Time and space dependence of large-scale synthesis of colloidal particle with special morphology and tuneable polymer film architecture

This paper describes a facile method to control the morphology of polymer colloids and the architecture of polymer film via miniemulsion polymerization. By taking advantage of cyclization between the symmetrical diacrylate cross-linker hexamethylene diacrylate (HDDA) and the pendent vinyl in colloidal particles, the morphology of polymer colloids and the architecture of the after-formed polymer film were able to be well controlled by tuning the loading of cross-linker HDDA and crosslinking time. Four kinds of polymer colloid morphologies and four kinds of film architecture (honeycomb, close-packed, loose-packed, and enhanced-honeycomb) were characterized by TEM. The film formation mechanisms behind them were proposed based on the special and interesting results including Z-average size of the colloidal particles, Mc (molecular weight between crosslinking points) and mechanical properties of polymer film. Our results highly suggested that the morphology of polymer colloids and the polymer film architecture together determine the adhesive properties of the colloidal polymer film. The best of 180°-peel resistance, T-peel resistance and shear resistance of the polymer films were 138.12 N/25 mm, 40.98 N/25 mm and 25.72 N/cm² at 2.0 phm, 2.0 phm and 0.4 phm with the same crosslinking time of 90 min, respectively. The proposed method is promising to be scaled up for industrial production due to its well adaptability.     

Continuum model of two-dimensional crystal lattice of metamaterials

The continuum models of two-dimensional crystal lattice of metamaterial are investigated in this paper. The equivalent classical continuum requires the introduction of frequency-dependent mass density that becomes negative or infinite near the resonance frequency. In order to avoid the frequency-dependent mass density and make the dispersive characteristic of the elastic waves propagating in the equivalent continuum approximating that of lattice wave in two-dimensional crystal lattice of metamaterial, three kinds of continuum models, namely, the multiple displacements continuum model, the strain gradient continuum model and the nonlocal strain gradient continuum model, are investigated. It is found that the nonlocal gradient continuum model may better represent the dispersive relation and the bandgap characteristics of the metamaterial by the appropriate selection of nonlocal parameters.     

The correlation between porosity characteristics and the crystallographic texture in extruded stabilized aluminium titanate for diesel particulate filter applications

Porous ceramic diesel particulate filters (DPFs) are extruded products that possess macroscopic anisotropic mechanical and thermal properties. This anisotropy is caused by both morphological features (mostly the orientation of porosity) and crystallographic texture. We systematically studied those two aspects in two aluminum titanate ceramic materials of different porosity using mercury porosimetry, gas adsorption, electron microscopy, X-ray diffraction, and X-ray refraction radiography. We found that a lower porosity content implies a larger isotropy of both the crystal texture and the porosity orientation. We also found that, analogous to cordierite, crystallites do align with their axis of negative thermal expansion along the extrusion direction. However, unlike what found for cordierite, the aluminium titanate crystallite form is such that a more pronounced (0 0 2) texture along the extrusion direction implies porosity aligned perpendicular to it.     

Can synchronicity and visual modality enhance social presence in mobile messaging?

As companies move increasingly toward text-based computer-mediated communications (CMC) for providing customer service, they tend to lose out on the social presence of a live agent interacting in person or via the telephone. Given the importance of social presence for maintaining healthy customer relations, how can companies counter the relative lack of social presence in CMC? Increasing the synchronicity of communications is one solution, but it is not always possible to provide instant responses to customers. In such cases, can a richer modality (e.g., picture of the customer-service agent) make up for diminished synchronicity and thereby enhance social presence? We addressed these questions with a 3 [synchronicity: high (no delay in response time) vs. medium (1-h delay) vs. low (6-h delay)] × 3 [modality: text-only vs. text+picture vs. text+emoticon] ful factorial, between-subjects experiment in which participants (N = 108) interacted with a customer service agent in a mobile e-commerce context. Data reveal that participants in high synchronicity and text+emoticon conditions felt higher social presence and perceived the customer service agent more positively than those in other conditions. Social presence and task impression mediated the relationship between each independent variable and their evaluations of the customer service agent.     

中文基本复合名词短语语义关系体系及知识库构建

名词短语一直是中外语言学领域的重要研究对象,近年来在自然语言处理领域也受到了研究者的持续关注。英文方面,已建立了一定规模的名词短语语义关系知识库。但迄今为止,尚未建立相应或更大规模的描述名词短语语义关系的中文资源。该文借鉴国内外诸多学者对名词短语语义分类的研究成果,对大规模真实语料中的基本复合名词短语实例进行试标注与分析,建立了中文基本复合名词短语语义关系体系及相应句法语义知识库,该库能够为中文基本复合名词短语句法语义的研究提供基础数据资源。目前该库共含有18 281条高频基本复合名词短语,每条短语均标注了语义关系、短语结构及是否指称实体等信息,每条短语包含的两个名词还分别标注了语义类信息。语义类信息基于北京大学《现代汉语语义词典》。基于该知识库,该文还做了基本复合名词短语句法语义的初步统计与分析。     

Strain hardening behaviors and mechanisms of polyurethane under various strain rate loading

The uniaxial tension experiments are performed on thermoplastic polyurethane to investigate its mechanical behaviors and related potential mechanisms, and the loading strain rate is designing to be wide ranging from 0.0001 to 1 s⁻¹. It is found that the polyurethane presents an obvious rate-dependence, and the stress strain curves share distinct strain hardening characteristics under the investigated strain rates. Furthermore, the strain hardening ratios are sharing nearly same trends and appear to be influenced by both strain rate and the induced adiabatic heating. Besides, the ratio is also strain-dependent on previous loading history. Then, a two-dimension unit cell model is built to investigate potential equivalent mechanisms, of which the hard phase as inclusion is equivalent with crystallization zone, crosslinking sites, and so forth. The simulation results facilitate to explain the distinct strain hardening ratios, even for the matrix from the extrapolated curves under super-low strain rate loading. Finally, the analogic mechanisms of equivalent hard inclusions are proposed, which can reasonably explain the strain rate- and strain-dependence characteristics of polyurethane mechanical behaviors.     

Scientists as political experts: Atomic scientists and their claims for expertise on international relations, 1945–1947

This paper explores the construction of scientists' expertise on international affairs through a study of the rhetoric of U.S. atomic scientists during public and policy‐making debates on the international control of atomic energy between 1945 and 1947. It explores the claims scientists made about the nature of their expertise on issues of diplomacy and international relations and how their expertise was produced and reproduced. The paper shows that scientists were able to successfully project themselves, in the public domain, as experts on political and diplomatic matters related to the atomic. In calling for the international control of atomic energy, scientists constructed their expert knowledge in contrast to, as they portrayed it, the failed expertise of diplomats and political thinkers. In boundary work through their speeches, articles, and government testimonies, scientists drew a line between the political and the scientific, but argued that, as scientist‐citizens, they were able to take their rational thinking from one realm into the other.     

What do stakeholders think about knowledge transfer offices? The perspective of firms and research groups in a regional innovation system

Knowledge transfer offices (KTOs) are required to adopt a comprehensive approach to managing a broad set of channels of university–industry collaboration, including collaborative research, business services, exchange of human resources and informal relations within a regional innovation system. The perspectives of firms and academic researchers, the main stakeholders of KTOs, are useful complements to assess KTO activity. The goal of this article is to study the effectiveness that these stakeholders attribute to KTOs. Based on survey data collected in the Spanish region of Andalusia, the article explores stakeholders’ perceptions and determinants. The results show that the level of engagement in a diversified range of activities and the importance attributed to knowledge transfer in the strategy of both research groups and firms are the best predictors of the perceived effectiveness of KTOs. The article also underlines specific differences between the two types of stakeholders.     

Phase equilibria in the CaO·SiO2Na2O·SiO2Na2O·Al2O3·6SiO2 system

Equilibrium phase relations in the system CaO·SiO₂Na₂O·SiO₂Na₂O·Al₂O₃·6SiO₂ at 40–80 wt% Na₂O·Al₂O₃·6SiO₂ composition range have been experimentally studied at temperatures between 800 °C and 1200 °C. The liquidus temperature was determined with differential scanning calorimetry. The equilibrated samples were quenched with pressurized nitrogen, and examined with electron probe X-ray microanalysis and X-ray diffraction for identification of microstructure and phase relations. Five primary phase fields, CaO·SiO₂, Na₂O·SiO₂, Na₂O·2CaO·3SiO₂, 2Na₂O·CaO·3SiO₂ and Na₂O·Al₂O₃·6SiO₂ were established. The ternary eutectic point of CaO·SiO₂, Na₂O·2CaO·3SiO₂ and Na₂O·Al₂O₃·6SiO₂ was determined to be at 1030 °C with the composition of 29.0 wt% CaO·SiO₂, 12.0 wt% Na₂O·SiO₂ and 59.0 wt% Na₂O·Al₂O₃·6SiO₂. Peritectic reaction of Na₂O·2CaO·3SiO₂, 2Na₂O·CaO·3SiO₂ and Na₂O·Al₂O₃·6SiO₂ occurred at 930 °C with the composition of 13.0 wt% CaO·SiO₂, 29.0 wt% Na₂O·SiO₂ and 58.0 wt% Na₂O·Al₂O₃·6SiO₂. The liquidus surface projection of the ternary system has been constructed in the composition region important for the bottom ash application.