Controllable preparation of porous ZrB2–SiC ceramics via using KCl space holders

In this work, a novel and facile technique based on using KCl as space holders, along with partial sintering (at 1900 °C for 30 min), was explored to prepare porous ZrB₂–SiC ceramics with controllable pore structure, tunable compressive strength and thermal conductivity. The as-prepared porous ZrB₂–SiC samples possess high porosity of 45–67%, low average pore size of 3–7 μm, high compressive strength of 32–106 MPa, and low room temperature thermal conductivity of 13–34 W m⁻¹ K⁻¹. The porosity, pore structure, compressive strength and thermal conductivity of porous ZrB₂–SiC ceramics can be tuned simply by changing KCl content and its particle size. The effect of porosity and pore structure on the thermal conductivity of as-prepared porous ZrB₂–SiC ceramics was examined and found to be consistent with the classical model for porous materials. The poring mechanism of porous ZrB₂–SiC samples via adding pore-forming agent combined with partial sintering was also preliminary illustrated.     

A novel fabrication procedure for producing high strength hydroxyapatite ceramic scaffolds with high porosity

Hydroxyapatite (HA) scaffolds were fabricated using the space holder method with a pressureless sintering process in a systematically developed manner at different fabrication stages to increase the strength of the scaffold at high porosity. Polyvinyl alcohol (PVA) and Polymethyl methacrylate (PMMA) were used as binders and space holder agents, respectively. The physical properties of the HA scaffolds were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), linear shrinkage test, and porosity measurements. The mechanical properties of the HA scaffolds were analyzed using compressive strength measurements. The results revealed that the HA scaffold met the expected quality requirements with a compressive strength of 2.2 MPa at a porosity of 65.6% with pore sizes distributed in the range of 126–385 μm. The shrinkage of the scaffold diameter occurred by 20.27%, this diameter shrinkage predominantly to the shrinkage of the HA scaffold caused by sintering. Besides, suspect that a higher PMMA concentration causes pore size shrinkage upon sintering. The formation of pore interconnections was evidenced by SEM observations and the ‘translucent light method’ developed in this study. The results of the scaffold phase test using XRD showed that the final scaffold consisted only of the HA phase, as the PVA and PMMA phases burned out during the sintering process.     

基于控制变量参数化方法的自由漂浮空间机器人路径规划研究

针对自由漂浮空间机器人传统路径规划方法对基座卫星扰动较大的问题，提出了一种基于控制变量参数化的路径规划方法。该方法将路径规划问题转化成以基座姿态扰动最小为目标函数并满足一系列约束条件的最优控制问题，并采用控制变量参数化方法进行离散化处理，将最优控制问题转化成求解非线性规划问题，并给出了完整的理论收敛性证明，从而准确地估计出自由漂浮空间机器人末端执行器的最优路径。仿真结果表明，与传统的分解加速度方法相比，该方法得到的运动路径所引起的基座卫星姿态扰动为0.104rad，相比传统方法降低了17.53%，验证了所提路径规划方法的有效性与最优性。     

User activities and the heterogeneity of urban space:The case of Dahiyat Al Hussein park

Urban researchers have maintained a constant interest in the complexity and continuity of urban space usage. Some have applied actor–network theory (ANT) to investigate the heterogeneity of spaces and present them through the networks of their users’ activities. However, these accounts are predominantly limited in examining the extent to which these spaces may be heterogeneous when exploring such networks. This paper draws on recent ANT scholarship, which employs an ethnographic research conducted in a main park in a housing project at Dahiyat Al Hussein in Amman, Jordan. The findings describe the complex and unpredictable negotiations that occur within spaces by documenting the varieties and interrelations among user activity networks within this common and shared urban space. This research reveals the extent to which spaces, parks in this case, may be heterogeneous by unpacking their usage. The conclusions and insights assert the necessity of paying attention to design detail and creating designs that are responsive to evolving user activities.     

Space charge region effects in bidirectional illuminated P3HT:PCBM bulk heterojunction photodetectors

Organic semiconductors are widely investigated for their application in photovoltaics and photodetectors. We show that the efficiency of these devices is strongly influenced by the position of the space charge region, due to unintentional doping, and wavelength-dependent absorption properties in bulk heterojunctions. Spray-coated P3HT:PCBM bulk heterojunction photodiodes with thicknesses up to 4.2 μm and semitransparent top contact enable the characterization of exciton generation and separation in both irradiation directions. A large difference in external quantum efficiency (EQE) is observed for top and bottom illuminated configurations and is explained by a bias dependent arrangement of the space charge region at the two contact electrodes. Numerical drift–diffusion simulations allow to get insight into first order mechanisms behind the spectral features of EQE data in highly-doped organic photodiodes.     

环境设计专业学习空间设计探析--以教室改造的参与式设计为例

学习空间的设计必须基于教育理念、学习模式、技术设施与精神氛围等因素展开,以更开放、灵活及多样化的有趣形态来吸引使用者。对于已掌握基本设计方法并具有一定设计思维的环境设计专业学生而言,设计与自身学习行为关联的学习空间,能体现"参与式设计"的特殊意义:即一方面以有着直观体验感受的熟悉空间作为训练案例来有效地整合设计能力;另一方面则通过用户与设计者身份的叠加,从使用者体验一维到对空间发展的专业预设考虑一维共同实现学习空间设计理念的更新。     

融入局部几何特征的流形谱聚类图像分割

为了改善谱聚类图像分割的精准性和时效性,文中提出融入局部几何特征的流形谱聚类图像分割算法.首先,考虑图像数据的流形结构,在数据点的K近邻域内执行局部PCA,得到数据间本征维数的关系.然后,引入流形学习中的局部线性重构技术,通过混合线性分析器得到数据间局部切空间的相似性,结合二者构造含有局部几何特征的相似性矩阵.再利用Nystr m技术逼近待分割图像的特征向量,对构造的k个主特征向量执行谱聚类.最后,在Berkeley数据集上的对比实验验证文中算法的准确性和时效性优势.     

当一切都合为整体 ——克里斯蒂安·克雷兹访谈

本文是对克里斯蒂安·克雷兹进行的访谈。"整体"的概念体现在访谈的方方面面之中:克雷兹的建筑学习开始于在类比建筑学影响下,将建筑理解为一个整体的设计方法;在他当下思考中,整体是对于空间本质的根本认知,建筑的外观变化源于空间认知的整体逻辑而不是碎片式的风格转变;在他从概念到实践的工作方式中,整体的概念体现在对于感性一以贯之的坚持;在他的实践项目,尤其是中国的竞赛项目中,整体是对于建筑与社会问题的综合思考,其新近完成中国美术学院良渚校区竞赛的综合体量也是这点的体现之一。     

Current-ramp assisted sintering of 3YSZ: Electrochemical and microstructural comparison to flash and thermal sintering

Flash sintering features an unoptimized and uncontrolled rise in current density and sample conductivity. By using a controlled current-ramp technique with a predetermined ramp function, microstructure and electrochemical properties can be improved. This current-ramp method is investigated through use of test functions that follow square-root, linear, and parabolic time dependence with comparison to conventional flash sintering and thermal sintering. Steeper ramp functions during the sintering result in higher activation energy, suggesting a change in the vacancy concentration for both the bulk and grain boundary regions. Estimation of the grain boundary domain width suggests a grain size dependence of the unique space charge contribution to conduction independent of sintering method. Contrary to conventional wisdom, flash sintering can actually result in enhanced grain growth compared to controlled current-ramps and conventional sintering, implying that uncontrolled rise in current to a set cutoff may not be the optimal method for densification.