Improved thermal stability of the near-infrared Al-modulated Zn3Ga2GeO8: Cr3+ phosphors for plant growth applications

The exploration of the high thermal stability near-infrared (NIR) phosphors is significantly crucial for the development of plant lighting. However, NIR phosphors suffer from the poor chemical and thermal stability, which severely limits their long-term operation. Here, the successful improvement of luminous intensity (149.5%) and thermal stability at 423 K of Zn₃Ga₂GeO₈ (ZGGO): Cr³⁺ phosphors is achieved for the introduction of Al³⁺ ions into the host. The release of carriers in deep traps inhibits the emission loss for the thermal disturbance. Furthermore, an NIR light emitting diodes (LEDs) lamp is explored by combining the optimized Zn₃Ga_1.1675Al_0.8GeO₈: 0.0325Cr³⁺ phosphors with a commercial 460 nm blue chip, and the emission band can match well with the absorption bands of photosynthetic pigments and the phytochrome (P_R and P_FR) of plants. The explored LEDs lamp further determines the growth and the pheromone content of the involved plants for the participation of the NIR emission originated from Cr³⁺ ions. Our work provides a promising NIR lamp as plant light with improved thermal stability for long-term operation.     

Far-red-emitting YAl3(BO3)4:Cr3+ phosphors with excellent thermal stability and high luminescent yield for plant growth LEDs

Phosphors-converted LEDs (pc-LEDs) are excellent artificial light sources for indoor plant cultivation, in which the far-red-emitting component (700−780 nm) plays an important role in regulating the photomorphogenesis of plants. Accordingly, highly efficient and thermally stable far-red-emitting phosphors are indispensable for developing high-performance plant cultivation pc-LEDs. Herein, far-red-emitting YAl₃(BO₃)₄:Cr³⁺ (YAB:Cr³⁺) phosphors were synthesized by solid-state reaction, and their photoluminescence characteristics, thermal quenching, quantum yield (QY), and application in pc-LEDs were systematically investigated. The YAB:Cr³⁺ phosphor has an intense broadband absorption to the blue light, simultaneously exhibiting the sharp-line ²E emission and the broadband ⁴ T₂ emission of Cr³⁺ with a QY of ~86.7%. The far-red broadband emissions of YAB:Cr³⁺ centered at ~735 nm show a high resemblance to the active-state (P_FR) absorption of plant phytochrome. Moreover, the YAB:Cr³⁺ phosphor shows the thermally enhanced luminescence at temperatures of 303−393 K and the near-zero thermal quenching up to 423 K. The anomalous thermal enhancement is attributed to the temperature-dependent repopulation between ²E and ⁴ T₂ states. Finally, a pc-LED device was fabricated with the YAB:Cr³⁺ phosphor and blue chip, exhibiting the light out power of ~50.6 mW and energy conversion efficiency of ~17.4% at 100 mA drive current, respectively. The exceptional PL features including suitable excitation/emission wavelengths, suppressed thermal quenching and high QY make YAB:Cr³⁺ phosphors very promising for applications in plant growth pc-LEDs.     

多堆厂址始发事件分析探讨

多堆厂址一级概率安全评价（PSA）研究中，机组数目的增加使得建模工作量剧增，给整个核电厂的风险评估带来困难。结合已有基础，本文研究了多堆厂址始发事件分析的筛选方法，提出利用堆芯损伤频率（CDF）上下限值评估方法，分析厂址内不同机组数对厂址CDF的影响。结果表明，双机组厂址适合优先进行具体分析。针对双机组核电站，对多堆厂址内各始发事件进行筛选。结果表明，丧失厂外电、丧失热阱等事件适合建模分析，并对其他筛选结果给出后续分析建议，为多堆厂址一级PSA后续事故序列建模工作提供了重要基础。     

Physicochemical and thermophysical properties of CaO–TiO2–SiO2–Na3AlF6 system based electrode coating for AUSC power plant

The aim of this study is to investigate the physicochemical and thermophysical properties of CaO–TiO₂–SiO₂–Na₃AlF₆ based electrode coating developed for the welding of advanced ultra-supercritical (AUSC) thermal power plant components. The extreme vertices approach has been used to create twenty-six electrode coating compositions. Various physicochemical and thermophysical properties were characterized using experiments. The coating properties are essential in ensuring sound weld with desirable in-service performance. The developed coating's structural behavior was analyzed using Fourier transformation infrared spectroscopy (FTIR) and X-ray diffraction (XRD). In addition, regression analysis was carried out to evaluate the influence of coating constituents. Individual constituents and their interaction were found to have a prominent role in influencing the physicochemical and thermophysical properties.     

Nature inspired 21 branches sneezewort/Achillea ptarmica plant growth pattern–shaped antenna for Ku‐band applications

This reported paper presents the design and analysis of wideband nature inspired planar antenna of 46 × 18 × 1.6 mm³ size, designed using FR4 (Flame Retardant) substrate. The antenna patch is delineated from the growth pattern of sneezewort plant with supplementary notion of golden ratio in branching and branch width. The total number of branches in each stage follows the Fibonacci series and the branch width is calculated from the golden ratio concept. Starting from one feed line and two branches, the maximum numbers of branches are increased to 20. There has been significant enhancement in the radiation performance of proposed geometry by increasing the number of branches to 21 and by modifying ground with T‐shaped slot. The antenna covers wide impedance bandwidth of 8.2 to 16.5 GHz by possessing stable radiation characteristics.     

生物质电厂废弃物草木灰成分分析及成形

生物质热电厂焚烧废弃物的主要成分是草木灰，其产生量大、密度小。大量草木灰不经处理会造成环境污染问题。本文首先分析草木灰的化学成分，确定草木灰的肥料特征，通过添加NH₄H₂PO₄使草木灰的pH达到国家复合肥的相关标准。选用聚天冬氨酸（30%水溶液）作为复合肥的黏结剂，应用于草木灰复合肥的成形造粒，以增加其抗压强度和肥效。研究不同烘干时间、烘干温度、聚天冬氨酸添加量对草木灰复合肥抗压强度的影响规律，通过分析植物的形态及生理指标，进而研究草木灰复合肥的肥效。结果表明：最佳烘干条件为10h、140℃，聚天冬氨酸对草木灰的抗压强度有明显的增强作用，并且草木灰与聚天冬氨酸的复配比为6g∶1mL时肥效最好。此方法解决了元素循环中断、草木灰环境污染，在运输过程中草木灰复合肥易碎，纯草木灰肥效低等问题。     

腐蚀对模块式钢结构选煤厂设备支架振动响应影响的测试及分析

选煤厂采用模块式钢结构作为设备支架,受设备使用及养护不当造成结构构件严重腐蚀,构件截面削弱,导致结构产生过大振动,通过对结构各层振动响应测试,得到各测点水平向及竖直向振动速度幅值。经分析得出腐蚀后对结构整体刚度影响程度,为后期采取措施及安全生产提供依据。     

药食同源植物丁香各部位抗营养因子分析

结合食品饲料安全国家标准以及文献方法,对药食同源丁香植株花蕾、果实、枝、叶部位的抗营养因子进行研究分析。结果表明:丁香花蕾、果实、枝、叶各部位的主要抗营养因子含量均处于食品或饲料的正常范围。植酸含量果实最低为33.24 mg/g。胰蛋白酶抑制剂活性各部位较接近,其中果实含量最高为44.2 mg/g。植物凝集素含量叶最低,微凝血试验中果实和叶表现出微弱的凝血反应。单宁酸含量枝最低,草酸含量花蕾最低。可溶性非淀粉多糖含量果实最低,含量为0.278 mg/g。从几类主要抗营养因子含量来看,各部位含量均较接近,且各抗营养因子在各部位中的含量趋势都有所不同且各有高低。