Influence of LiBO2 addition on the microstructure and lithium-ion conductivity of Li1+xAlxTi2−x(PO4)3(x = 0.3) ceramic electrolyte

Concerning the safety problems of conventional Li-ion batteries with liquid electrolytes, it is crucial to develop reliable solid-state electrolytes with high ionic conductivity. Li_1+xAl_xTi_2?x(PO₄)₃ (LATP, x = 0.3) is regarded as one of the most promising solid electrolytes due to its high ionic conductivity and excellent chemical stability to humidity.Herein, a new strategy is proposed for improving the sintering behavior and enhancing the ionic conductivity of LATP by using LiBO₂ as the sintering aid via liquid phase sintering. The as-prepared sample LATP with homogeneous microstructure and high relative density of 97.1% was successfully synthesized, yielding high total ionic conductivity of 3.5 × 10^?4 S cm^?1 and low activation energy of 0.39 eV at room temperature. It was found that the addition of LiBO₂ could effectively enhance the densification and increase the ionic conductivity of LATP electrolyte, proving an effective way to synthesis LATP ceramics by a simple and reliable route.     

新冠肺炎疫情对上海经济社会发展的影响机制与应对策略

新型冠状病毒肺炎(以下简称新冠肺炎)疫情对上海经济社会发展造成了诸多影响,上海正在深入学习贯彻习近平总书记系列重要讲话精神,坚定推进"两手抓、两手硬、两手赢"。通过电话咨询部分企业家、查阅媒体相关文献、对比SARS疫情、政策分析等方式,研究认为新冠肺炎疫情对上海经济发展的影响可以从"短期-中期-长期"的时间序列进行分析,而对社会发展影响则可从"个人-社区-城市-社会"空间序列进行探讨,在影响机制的基础上还提出了相应的对策建议。     

Effects of deformation rate on properties of Nd,Y-codoped CaF2 transparent ceramics

Different deformation rates of Nd,Y-codoped CaF₂ transparent ceramics were prepared by ceramization of single crystals. The deformation rate effects on the crystallization behaviors, microstructures, mechanical properties, and optical performances were investigated for the first time. The results indicate that the comprehensive performances of Nd,Y-codoped CaF₂ ceramic (△a?=?62%) are the most optimal compared with other ceramics having different deformation rates (△a?=?34%, 40%, 50%, and 75%). In further investigations of the optical properties, the Nd,Y-codoped CaF₂ ceramic (△a?=?62%) sample exhibited a high transparency (T_a?>?91%, 3-mm thick，250?～?1200?nm), low light scattering, superior fracture toughness (K_1c?～?0.71?MPa·m^1/2), strong fluorescence emission, long lifetime (τ?=?348.72?μs), and broad FWHM (29.2?nm), promising a good candidate for high-power laser material.     

Strength and dilatancy behaviors of deep sands in Shanghai with a focus on grain size and shape effect

With rapid development of infrastructures like tunnels and open excavations in Shanghai, investigations on deeper soils have become critically important. Most of the existing laboratory works were focused on the clayey strata up to Layer 6 in Shanghai, i.e. at depth of up to 40 m. In this paper, Layers 7, 9, and 11, which were mostly formed of sandy soils at depth of up to 150 m, were experimentally investigated with respect to physico-mechanical behaviors. The stress–strain behaviors were analyzed by the consolidated drained/undrained (CD/CU) triaxial tests under monotonic loading. One-dimensional (1D) oedometer tests were performed to investigate the consolidation properties of the sandy soils. Specimens were prepared at three different relative densities for each layer. Also, the micro-images and particle size analyzers were used to analyze the shape and size of the sand grains. The influences of grain size, density, and angularity on the stress–strain behaviors and compressibility were also studied. Compared to the other layers, Layer 11 had the smallest mean grain size (D₅₀), highest compressibility, and lowest shear strength. In contrast, Layer 9 had the largest mean grain size, lowest compressibility, and highest shear strength. Layer 7 was of intermediate mean grain size, exhibiting more compressibility and less shear strength than that of Layer 9. Also, the critical state parameters and maximum dilatancy rate of different layers were discussed.     

K0固结条件对上海软土强度和变形影响的试验研究

本文通过对上海淤泥质粉质粘土和淤泥质粘土,在K_0固结条件下的常规三轴和真三轴排水剪切试验,探讨了K_0固结状态对上海软土强度和变形性能的影响规律,并与各向等压固结三轴排水剪切试验的情况进行了比较和分析。     

上海的支柱产业——房地产业浅析

上海房地产业已具备了成为国民经济支柱产业的必要条件。选择房地产业作为支柱产业的基本依据即发展上海房地产业符合产业结构演进的方向 ,有利于结构优化升级 ,更好地推动现代化国际大都市的建设和管理 ,促进和带动相关产业的兴起和经济的快速发展 ,有助于提高市民居住水平。     

上海近代城市规划及其制度背景与城市空间形态特征

基于上海多样拼贴的城市形态特征,分析了公共租界城市规划意识从无到有的历程以及法租界和1927年后上海市政府的城市规划,讨论重点是规划中对城市形态规定的差异及其不同实现途径和制度背景,找到不同城市形态的成因、显性特征和隐藏秩序.     

上海城市交通的战略选择:空间结构的视角

首先简要介绍了上海市目前交通拥堵状况和解决大城市交通问题的研究进展,在详细分析交通供需矛盾的现状和未来发展趋势的基础上,提出了从优化城市空间结构的角度解决交通问题的新思路。指出对于上海城市空间结构的分析显示出优化空间结构对于解决交通问题的现实必要性。最后就如何优化上海城市空间结构来解决上海交通问题提出了一些战略性的思考和建议。     

安藤忠雄的上海新作--上海国际设计中心

本文介绍了上海国际设计中心项目概况,并从形体、功能、材料、构造等方面详细地阐述了安藤忠雄对于该建筑的理解与把握。