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1.
《Advanced Powder Technology》2022,33(9):103722
Through a facile hydrothermal method, we have successfully prepared Ti3C2/Bi2.15WO6 (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi2.15WO6 and Ti3C2. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min?1, which is higher than that of pure BWO (30% and k = 0.0005 min?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti3C2 is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light. 相似文献
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《International Journal of Hydrogen Energy》2022,47(85):36216-36231
The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB. 相似文献
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《International Journal of Hydrogen Energy》2022,47(67):28782-28793
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production. 相似文献
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分析空巷破坏形式及治理难点,确定虎龙沟煤业81511工作面采用超高水材料充填过空巷的技术方案,阐述超高水材料空巷充填的作用机理、工艺和关键技术。现场应用后,未出现片帮、冒顶及压架事故,保障了81511工作面的正常安全回采。 相似文献
7.
超临界二氧化碳是一种特殊的流体,具有粘度低、扩散系数大、密度大和溶解性较好等特点,因此被认为是第四代核反应堆能量传递的首选材料。由于核反应堆的工作环境十分苛刻,超临界二氧化碳应用于核反应堆系统中易造成材料腐蚀,为确保核反应堆安全有效地运行,对超临界二氧化碳腐蚀行为进行系统研究,介绍了核反应堆的发展历程,重点探讨超临界二氧化碳对合金材料腐蚀的机理,详细阐述了温度、压力、杂质和流速等因素对材料在超临界二氧化碳中腐蚀行为的影响,针对目前的研究提出了亟待解决的问题。 相似文献
8.
基于加权Ashby选材法及车门结构设计关键性能分析,总结了与质量,成本相关的材料效率计算公式,并分别绘制了材料的密度-弹性模量、密度-屈服极限、对数形式密度成本-弹性模量、对数形式密度成本-屈服极限Ashby图,通过区域划分建立了相应的评分体系。根据所得材料效率,结合专家评分方法,获得了备选材料库中每种材料子性能的得分以及材料综合性能得分,再根据得分结果选出最佳材料设计方案。结合具体车门外板结构对材料方案进行了抗凹性能验证,结果表明此方法对车门外板的选材设计具有重要的指导意义。 相似文献
9.
基于生物酶的专一性、高效性和环境友好性,生物技术在制浆造纸工业中已获得了广泛应用,并取得了良好的经济和环保效益。采用生物酶预处理木质纤维原料不仅可以改善纤维形态、提高纸浆性能、降低磨浆能耗、提高生产效率,而且能够缓解传统制浆造纸工业面临的环境污染问题,为造纸行业的绿色转型发展提供更多可能。但目前生物酶技术在木质纤维原料预处理工段的应用还存在一些不足,如生物酶在各种环境下如何保持活性、生物酶成本高、处理条件苛刻及反应时间长等均是实际生产中需要解决的问题。本文综述了果胶酶、木聚糖酶、纤维素酶及木质素降解酶等生物酶预处理木质纤维原料的理论与技术研究进展,以期为解决上述问题并使生物酶预处理技术在制浆造纸工业化生产中达到高效利用提供一定参考与思路。 相似文献
10.
Nonintrusive load monitoring (NILM) is crucial for extracting patterns of electricity consumption of household appliance that can guide users’ behavior in using electricity while their privacy is respected. This study proposes an online method based on the transient behavior of individual appliances as well as system steady-state characteristics to estimate the operating states of the appliances. It determines the number of states for each appliance using the density-based spatial clustering of applications with noise (DBSCAN) method and models the transition relationship among different states. The states of the working appliances are identified from aggregated power signals using the Kalman filtering method in the factorial hidden Markov model (FHMM). Thereafter, the identified states are confirmed by the verification of system states, which are the combination of the working states of individual appliances. The verification step involves comparing the total measured power consumption with the total estimated power consumption. The use of transient features can achieve fast state inference and it is suitable for online load disaggregation. The proposed method was tested on a high-resolution data set such as Labeled hIgh-Frequency daTaset for Electricity Disaggregation (LIFTED) and it outperformed other related methods in the literature. 相似文献