Studies of structure and cycleability of LiMn2O4 and LiNd0.01Mn1.99O4 as cathode for Li-ion batteries

Lithium manganese oxides LiMn₂O₄ and rare earth elements doped LiNd_0.01Mn_1.99O₄ were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd³⁺ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability.     

FPGA的动力电池检测系统研究

为提高动力电池使用效率,提出了一种基于FPGA的动力电池检测系统的设计方案.采用AD转换芯片实现对电池电压、电流的采集,数字温度传感器对温度进行采集,再通过软件实现对数据的处理和实时显示.系统运行稳定,数据处理能力强,集成度高,易于扩展.     

Preparation of lithium-ion polymer battery using LiNi1/3Co1/3Mn1/3O2 as a cathode material and its electrochemical properties

In this work, LiNi_1/3Mn_1/3Co_1/3O₂ powders were synthesized from co-precipitated spherical metal hydroxide. In the voltage range of 2.8–4.2, 2.8–4.4, and 2.8–4.6 V, the discharge capacities of LiNi_1/3Mn_1/3Co_1/3O₂ electrode were 163, 177, and 193 mAh⋅g⁻¹, respectively. A gel polymer electrolyte (GPE) was also prepared using polyoxyalkylene glycol acrylate (POAGA) as a macromonomer. LiNi_1/3Mn_1/3Co_1/3O₂/GPE/graphite cells were prepared and their electrochemical properties were evaluated at various current densities and temperatures. The ionic conductivity of the GPE was more than 6.2 × 10⁻³ S⋅cm⁻¹ at room temperature. POAGA-based cells were showed good electrochemical performances such as rate capability, low-temperature performance, and cycleability.     

一种环保化学储能电池——钒氧化还原液流电池

可再生能源需要性能优良的储能电池与之配套，因此，研究和开发价廉、高效率的储能系统是十分必要的。本文通过介绍钒氧化还原液流电池的原理和特点，指出钒电池是一种潜力巨大的新型环保储能电池。同时介绍钒电池制备和应用时的三大技术关键及一定的解决方法。     

全钒液流电池隔膜在钒溶液中的性能

考察了Nafion、日-160、日-80、FYM(日本产Nafion膜)和均相膜5种离子交换膜的两个关键性能(渗透性和面电阻)及其影响因素,对均相膜的化学稳定性进行了初步研究,并对两种膜进行了改性。实验发现:均相膜的钒扩散系数最小,但面电阻较大,化学稳定性不好;用二乙烯苯(DVB)对均相膜改性,综合性能较好;减小电场可降低钒离子扩散,提高钒溶液中氢离子浓度可减小面电阻。     

光伏储能用VRLA蓄电池的设计与开发

对于光伏储能用VRLA蓄电池的设计与开发,要严格按照产品的使用环境情况进行分析,有针对性地调整配方、工艺控制参数、正负极板的设计比例等,以满足光伏储能用铅酸蓄电池的要求.     

中空海胆状结构的碳包覆Fe2O3用作锂离子电池的高性能负极材料

Fe2O3由于成本低廉,储量丰富和理论比容量高(1007 mA hg^-1)等特点,在锂离子电池负极材料的应用中极具发展前景.然而一些问题仍然存在,如:充放电过程中比容量的迅速衰减,不可逆的体积膨胀以及较短的循环寿命等.这些问题严重制约了Fe2O3在锂离子电池中的实际应用.为了突破这些局限,本文以金属-有机骨架(MOF...     

Al4B2O9纳米棒改性制备优异综合性能的固体聚合物电解质

随着储能设备和电力驱动产品的激增,特别是电动汽车的大规模推广应用,全固态电池被认为是最有可能解决电动设备日益严峻的安全问题和高能量密度需求的策略之一.本文报道了一种Al4B2O9纳米棒改性的聚环氧乙烷(PEO)基固体聚合物电解质(ASPE),其具有高离子电导率、宽电化学窗口、良好的机械性能和阻燃性能.具体来说,因为Al...     

铅酸蓄电池设计系统软件的开发

为了对密封铅酸蓄电池的开发进行全程辅助支持,开发了阀控式密封铅酸蓄电池(VRLA)辅助设计软件——电池设计系统(BDS)。在BDS软件中,除了常规的开发功能外,还增加了槽体设计和失水估算功能。为维护设计数据的一致性,引进了参数设置、数据文件共享功能。通过设计向导、联机帮助、窗口提示、全面的快捷操作和统一的界面设计等,可以提供一个良好的开发环境。软件的开发功能和联机帮助均可以随时根据需要进行定制或者添加新的内容。     

LiCoxMnyNi1-x-yO2电极材料的研究进展

LiCoxMnyNi1-x-yO2电板材料是当前锂离子电池新一代正板材料的研究热点之一。介绍了锂离子电池正板材料LiCoxMnyNi1-x-yO2的结构与性能,总结了制备方法、制备工艺参数对其性能的影响,对LiCoxMnyNi1-x-yO2的掺杂改性作了综述,并对锂离子电池正板材料的发展方向作了展望。