.04 M PoPD coating. The overall studies revealed the PoPD coating with optimized 0.04 M oPD concentration showed best performance and provided more anodic protection to 316L SS bipolar plates.     

曝气生物滤池去除SS以及水头损失增长的特性研究

通过中试考察了不同气水比下,上流式曝气生物滤池(BAF)去除悬浮物以及水头损失增长的特性.结果表明:随着气水比的增大,BAF对SS的去除效率降低,对SS的主要去除区域逐步向滤层上部推移,且反冲洗后滤层对SS去除能力的恢复减慢;BAF滤柱内的生物量随着气水比的增大而增加,随着滤层高度的增加而逐步减少,滤层高度为50 cm处的生物量高达12.50 ～21.52 mgVAS/g陶粒;BAF内水头损失的增加速率随着气水比的增大而减小,当气水比由2∶1增大为10∶1时,反冲洗周期内的终点水头损失由30.1 kPa减少为10.5 kPa.     

A bill of materials-based approach for end-of-life decision making in design for the environment

Re-use, recycling or remanufacturing of products and components are good alternatives for reducing the environmental problems resulting from the huge amounts of waste currently arriving at landfills. A new approach is proposed in this paper for enhancing these alternatives from the earliest stages of product design. Given the product structure (obtained from its bill of materials (BOM)) and the joining and geometrical relationships among the components (obtained from the three-dimensional, computer-aided design representation), a model is proposed that will determine the EOL (EOL) strategy, i.e. the depth of disassembly inside the structure and the final end (re-use, recycle, remanufacture or disposal) for each disassembled part leading to the highest profit. A scatter search (SS) metaheuristic is used to determine the disassembly cost at each level of the BOM. The model presents a number of major improvements with respect to previous research. It addresses the problems of simultaneously determining both the best EOL strategy and the disassembly sequence, as well as allowing removal of components not only over the two or three Cartesian axes and affording the possibility of modifying the encountered strategy in a further step so as to fulfil other business criteria (such as disassembly time, resources availability or maximum waste generation rate).     

Characterization of stainless steel parts by Laser Metal Deposition Shaping

Laser Metal Deposition Shaping (LMDS) is a new rapid manufacturing technology, which can build fully-dense metal components directly from the information transferred from a computer file by depositing metal powders layer by layer with neither mould nor tool. Typically, performed with stainless steel (SS) 316 powder, the orthogonal experiments combining with the ideal overlapping model were applied to ascertain the optimal processing parameters. Then the characteristics of microstructure, composition and phase of as-deposited cladding layers were analyzed through Scanning Electron Microscope (SEM) and X-ray diffraction (XRD), as well as relative model. Furthermore, the cooling rate and the solidification velocity during LMDS were evaluated based on empirical method. With the optimal parameters, some parts were fabricated without obvious defects, and then the mechanical properties of them were tested. Finally, the influencing regularities of critical parameters on microstructure and properties were concluded by comparison. The results prove that the microstructure of SS 316 deposits is composed of the slender dendrites growing epitaxially from the substrate, the mechanical properties are favorable and anisotropic, and the composition is uniform. Besides, the microstructure morphology and the mechanical properties are affected by the varied processing parameters at different degrees. Among them, the scanning speed shows the most remarkable effects on microstructure morphology, characteristic microscale, mechanical properties, as well as geometric shape of as-deposited parts.