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1.
Bowen Lv Zhaoliang Qu Baosheng Xu Yiguang Wang Daining Fang 《Ceramics International》2021,47(12):16547-16554
A numerical model is developed for surface crack propagation in brittle ceramic coatings, aiming at the intrinsic failure of rare-earth silicate environmental barrier coating systems (EBCs) under combustion conditions in advanced gas turbines. The main features of progressive degradation of EBCs in such conditions are captured, including selective silica vaporization in the top coat due to exposure to water vapor, diffusion path-dependent bond coat oxidation, as well as crack propagation during cyclic thermal loading. In light of these features, user-defined subroutines are implemented in finite element analysis, where surface crack growth is simulated by node separation. Numerical results are validated by existing experimental data, in terms of monosilicate layer thickening, thermal oxide growth, and fracture behaviors. The experimentally observed quasi-linear oxidation in the early stage is also elucidated. Furthermore, it is suggested that surface crack undergoes rapid propagation in the late stage of extended thermal cycling in water vapor and leads to catastrophic failure, driven by both thermal mismatch and oxide growth stresses. The latter is identified as the dominant mechanism of penetration. Based on detailed analyses of failure mechanisms, the optimization strategy of EBCs composition is proposed, balancing the trade-off between mechanical compliance and erosion resistance. 相似文献
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某电力公司变电站用铝合金设备线夹在运行过程发生批次开裂事故,通过宏观观察、断口分析、化学成分分析、力学性能测试、冷冻模拟试验等方法,对设备线夹的开裂原因和开裂机理进行了分析。结果表明:设备线夹焊缝存在焊接缺陷,导致焊缝强度下降;设备线夹接线管底部存在积水空间,寒冷天气下积水结冰,体积膨胀,使焊缝承受设计工况外的负载而过载开裂,造成了线夹开裂。 相似文献
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AbstractA mechanical model of steel-concrete composite beams considering horizontal slip and vertical pull-out effects under negative bending moment was established based on the theory of elastic deformation. By using the principle of force equilibrium and deformation compatibility condition, the differential equation was derived and deduced using computational calculation program, in which the formula of the pull-out force in shear connectors under negative bending moment was obtained. The experiment was conducted in order to verify the reliability of theoretical results. The results show: under the same load condition, the pull-out force of a single stud increases with the increase of the stud spacing. All the theoretical results were verified by comparing with experiment results to illustrate the accuracy and reliability of the calculation method. It provides a theoretical reference for the study of the interface interaction considering horizontal slip and vertical pull-out effect in the negative bending moment region of continuous composite beams. 相似文献
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《Ceramics International》2022,48(17):24888-24897
In the furnace cycle test, the growth of oxide film leads to the propagation and coalescence of multiple cracks near the interface, which should be responsible for the spallation of thermal barrier coatings (TBCs). A TBC model with real interface morphology is created, and the near-interface large pore is retained. The purpose of this work is to clarify the mechanism of TBC spallation caused by successive initiation, propagation, and linkage of cracks near the interface during thermal cycle. The dynamic growth of thermally grown oxide (TGO) is carried out by applying a stress-free strain. The crack nucleation and arbitrary path propagation in YSZ and TGO are simulated by the extended finite element method (XFEM). The debonding along the YSZ/TGO/BC interface is evaluated using a surface-based cohesive behavior. The large-scale pore in YSZ near the interface can initiate a new crack. The ceramic crack can propagate to the YSZ/TGO interface, which will accelerate the interfacial damage and debonding. For the TGO/BC interface, the normal compressive stress and small shear stress at the valley hinder the further crack propagation. The growth of YSZ crack and the formation of through-TGO crack are the main causes of TBC delamination. The accelerated BC oxidation increases the lateral growth strain of TGO, which will promote crack propagation and coalescence. The optimization design proposed in this work can provide another option for developing TBC with high durability. 相似文献
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在利用飞秒激光对单晶硅材料进行微尺度烧蚀时,衍生的等离子体发光光斑中蕴含着大量的加工信息。如何有效提取光斑图像的几何特征信息,对研究飞秒激光烧蚀加工工艺过程具有重要意义。轮廓特征是描述激光光斑最重要的特征之一,本文着重分析了等离子体光斑轮廓特征与光斑运动规律间的关系及光斑运动情况分类方法。首先,考虑到光斑微弱的特性,对光斑图像进行增强处理。其次,采用链码方法提取光斑轮廓特征,并利用傅里叶描述子低频特性,选取少量的描述子重建光斑图像轮廓特征,减少了复杂的计算量,有效提高了光斑图像分类的速度与质量。最后,运用Hu不变矩特征证明傅里叶描述子用于提取激光光斑对轮廓特征的有效性。 相似文献
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以碱式碳酸镍、碱式碳酸锌、碱式碳酸铜和水泥为原料制备水泥负载的Cu-Ni,Cu-Zn,Cu-Ni-Zn催化剂,考察了合成催化剂的甲醇裂解反应性能。结果表明:在常压、质量空速为3.39 h-1、温度为380~420 ℃的条件下,Cu-Ni/水泥催化剂作用下的甲醇转化率均在96%以上;Cu-Zn/水泥催化剂作用下的甲醇转化率较低,但对H2和CO选择性较高;Cu-Ni-Zn/水泥催化剂经1 600 h运转,甲醇转化率和产物分布变化不大,甲醇转化率基本维持在81%以上,(H2+CO)摩尔分数大于98%,说明Cu-Ni-Zn/水泥催化剂具有良好的高温稳定性。 相似文献
10.
以废弃的流化催化裂化催化剂(简称SFCC)为载体、β-环糊精为金属络合剂、硝酸镍为镍源,采用湿法浸渍法制备β-环糊精修饰的Ni/SFCC催化剂(简称Ni/SFCC-CD催化剂),考察其对C9石油树脂的催化加氢性能。通过BET比表面积测试、H2程序升温还原、X射线光电子能谱等手段对催化剂的物相结构进行表征,研究β-环糊精的作用机理及其对催化剂加氢性能的影响。研究结果表明:在反应温度为260 ℃、反应压力为7 MPa、反应时间为2.0 h的最优条件下,采用Ni/SFCC-CD催化C9石油树脂加氢,可制得溴值为1.45 gBr/(100 g)、色号(加纳德)小于1的水白色氢化C9石油树脂,催化剂循环使用4次后仍保持良好活性;β-环糊精的作用机理是:β-环糊精与硝酸镍产生络合作用,抑制硝酸镍的分解、控制NiO的结晶过程和增强活性组分Ni与载体之间的相互作用力,从而提高了Ni/SFCC-CD的催化活性和稳定性。 相似文献