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《International Journal of Hydrogen Energy》2022,47(59):24843-24851
Lithium alanate (LiAlH4) is a material that can be potentially used for solid-state hydrogen storage due to its high hydrogen content (10.5 wt%). Nevertheless, a high desorption temperature, slow desorption kinetic, and irreversibility have restricted the application of LiAlH4 as a solid-state hydrogen storage material. Hence, to lower the decomposition temperature and to boost the dehydrogenation kinetic, in this study, we applied K2NiF6 as an additive to LiAlH4. The addition of K2NiF6 showed an excellent improvement of the LiAlH4 dehydrogenation properties. After adding 10 wt% K2NiF6, the initial decomposition temperature of LiAlH4 within the first two dehydrogenation steps was lowered to 90 °C and 156 °C, respectively, that is 50 °C and 27 °C lower than that of the аs-milled LiAlH4. In terms of dehydrogenation kinetics, the dehydrogenation rate of K2NiF6-doped LiAlH4 sample was significantly higher as compared to аs-milled LiAlH4. The K2NiF6-doped LiAlH4 sample can release 3.07 wt% hydrogen within 90 min, while the milled LiAlH4 merely release 0.19 wt% hydrogen during the same period. According to the Arrhenius plot, the apparent activation energies for the desorption process of K2NiF6-doped LiAlH4 are 75.0 kJ/mol for the first stage and 88.0 kJ/mol for the second stage. These activation energies are lower compared to the undoped LiAlH4. The morphology study showed that the LiAlH4 particles become smaller and less agglomerated when K2NiF6 is added. The in situ formation of new phases of AlNi and LiF during the dehydrogenation process, as well as a reduction in particle size, is believed to be essential contributors in improving the LiAlH4 dehydrogenation characteristics. 相似文献
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《Journal of dairy science》2022,105(6):5471-5492
The detection of reproductive tract disease (RTD) 3 wk postpartum is important because of its effect on subsequent reproductive outcomes. Numerous methods for the diagnosis of RTD are described, some of which are more practical and instantaneous in terms of diagnosis. Two of these methods involve identification of purulent vaginal discharge (PVD) and evidence of ultrasonographic uterine changes indicative of endometritis (UE). The objectives of our retrospective observational study were (1) to assess the association of PVD or UE score at the prebreeding examination (PBE) with the hazard of pregnancy within the subsequent breeding season; (2) to determine the test sensitivity (Se) and specificity (Sp) at the point of sampling of both tests using a Bayesian latent class model; and (3) to determine the effect of varying positivity thresholds on test accuracy. To achieve these objectives, we analyzed an initial data set of 5,049 PBE from 2,460 spring-calved cows in 8 herds between 2014 and 2018. Each PBE was conducted once between 25 and 86 d in milk. At each PBE, vaginal discharge was obtained with a Metricheck device (Simcro) whereas uterine contents were assessed using transrectal ultrasonography. Purulent vaginal discharge was scored on a scale of 0 to 3 depending on discharge character, and UE was scored on a scale of 0 to 4 depending on the presence and consistency of intraluminal fluid. Cows with scores of ≥2 in either test had received treatment. Fertility data were available from 4,756 PBE after data exclusion. The association between PVD or UE score at the PBE and subsequent hazard of pregnancy was analyzed using a Cox proportional hazards model. Cows with a PVD score of 2 or 3 were less likely to conceive than cows with a PVD score 0 [score 2 hazard ratio (HR) = 0.74; 95% confidence interval (CI): 0.59–0.94; score 3 HR = 0.65; 95% CI: 0.51–0.84]. Cows with a UE score of 1, 2, 3, or 4 were less likely to conceive than cows with a UE score of 0 (score 1 HR = 0.82; 95% CI: 0.73–0.93; score 2 HR = 0.79; 95% CI: 0.62–1.00; score 3 HR = 0.43; 95% CI: 0.43–0.90; score 4 HR = 0.39; 95% CI: 0.26–0.58). To determine the Se and Sp of PVD or UE score for diagnosis of RTD at the time of PBE, a Bayesian latent class model was fitted on 2,460 individual cow PBE. Flat priors were used for the Se and Sp of UE, whereas informative priors were used for PVD Se (mode = 65%, 5th percentile = 45%) and Sp (mode = 90%, 5th percentile = 80%) and RTD prevalence (mode = 20%, 5th percentile = 10%). Posterior estimates (median and 95% Bayesian probability intervals; BPI) were obtained using ‘rjags' (R Studio). The optimal test thresholds (PVD and UE score ≥1) were selected by assessing the effect of different thresholds on test estimates and using a misclassification cost analysis. Based on these, median (95% BPI) Se for PVD and UE score ≥1 were 44% (29–60%) and 67% (33–100%), respectively. Median Sp for PVD and UE score ≥1 were 90% (86–93%) and 91% (86–93%), respectively. Higher scores in both tests were associated with impaired fertility, and UE scoring with a threshold of ≥1 had the highest test Se and Sp estimates although test Se was conditional on days in milk when the PBE occurred. 相似文献
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诱导式卫星欺骗干扰可诱导航空器逐渐偏离预定航迹,难以被发现,因此及时有效地检测干扰是飞行安全的保障。在现有紧组合导航体制基础上,设计了一种基于误差估值累加开环校正的紧组合导航结构,并证明了其性能与传统闭环校正紧组合导航性能等效。在此结构中,将紧组合导航系统与自适应序贯概率比检测方法结合,提出了一种基于误差估值累加开环校正的诱导式欺骗检测方法,融合紧组合导航信息与其他不受欺骗影响的导航信息,构建欺骗检测统计量进行诱导式欺骗检测。仿真结果表明,开环校正结构可避免随时间累加的惯性导航系统误差所导致的组合导航滤波器发散问题,同时欺骗检测方法可进一步提高算法对“最坏”情形下微小诱导式欺骗的检测效果。 相似文献
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《Ceramics International》2022,48(2):1889-1897
SiC fiber reinforced ceramic matrix composites (SiCf-CMCs) are considered to be one of the most promising materials in the electromagnetic (EM) stealth of aero-engines, which is expected to achieve strong absorption and broad-band performance. Multiscale structural design was applied to SiCf/Si3N4–SiOC composites by construction of micro/nanoscale heterogeneous interfaces and macro double-layer impedance matching structure. SiCf/Si3N4–SiOC composites were fabricated by using SiC fibers with different conductivities and SiOC–Si3N4 matrices with gradient impedance structures to improve impedance matching effectively. Owing to its unique structure, SiCf/Si3N4–SiOC composites (A3-composites) achieved excellent EM wave absorption performance with a minimum reflection coefficient (RCmin) of ?25.1 dB at 2.45 mm and an effective absorption bandwidth (EAB) of 4.0 GHz at 2.85 mm in X-band. Moreover, double-layer SiCf/Si3N4–SiOC with an improved impedance matching structure obtained an RCmin of ?56.9 dB and an EAB of 4.2 GHz at 3.00 mm, which means it can absorb more than 90% of the EM waves in the whole X-band. The RC is less than ?8 dB at 2.6–2.8 mm from RT to 600 °C in the whole X-band, displaying excellent high-temperature absorption performance. The results provide a new design opinion for broad-band EM absorbing SiCf-CMCs at high temperatures. 相似文献
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《Ceramics International》2022,48(3):3669-3675
ZnAl2O4 nanocrystalline particles were prepared using the solution combustion method using a new combustion fuel, Leucine. The prepared samples' structural, microstructural–elemental composition, and optical characteristics were investigated using XRD, SEM-EDS, and UV–Visible spectroscopy. As-synthesized ZnAl2O4 nanoparticles are polycrystalline, with no secondary phases, and crystallized in a cubic - spinel structure. The polycrystalline nature of the prepared sample is due to the exothermicity of fuel and oxidizer, which demonstrate that the fuel utilized (Leucine) provided adequate energy for the production of nanoparticles in their as-synthesized form, as supported by adiabatic temperature through thermodynamic calculations. The thermodynamic calculations also include a universal method to estimate the specific heat capacity at constant pressure. Furthermore, even after 2 h of calcination at 600 °C, ZnAl2O4 exhibits a single phase with no secondary phases, indicating the material stability and single-phase nature. The crystallinity of ZnAl2O4 nanoparticles was observed to increase with increasing annealing temperature. SEM micrographs of as-synthesized samples exhibit the formation of dense particles, voids, and pores in the as-synthesized sample. In addition, tiny aggregates were detected on the surface of more prominent clusters, which reduced as the calcination progressed. In addition, calcined samples exhibit a greater optical reflectance than as-synthesized samples. Tauc's graphs were used to compute the optical energy bandgap. The calculated energy band gap is redshifted to that of the bulk material. The bandgap energy decreases upon calcination, suggesting that the prepared materials have a larger crystallite size or more crystallinity. Correlations were found between the Tad, and the structural and optical properties of the prepared samples. The findings suggest that Leucine could be used as a novel combustion fuel to produce crystalline ZnAl2O4 nanoparticles in their as-synthesis form. 相似文献
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《International Journal of Hydrogen Energy》2022,47(38):17056-17068
The study of steels which guarantee safety and reliability throughout their service life in hydrogen-rich environments has increased considerably in recent years. Their mechanical behavior in terms of hydrogen embrittlement is of utmost importance. This work aims to assess the effects of hydrogen on the tensile properties of quenched and tempered 42CrMo4 steels. Tensile tests were performed on smooth and notched specimens under different conditions: pre-charged in high pressure hydrogen gas, electrochemically pre-charged, and in-situ hydrogen charged in an acid aqueous medium. The influence of the charging methodology on the corresponding embrittlement indexes was assessed. The role of other test variables, such as the applied current density, the electrolyte composition, and the displacement rate was also studied. An important reduction of the strength was detected when notched specimens were subjected to in-situ charging. When the same tests were performed on smooth tensile specimens, the deformation results were reduced. This behavior is related to significant changes in the operative failure micromechanisms, from ductile (microvoids coalescence) in absence of hydrogen or under low hydrogen contents, to brittle (decohesion of martensite lath interfaces) under the most stringent conditions. 相似文献