Zeolite synthesis from paper sludge ash with addition of diatomite

BACKGROUND: This study aimed to investigate the synthesis of zeolites from paper sludge ash (PSA) with added diatomite to remove both NH₄⁺ and PO₄^3? for water purification. The PSA had low Si and significant Ca contents. Four types of diatomite: white (T‐W) and brown (T‐B) from deposits of marine origin in Takanosu, and white (S‐W) and gray (S‐G) from lacustrine deposits in Shonai, were added to NaOH solution to increase the Si content and thereby synthesize zeolites with high cation exchange capacity (CEC). RESULTS: The order of the amounts of Si extracted from the diatomite to the alkali solution was S‐W > T‐W = T‐B > S‐G, which correlates with the amorphous SiO₂ content of diatomite. The original ash without addition of diatomite yielded hydroxysodalite with CEC of about 1.0 mmol g^?1. For all samples, the addition of diatomite to the solution yielded zeolite‐P with a higher CEC, but the addition of excess Si inhibited the synthesis of zeolite‐P, and the CEC of the product was low. A product with high CEC including zeolite‐P was obtained in a solution with around 500 mmol L^?1 of Si concentration, and had the ability to remove both NH₄⁺ and PO₄^3?. CONCLUSION: Diatomite has the potential for used as an additive for the synthesis of high CEC zeolite from PSA. The product with zeolite‐P exhibited relatively high CEC, capacity for NH₄⁺ uptake, and the ability to remove PO₄^3? by precipitation, which is preferable for water purification applications. Copyright © 2008 Society of Chemical Industry     

硅藻土涂层气孔率对大口径球铁管外表面凹陷缺陷的影响

本文主要从涂层结构 ,即涂层气孔的种类、数量论述其对大口径球铁管外表面凹陷缺陷的影响。从涂料雾化液滴大小、金属型温度、喷嘴距金属型内表面距离、喷嘴移动速度、涂料中膨润土含量、金属型转速等工艺参数来控制涂层气孔率 ,保证涂层透气性 ,从而消除凹陷缺陷     

以硅藻土为硅源制备SiC/堇青石复合多孔陶瓷的性能研究

以硅藻土为主要硅源,同时配合SiC、Al_2O_3、滑石粉末为主要原料,通过反应烧结技术制备SiC/堇青石复相多孔陶瓷,研究了不同原料配比对SiC/堇青石复相多孔陶瓷的相组成、显微结构、抗弯强度、气孔率的影响,同时在得出最优配比组的基础上,研究石墨造孔剂的含量、碳化硅颗粒粒径、孔径分布等因素对SiC/堇青石复相多孔陶瓷的影响。结果表明:当SiC与其余物料理论质量比为8∶2时,在1250℃下保温3h制备的样品综合性能最佳,其气孔率为37.721%,抗弯强度达到49.1887 MPa。     

国产硅藻土研究进展及其新应用

简介国产硅藻土结构，吸附性质等方面研究的进展，以及近年硅藻土的一些新应用。     

添加固体废弃物的硅藻土基多孔材料的制备

硅藻土作为主要基料,白云石为添加剂,加入其他固废物,制备了一种新型多孔材料。通过X射线衍射、扫描电镜及强度、吸水率等测试手段对制品进行了分析,探讨了硅藻土、白云石不同固体废弃物对多孔材料形成和性能的影响。研究表明,在硅藻土、白云石、粉煤灰、熟污泥的质量分数分别为45%、35%、10%、10%时,经1 020℃烧成并保温30min形成的多孔材料的密度为1.36g/cm3,孔隙率45%,吸水率为25%,抗折强度达12.43MPa,通过物相分析其多孔材料的成分主要晶相为莫来石与钙长石及透辉石。     

硅藻土胎模成形刀具设计

通过硅藻土胎模的加工实践,分析了硅藻土特点及其切削性能,设计了加工硅藻土胎模成型曲面的成形刀具,不但提高了胎模加工表面的质量,而且使硅藻土胎模成型曲面的加工效率提高了几十倍。     

聚丙烯酰胺无机物复合高吸水性树脂的合成

通过水溶液聚合法,以过硫酸盐为引发剂,N,N 亚甲基以丙酰胺为交联剂,添加不同含量的硅藻土,合成高吸水性树脂.并讨论了交联剂、引发剂、硅藻土等聚合条件对复合材料吸水性能的影响,制备出的材料具有较高的吸水性能和保水性,在降低产品生产成本以及提高材料综合性能方面具有使用价值.     

硅藻土粒径和含量对PVC木塑复合材料性能的影响

考察了硅藻土粒径、添加量对PVC木塑复合材料加工性能、表面状态及力学性能的影响.结果表明,粒径越小越有利于加工,复合材料的表面状态越好,拉伸强度越高；硅藻土添加量对复合材料的性能影响较大,在5～15质量份范围内,加工性能和力学综合性能较好.     

硅藻土在工业污水处理中的应用研究进展

吸附材料在工业污水处理中占有重要的地位.硅藻土具有独特的表面结构与优异的吸附性能,适合于作为吸附材料应用于各种工业污水的处理.在简单介绍硅藻土的基础上,综述了近年来国内外在硅藻土对工业废水中的染料、重金属离子及有机化合物等污染物吸附的研究进展,并展望了其未来的发展趋势.     

浙江硅藻土吸附性能的研究

测定了25℃时浙江硅藻土对苯的吸附等温线及吸附回线,硅藻土的孔径分布、硅藻土表面硅羟基SiOH数目,并讨论了吸附等温线及吸附回线与孔结构、表面SiOH数目之间的关系.