Effects of Carbon Fillers on Crystallization Properties and Thermal Conductivity of Poly(phenylene sulfide)

Differential scanning calorimetry and polarized optical microscopy methods were used to investigate the crystallization behavior and isothermal crystallization kinetics of poly(phenylene sulfide) (PPS)/carbon nanotube (CNT) and PPS/CNT/carbon fiber (CF) composites. In this article, the influences of CNT and CF on PPS crystallization behavior are explained. The thermal conductivity properties of composites were studied using the laser flash method. The results show that CNT increased crystallization temperature and rate and thermal conductivity greatly improved at 8 wt.% CNT content. In addition, the crystallization and thermal performance of PPS are significantly improved via synergistic effects of CNT and CF in the composites.     

Material response characterization of a low-density carbon composite ablator in high-enthalpy plasma flows

Future space exploration missions beyond Earth’s orbit, such as sample returns from Mars, will use ablative materials for the thermal protection system in order to shield the spacecraft from the severe heating during reentry. In this paper, we present the results of an elaborate test campaign on a lightweight carbon composite ablator with the aim of defining a procedure for material response characterization in a 1.2-MW inductively heated Plasmatron facility, suitable to reproduce the hypersonic flight boundary layer environment. Three different test gases were used, air, nitrogen, and argon, at surface temperatures exceeding 3300 K. A comprehensive experimental setup was developed including a nonintrusive technique to measure surface recession by means of a high-speed camera. Surface degradation was strongly test gas dependent, while mass loss was mainly driven by in-depth decomposition of phenolic resin. Emission spectroscopy helped us identify C₂ as a product of dissociating hydrocarbons, as well as cyanogen, suggesting surface nitridation. Melt flow at the surface and silicon emission indicated degradation of the glass microspheres used as additional filler. In air plasma, oxidation was inferred to be the main mechanism for ablation.     

TPS/TDC3000系统串口通讯的规划与应用

针对TPS/TDC30 0 0系统串口通讯方式、机理进行了一般性的介绍 ,对规划与应用中常见的的问题 ,根据实际工程应用经验提出了解决方案。     

Interface between electroless amorphous Ni–Cu–P coatings and Al substrate

The initial phase arising at the interface with aluminum substrate during electroless deposition of amorphous high phosphorus (16–19 at.%) Ni–Cu–P alloy with alloyed copper 1.7–3.4 at.% is studied. Stripped deposit foils are inspected by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy coupled with energy dispersive X-ray analysis (TEM-EDX). Depending on the plating conditions, various particles, some of them crystalline, are revealed at the foils sides formerly adhering to the substrate. EDX analysis of the crystallites shows diverse copper contents of about 34–64 at.%, without any phosphorus. Electron diffraction analysis indicates a lattice structure very close to that of Cu. The presence of a phase without phosphorus and enriched in copper at the interface with the Al substrate is also confirmed by Auger electron spectroscopy. This initially arising crystalline phase might exert a limited effect on the main properties of bulk Ni–Cu–P deposits: the composition uniformity through the thickness, amorphous structure and paramagnetic behavior. A modification of the plating process is recommended, which is decreasing the probability of inhomogeneities formation.     

A wall jet electrode reactor and its application to the study of electrode reaction mechanisms Part II: A general computational method for the mass transport problems involved

A numerical computational method to solve the problems of mass transport to the impinged surface of a wall-jet electrode reactor is put forward, thus providing the necessary tool for a quantitative electrochemical investigation of the mechanism of electrode processes, using a wall-jet electrode reactor as a hydrodynamic electrode system. The computational method is based on a second order-correct implicit finite difference approach and a coordinate transformation making a simple Cartesian space discretization compatible with efficient computing, thus allowing the computations to be performed on a personal computer. The computational approach is demonstrated through calculation of a single step chronoamperometric transient for a simple one electron transfer reaction and shown to be accurate by comparing the computed with experimentally determined current transients using as a model reaction the reduction of ferricyanide ions at a platinum electrode surface from a 0.01 m K₃Fe(CN)6-0.01 m K₄Fe(CN)₆ solution containing l m KCl as supporting electrolyteList of symbols a nozzle diameter (m) - C _i concentration of electroactive species i (mol m^–3) - C _i normalized concentration of electroactive species i - D _i diffusion coefficient of the electroactive species i (m² s^–1) - E electrode potential (V vs SCE) - E ₀ equilibrium potential (V vs SCE) - F Faraday's constant (C mol^–1) - dimensionless parameter, describing the distance normal to the impinged electrode - H distance between the working electrode and the tip of the nozzle (m) - I electrode current (A) - k _r constant linking the typical velocity of the wall-jet to the mean velocity in the nozzle - M flux of exterior momentum flux - v kinematic viscosity (m² s^–1) - r distance along the impinged electrode in cylindrical pole coordinates having their origin at the intersection of the jet axis and the electrode surface - R radius of the impinged electrode (m) - dimensionless time - t time (s) - v _I velocity component along the impinged electrode (m s^–1) - v _Z velocity component normal to the impinged electrode (m s^–1) - V _f volume flow rate (m^–3 s^–1) - dimensionless parameter, describing the distance normal to the impinged electrode - z distance normal to the impinged electrode in cylindrical pole coordinates having their origin at the intersection of the jet axis and the electrode surface (m)     

A confocal video-rate laser-beam scanning reflected-light microscope with no moving parts

A no-moving-parts, 30 frames/s, laser-beam scanning confocal reflected-light microscope has been developed. In principle, the technique can be extended to fluorescence and transmission light microscopy. Acousto-optic beam deflectors controlled by digital electronics move a laser beam in a 512-line interlaced 8·5 times 8·5-mm raster. The light passes through a beam splitter, enters an inverted microscope through the side camera port, and is imaged at the object by the microscope objective. Reflected light returns through the objective, exits the camera port, is reflected off the beam splitter, and is imaged on to the photocathode of an image dissector tube (IDT). Confocality is provided by raster scanning the IDT aperture coincident with the congruent image of the laser beam incident on the object. Real-time jitter-free reflected light images of a variety of biological objects have been produced. Computer-controlled alignment of the laser scan and IDT is performed in several seconds.     

基于WEB嵌入式自适应智能控制系统的研究与开发

提出一种基于WEB嵌入式自适应智能控制系统设计方案,提供了各组成模块软硬件的详细设计与具体实现;系统采用主流的S3C2410作为处理器,通过I2C总线实现各硬部件的连接;开发的嵌入式WEB服务器模块,使得用户能够对温度传感器读数进行互联网远程监测和多路数字、模拟量输出智能控制;并且神经网络模块能够自适应地学习和控制温度读数与制冷设备输出数之间的关系。实验结果显示改进后的Hopfield算法的收敛性和记忆性得到了提高,并使该系统具有较大的应用价值。     

Electrochemical reduction of silver thiosulphate complexes Part I: Thermodynamic aspects of solution composition

Deposition of silver from electrolyte solutions is of major importance in the industrial applications of photographic development and electroplating. Prior to the kinetic study of the reduction of silver thiosulphate complexes, the concentrations, activities and activity coefficients of all components formed in AgNO₃-Na₂S₂O₃-NaNO₃ solutions are calculated, starting from the measurement of the equilibrium potential. In view of the high ionic strength of the solutions (greater than 0.1 mol kg^–1), the ion interaction model is applied for the estimation of the activity coefficients, inevitably imposing the use of an iterative calculation routine. The activity coefficients are shown to comply with known thermodynamic laws, supporting the appropriateness of the model, together with the approximations.List of symbols a activity (m) - c concentration (m) - d density (kg dm^–3) - h hydration number - m molality (mol kg^–1) - x molfraction - y activity coefficient (molarity scale) - z charge of an ion - E ₀ equilibrium potential vs NHE (V) - I ionic strength (m or mol kg^–1) - M molecular weight (kg dm^–3) - T temperature (K) Greek symbols stability constant - activity coefficient (molality scale) - stoichiometric coefficient - osmotic coefficient Indices Indices f free (uncomplexed) - s solvent - t total - – (or a) anion - + (or c) cation - ± mean quantity     

机器人RV减速器摆线轮在线检测关键技术研究

为满足机器人RV减速器摆线轮在线检测要求,提出了一种采用多传感器测量系统对其关键尺寸进行快速检测的方法.设计出以中心孔为定位基准,采用接触式电感传感器对孔组位置度误差进行检测;根据被测孔径特点,采用非接触气动测量方式实现对摆线轮轴承安装孔内径和圆度的快速评定的方案.通过对研制出的样机与三坐标测量机的测量结果进行实验比对,实现孔组的位置度最大测量误差小于3μm,孔径及圆度最大测量误差均小于1μm,整机测量节拍均小于1 min的结果,实验表明本系统的测量方法和评定算法准确可靠,满足企业实际在线生产需要.