Site occupation and energy transfer in full color emitting phosphor Ba2Ca(BO3)2:Ce3+(K+),Eu2+,Mn2+

White light-emitting diodes (WLEDs) fabricated by single-phase full color emitting phosphor are an emerging solution for health lighting. The crystallographic site occupation of activators in a proper host lattice is crucial for sophisticated design of such phosphor. Here, we report a high quality white light-emitting phosphor Ba₂Ca(BO₃)₂:Ce³⁺(K⁺),Eu²⁺,Mn²⁺ with spectral distribution covering whole visible region. Blue light emission originates from Ce³⁺ ions occupying preferentially Ba²⁺ site by controlling synthesis conditions. Green and red lights are obtained from Eu²⁺ occupying Ba²⁺ (and Ca²⁺) site and Mn²⁺ occupying Ca²⁺ site, respectively. In this triple-doped phosphor, strong red emission with a low concentration of Mn²⁺ is realized by the efficient energy transfer from Ce³⁺ and Eu²⁺ to Mn²⁺. Furthermore, high quality white light is accomplished by properly tuning the relative doping amount of Ce³⁺(K⁺)/Eu²⁺/Mn²⁺ based on efficient simultaneous energy transfer. The results indicate that Ba₂Ca(BO₃)₂:Ce³⁺(K⁺),Eu²⁺,Mn²⁺ is a promising white light-emitting phosphor in WLEDs application.     

Analysis of predictor equations for determining the blast-induced vibration in rock blasting

The paper proposes a new empirical correlation designed to complement the “site laws” currently used to evaluate the attenuation in the rock masses of vibrations induced by rock blasting. The formula contains a deformed exponential known as the K-exponential, which seems to well represent a large number of both natural and artificial phenomena ranging from astrophysics to quantum mechanics, with some extension in the field of economics and finance. Experimental validation of the formula was performed via the analysis of vibration data covering a number of case studies, which differed in terms of both operation and rock type. A total of 12 experimental cases were analysed and the proposed formulation exhibited a good performance in 11 of them. In particular, the proposed law, which was built using blast test data, produced very good approximations of the points representing the vibration measurements and would thus be useful in organising production blasts. However, the developed formula was found to work less well when a correlation obtained for a given site was applied to another presenting similar types of rocks and operations, and thus should not be employed in the absence of measurements from test data.     

高迪的遗产——加泰罗尼亚地区建筑实践中的地景共识

本文以安东尼·高迪在古埃尔公园与古埃尔礼拜堂中处理场地的方式为出发点,通过对当代加泰罗尼亚建筑师爱德华·布鲁、恩瑞克·米拉莱斯、卡洛斯·费拉特尔、约瑟夫·里纳斯等人作品的分析,引出加泰罗尼亚建筑师在如何处理建筑与场地环境方式上的一种共识性态度,即在加泰罗尼亚,建筑师多以场地信息作为关键因素切入设计,最终的作品同场地和谐共融。这种不同于元素借用或者是材料肌理延续的方式在文章中被定义称为"地景式建筑"。     

Synergistic effect of co-alloying elements on site preferences and elastic properties of Ni3Al: A first-principles study

The site preferences of co-alloying elements (Mo–Ta, Mo–Re, Mo–Cr) in Ni₃Al are studied using first-principles calculations, and the effects of these alloying elements on the elastic properties of Ni₃Al are evaluated by elastic property calculations. The results show that the Mo–Ta, Mo–Re and Mo–Cr atom pairs all prefer Al–Al sites and the spatial neighbor relation of substitution sites almost has no influence on the site preference results. Furthermore, the Young's modulus of Ni₃Al increases much higher by substituting Al–Al sites with co-alloying atoms, among which Mo–Re has the best strengthening effect. The enhanced chemical bondings between alloying atoms and their neighbor host atoms are considered to be the main strengthening mechanism of the alloying elements in Ni₃Al.     

Phase equilibria in the Fe–Al–Nb system: Solidification behaviour,liquidus surface and isothermal sections

The Fe–Al–Nb phase diagram including isothermal sections at 1000, 1150, and 1300 °C as well as the liquidus surface and corresponding reaction scheme was studied experimentally by a combination of scanning electron microscopy (SEM), electron probe microanalysis (EPMA), X-ray diffraction (XRD), and differential thermal analysis (DTA). No genuinely ternary intermetallic phase exists in the system, but the two Fe–Nb phases NbFe₂ (C14-type Laves phase) and Fe₇Nb₆ (μ phase) have extended homogeneity ranges in the ternary system, where large amounts of Fe can be substituted by Al in both cases. The solubility of the third element was studied for all binary phases and the effect on the lattice parameters is discussed. From analysis of the as-cast microstructures and DTA experiments, the liquidus surface including all invariant reactions as well as the occurring solid state reactions were established. Three ternary eutectics, one eutectoid, and two peritectic reactions were found, and the list of invariant points is completed by seven U-type reactions.     

Total Site Hydrogen Integration with fresh hydrogen of multiple quality and waste hydrogen recovery in refineries

This paper proposes a novel method combining Pinch Methodology and waste hydrogen recovery, aiming to minimise fresh hydrogen consumption and waste hydrogen discharge. The method of multiple-level resource Pinch Analysis is extended to the level of Total Site Hydrogen Integration by considering fresh hydrogen sources with various quality. Waste hydrogen after Total Site Integration is further regenerated. The technical feasibility and economy of the various purification approaches are considered, demonstrated with a case study of a refinery hydrogen network in a petrochemical industrial park. The results showed that fresh hydrogen usage and waste hydrogen discharge could be reduced by 21.3% and 67.6%. The hydrogen recovery ratio is 95.2%. It has significant economic benefits and a short payback period for Total Site Hydrogen Integration with waste hydrogen purification. The proposed method facilitates the reuse of waste hydrogen before the purification process that incurs an additional environmental footprint. In line with the Circular Economy principles, hydrogen resource is retained in the system as long as possible before discharge.     

Adaptive sampling strategy for characterizing spatial distribution of soil liquefaction potential using cone penetration test

Characterizing spatial distribution of soil liquefaction potential is critical for assessing liquefaction-related hazards (e.g. building damages caused by liquefaction-induced differential settlement). However, in engineering practice, soil liquefaction potential is usually measured at limited locations in a specific site using in situ tests, e.g. cone penetration tests (CPTs), due to the restrictions of time, cost and access to subsurface space. In these cases, liquefaction potential of soil at untested locations requires to be interpreted from limited measured data points using proper interpolation method, leading to remarkable statistical uncertainty in liquefaction assessment. This underlines an important question of how to optimize the locations of CPT soundings and determine the minimum number of CPTs for achieving a target reliability level of liquefaction assessment. To tackle this issue, this study proposes a smart sampling strategy for determining the minimum number of CPTs and their optimal locations in a self-adaptive and data-driven manner. The proposed sampling strategy leverages on information entropy and Bayesian compressive sampling (BCS). Both simulated and real CPT data are used to demonstrate the proposed method. Illustrative examples indicate that the proposed method can adaptively and sequentially select the required number and optimal locations of CPTs.     

Hydrogen adsorption on pristine and platinum decorated graphene quantum dot: A first principle study

In the ever growing demand of future energy resources, hydrogen production reaction has attracted much attention among the scientific community. In this work, we have investigated the hydrogen evolution reaction (HER) activity on an open-shell polyaromatic hydrocarbon (PAH), graphene quantum dot “triangulene” using first principles based density functional theory (DFT) by means of adsorption mechanism and electronic density of states calculations. The free energy calculated from the adsorption energy for graphene quantum dot (GQD) later guides us to foresee the best suitable catalyst among quantum dots. Triangulene provides better HER with hydrogen placed at top site with the adsorption energy as −0.264 eV. Further, we have studied platinum decorated triangulene for hydrogen storage. Three different sites on triangulene were considered for platinum atom adsorption namely top site of carbon (C) atom, hollow site of the hexagon carbon ring near triangulene's unpaired electron and bridge site over C–C bond. It is found that the platinum atom is more stable on the hollow site than top and bridge site. We have calculated the density of states (DOS), highest occupied molecular orbitals (HOMO), lowest unoccupied molecular orbitals (LUMO) and HOMO-LUMO gap of hydrogen molecule adsorbed platinum decorated triangulene. Our results show that the hydrogen molecule (H₂) dissociates instinctively on all three considered sites of platinum decorated triangulene resulting in D-mode. The fundamental understanding of adsorption mechanism along with analyses of electronic properties will be important for further spillover mechanism and synthesis of high-performance GQD for H₂ storage applications.     

Prioritization of potential locations for harnessing wind energy to produce hydrogen in Afghanistan

Due to the devastating ecological effects and constrained reserves of fossil fuels, renewable energies are now globally accepted as viable alternative sources of energy. Among renewable energy sources, wind energy has become globally popular, primarily because wind farms can be rapidly built and easily maintained at a relatively low cost. Wind-powered hydrogen production is an effective solution for storing the excess energy output of wind farms. The hydrogen produced in this way can be used not only in fuel cells but also in cooling, oil, gas, and petrochemical fields. As a country devastated by war and instability, Afghanistan has major energy generation challenges and a substantially large power supply deficiency. However, there are good wind energy potentials in several parts of this country. There are also several hydrogen-consuming fields in Afghanistan that can benefit from hydrogen production from wind energy. This paper endeavored to distinguish the appropriate areas in Afghanistan for harvesting wind energy for hydrogen production using multi-criteria decision-making techniques. Eleven criteria were utilized to prioritize 20 Afghan provinces with wind energy potential. The Step-wise Weight Assessment Ratio Analysis (SWARA) was utilized to weight the criteria and Evaluation based on Distance from Average Solution (EDAS) were utilized to prioritize the provinces. Then, ARAS, TOPSIS, and VIKOR methods were used to validate the resultants. For criteria weighting with SWARA, “wind speed”, “wind power density” and “area of windy regions” with weights of 0.1423, 0.1356, and 0.1221 were introduced as the most significant criteria for this ranking. In all the rankings, Herat, Farah, and Jowzjan were identified as the top three most suitable provinces for wind power generation. The power output and hydrogen output to be achieved in Herat province using a 900-kW turbine were estimated to 2558.4 MW per year and 41.4 tons per year, respectively.     

破碎难采矿体开采地压的测试研究

针对新城金矿极破碎顶底柱难以安全采出的情况，开展了采场地压规律的动态监测。应用YZY型钻孔应力传感器和二次接收仪测量采场地压变化，采用电子数显式收敛计量测围岩变形，得出了顶底往开采地压变化的一般规律，为选择合理的矿柱开采方案和地压控制措施提供了科学的依据。