Thermal properties of hierarchical YSZ and LZO ceramic microspheres with multi-scaled voids investigated by using theoretical,experimental and simulation methods

Heat transfer within ceramic feedstock powders is still unclear, which impedes optimization of the thermal and mechanical properties of the thermal sprayed coatings. The microspheres (yttria-stabilized zirconia YSZ and lanthanum zirconate LZO) were prepared via the electro-spraying assisted phase inversion method (ESP). The thermal properties of the two ESP microspheres and a commercial hollow spherical powder (HOSP) were investigated by using theoretical, experimental, and simulation methods. Thermal conductivity of the single microsphere was estimated via a novel nest model that was derived from the Maxwell-Eucken 1 and the EMT model. Thermal conductivity of a single YSZ/LZO-ESP microsphere prepared at 1100–1200 °C was within 0.36–0.75 W/m K, which was ～ 20 % lower than that of a single YSZ-HOSP microsphere with a similar porosity. Heat flux simulation showed that high tortuosity around the multi-scaled voids of the ESP microsphere led to a more efficient decrease in thermal conductivity compared with total porosity.     

贵阳都市圈的空间结构分析与优化策略研究*

都市圈已经成为新型城镇化推进的主 要战略空间，在推进区域一体化发展中发挥着重 要作用。贵阳都市圈的建设对于西南地区的高质 量发展具有重要意义。基于空间相互作用理论， 研究通过建立城市综合质量评价指标体系、修 正引力模型、断裂点模型分析贵阳都市圈的空 间结构特征，结果表明贵阳都市圈呈现出核心 城市与周边城镇空间发展不均衡、强核心—弱 边缘的圈层式空间结构、圈层扩散及轴向放射 式的都市圈空间发展导向、距离核心城市40— 80 km断裂点区域发展滞后的空间结构特征。研 究发现贵阳都市圈仍处于初期发展阶段，核心 城市的发展能级受到生态环境及区域发展阶段 的影响，尚未形成对都市圈地区的全面带动。研 究提出需要进一步增强核心城市能级，积极培育次级中心城市，通过打造现代化产业体系、健全 交通网络强化都市圈内部联系，形成“核心—环网—放射状”的区域一体化都市圈空间结构。     

Fluoride-mediately solvothermal synthesis and tunable photocatalytic selectivity of urchin-like ZrO2 hollow microspheres

Photocatalysts often show excellent performances on the basis of their surface state of exposed faces with high reactivity, but unfortunately surfaces of this type are usually concealed into the interior of crystals for their high surface energy. We report here a possibility that for fluorine-terminated surfaces of monoclinic ZrO₂, these higher-energy surfaces could be retained and exposed. Urchin-like ZrO₂ hollow microspheres (UZHS) composed of nanoribbons with exposed (010) facets are obtained through a fluoride mediately solvothermal method. We prove the stabilization effect of fluorine adsorption on (010) facets by density functional theory calculations. More interestingly, UZHS exhibit tunable photocatalytic selectivity in dye degradation. The fluorinated UZHS exhibit good performances both on decomposing Congo red (CR) and methylene blue, while the surface-modified UZHS by calcination only favor decomposition of CR.     

首届全国大学生化工实验大赛总决赛的实践与思考

本文介绍了首届全国大学生化工实验大赛总决赛的组织、实施过程，重点介绍了为保证总决赛的公平公正所采取的措施；统计了参赛者的化工原理理论和化工原理实验成绩，分析了理论和实验教学中可能存在的问题，总结了理论教学和实验教学需要改进的地方，探讨了化工实验大赛对培养学生实践能力和创新精神的推动作用。     

Understanding the psychological benefits in organic consumerism: An empirical exploration

This research builds on the Theory of Planned Behavior (TPB) by proposing two additional constructs: warm glow and self-expressive benefits which could further drive consumer attitude and purchase intentions in the context of organic food consumption. We employed structural equation modelling (SEM) technique with Smart PLS 3.0 (Partial Least Squares) for the analysis of the hypothesised relationships between these psychological factors and the constructs of the Theory of Planned Behavior (TPB). The theoretical model was tested with samples from India (n = 471) and the USA (n = 440) collected using Amazon’s Mechanical Turk (M Turk). Results confirmed the importance of warm glow and self-expressive benefits in organic consumerism in both markets. The study makes an important contribution in adding these two constructs to the TPB and then suggests practical tips to policy makers.     

容迟网络中基于演化博弈的合作行为

针对容迟网络中节点由于资源有限而表现出来的自私特性,为改善网络中节点的合作行为,进而提高网络的整体性能,提出一种基于演化博弈(EGT)的节点合作行为促进机制。首先,采用囚徒困境模型建立节点与其邻居博弈的收益矩阵;其次,基于度中心性定义节点的社会权威性;进一步地,在节点策略更新规则时考虑社会权威的影响,选择当前邻居中社会权威较高的节点进行模仿学习;最后,在机会网络环境仿真器上基于真实的动态网络拓扑数据进行仿真实验。仿真结果表明,与随机选择邻居的费米(Fermi)更新规则相比,考虑社会权威的更新规则能够更好地促进节点合作行为的涌现,进而提升网络的整体性能。     

Real-time administration of tool sharing and best matching to enhance assembly lines balanceability and flexibility

Collaboration has been found in previous studies on the design of assembly lines to be a useful mechanism. In this study, the focus is on a collaborative assembly (CA) framework, inspired by the design principles of CCT, the Collaborative Control Theory, to improve balanceability and flexibility of assembly lines through tool sharing (TS) among idle and bottleneck workstations. TS is widely practiced in advanced assembly facilities to reduce cost and improve consistency and standardization in assembly and in assembly-and-test utilities, relying often on real time control. The framework developed here addresses the systems design aspect of Mechatronics, covering the planning, execution, and control mechanisms. Planning includes assembly line balancing (ALB) and initial TS decisions, made continually by solving a bi-objective mixed-integer program (BOMIP). A collaborative multi-agent system (CMAS) enhanced with a TS-best matching (BM) protocol is developed to execute the plan, control the process, and modify the TS decisions, considering dynamic changes in the system’s operations. Experiments show that the new CA framework significantly outperforms classic approaches (i.e., ALB without TS-BM) in terms of cycle time, utilization of tools, and balanceability. In addition, the control mechanism is proven to augment the line’s flexibility against the inherent uncertainties of assembly processes, compared to the previously developed static CA frameworks.     

Transport and solvent sensing characteristics of styrene butadiene rubber nanocomposites containing imidazolium ionic liquid modified carbon nanotubes

Obtaining strong interfacial interaction between filler and polymer matrix is very crucial for the fabrication of polymer nanocomposites with superior performance. Present study is aimed to fabricate high performance styrene butadiene rubber (SBR) nanocomposites with imidazolium type ionic liquid modified multiwalled carbon nanotube (MWCNT). Ionic liquid facilitates the dispersion of MWCNT in rubber matrix and it is obvious from transmission electron microscopy images. Diffusion of toluene through SBR nanocomposite membranes has been investigated as a function of surface modified MWCNT (f-MWCNT) content to analyze the chain dynamics and filler-polymer interactions. O₂ gas barrier effect of nanocomposites with special reference to the filler loading is explored. The substantial improvement in the barrier effect in presence of filler interpreted on the grounds of a theoretical model describing permeability of heterogeneous systems. Finally solvent sensing characteristics of prepared nanocomposites are also analyzed and it is observed that prepared nanocomposites can be used as a flexible solvent sensor.     

翻译转换理论在石油化工英语翻译中的应用

对石油化工文本的英译汉研究,有利于将国外最新技术成果带回国内,以供国内学者学习与借鉴。基于卡特福德的翻译转换理论,通过典型案例研究,提出适合该类文本的翻译方法,以期为从事该类的译者提供借鉴,提高该类文本翻译准确性,并为技术交流提供语言服务。     

Information system ecology: An application of dataphoric ascendancy

Information systems, like biological systems, are susceptible to external perturbations. Similar to flora and fauna in a biome, species of data can be classified within a dataphora. While entropic properties and data geometries can be used to describe local species of data within a dataphora, they are not designed to describe the global properties of an information system or evaluate its stability. Ecologists have used Information Theories to describe macro-level properties of biological ecosystems and statistical tools to evaluate biological systems. This research leverages an ecological perspective to model information systems as a living system. Our findings support the theory of dataphoric ascendancy with Wikipedia having a Diversity Index value of 0.68, within the range of 0.65 and 0.80 that indicates a balanced state. We further support our findings with additional evaluations of other ecosystems including the predicted collapse of the information service known as the Digital Universe. This research allows for an information system’s stability to be (a) characterized and (b) predicted using ecological measures specific to the diversity of data within the ecosystem.