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排序方式: 共有576条查询结果,搜索用时 15 毫秒
1.
Mohammadreza Kosari Uzma Anjum Shibo Xi Alvin M. H. Lim Abdul Majeed Seayad Emmanuel A. J. Raj Sergey M. Kozlov Armando Borgna Hua Chun Zeng 《Advanced functional materials》2021,31(47):2102896
Beyond the catalytic activity of nanocatalysts, the support with architectural design and explicit boundary could also promote the overall performance through improving the diffusion process, highlighting additional support for the morphology-dependent activity. To delineate this, herein, a novel mazelike-reactor framework, namely multi-voids mesoporous silica sphere (MVmSiO2), is carved through a top-down approach by endowing core-shell porosity premade Stöber SiO2 spheres. The precisely-engineered MVmSiO2 with peripheral one-dimensional pores in the shell and interconnecting compartmented voids in the core region is simulated to prove combined hierarchical and structural superiority over its analogous counterparts. Supported with CuZn-based alloys, mazelike MVmSiO2 nanoreactor experimentally demonstrated its expected workability in model gas-phase CO2 hydrogenation reaction where enhanced CO2 activity, good methanol yield, and more importantly, a prolonged stable performance are realized. While tuning the nanoreactor composition besides morphology optimization could further increase the catalytic performance, it is accentuated that the morphological architecture of support further boosts the reaction performance apart from comprehensive compositional optimization. In addition to the found morphological restraints and size-confinement effects imposed by MVmSiO2, active sites of catalysts are also investigated by exploring the size difference of the confined CuZn alloy nanoparticles in CO2 hydrogenation employing both in-situ experimental characterizations and density functional theory calculations. 相似文献
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2019年底,湖北武汉暴发了2019新型冠状病毒感染疾病(COVID-19),并快速在全国蔓延,且在多个国家发现病例。其感染病例和死亡病例在短时间内快速超过重症急性呼吸综合征(SARS),给中国带来了不可估量的损失。中国科研人员在短时间内,快速锁定病原体为2019-nCoV(或hCoV-19或SARS-CoV-2),并且在不同层面开展了相关抗病毒药物的研发工作。本文介绍了抗2019-nCoV新药研发的现状。同时,鉴于突发病原体的药物研发过程相对迟缓,我们建议对于潜在流行可能性的病原体,其药物研发要具有前瞻性,国家层面要推进广谱药物的研发和临床试验,以应对可能出现的疫情风险。 相似文献
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底吹富氧搅拌是熔池熔炼的一种关键强化技术,对品位低、杂质多的矿产资源具有很好适应性,底吹喷枪是其关键工艺设备。本文将数值模拟与数理统计相结合,建立了多孔道底吹喷枪强化搅拌的三维数学模型,并通过水力学模型实验对数学模型进行了验证。针对模型计算结果,以气泡上升时间、液体的气含率方差和平均湍流强度等为评价标准,对直管及多孔道底吹喷枪搅拌过程的混合均匀度进行对比研究。结果表明:多孔道喷枪喷吹方式在提高熔体搅动能的同时能使中上部熔体的混合更为充分,并在生产实践中取得了良好的应用效果。 相似文献
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长周期扰动应力下盘区柱内巷道稳定及盘区柱整体稳定是大规模开采的关注重点。采用数值模拟方法,构建了大规模、多中段、长周期强烈开采扰动下的数值模型,建立了锚杆支护的拉伸破断、剪切破断数值力学模型,研究了不同水平、不同阶段回采过程中盘区柱内巷道锚杆支护的受力特性和盘区柱围岩的应力和塑性区发展特征。研究结果表明:不同开采阶段不同开采水平的锚杆轴力和巷道顶板变形响应明显,锚杆剪力由于变形监测部位的限制响应程度甚微,盘区柱内巷道稳定性好。盘区柱内巷道围岩偏应力场与塑性区动态演化仅在前两个中段开采时反应强烈,大规模开采结束时盘区柱仍然能够保持正常稳定。分析方法及分析结果能够对盘区柱内巷道稳定及盘区柱整体稳定做出提前预判,为盘区柱的正常使用提供安全保障。 相似文献
6.
针对深埋矿山开采移动带二维圈定方法工作量大、精度低且难以满足日益增长的经济效益需求的问题,提出了一种深埋复杂矿体移动范围三维确定方法。结合沙岭金矿千米深井工程实例,在移动范围确定过程中,借助先进的3D建模技术获得三维矿山模型。该模型可以实现各类地质体的可视化,直观地展示其形态与产状,清晰地反映各构成因素间的相互关系。在3D模型中截取的特征剖面与经典移动带圈定岩移参数获取方法相结合,能轻松获得各特征剖面上的岩移参数值。通过给定的岩移参数值进而确定各特征剖面上的地表移动边界点,将各移动边界点连接即可实现矿山移动范围的圈定。研究结果表明,基于三维地质建模技术的移动带圈定方法合理可行,确定的纱岭金矿地表移动带能够兼顾安全生产与经济效益,为矿山生产开发奠定了有益基础,为类似矿山提供了有益借鉴。 相似文献
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Dandan LUO Rui ZHANG Shibo WANG M. Zubair IQBAL Ruibo ZHAO Xiangdong KONG 《材料科学前沿(英文版)》2022,16(4):220617
Herein, the rational design micromilieus involved silk fibroin (SF)-based materials have been used to encapsulate the osteoblasts, forming an extracellular coated shell on the cells, which exhibited the high potential to shift the regulation of osteoblasts to osteocytes by encapsulation cues. SF coating treated cells showed a change in cell morphology from osteoblasts-like to osteocytes-like shape compared with untreated ones. Moreover, the expression of alkaline phosphatase (ALP), collagen I (Col I) and osteocalcin (OCN) further indicated a potential approach for inducing osteoblasts regulation, which typically accelerates calcium deposition and cell calcification, presenting a key role for the SF encapsulation in controlling osteoblasts behavior. This discovery showed that SF-based cell encapsulation could be used for osteoblasts behavior regulation, which offers a great potential to modulate mammalian cells’ phenotype involving alternating surrounding cues. 相似文献
9.
金川镍矿是世界著名的巨型多金属共生硫化铜镍矿床之一。连选及工业试验结果表明,采用我院研制的AS、CEED、J-622等新型高效捕收起泡剂、混合用药精矿再磨并集中精选及合适的中矿处理方式等技术措施是提高金川二矿区矿石选矿指标的有效途径。J-622工业试验成果已应用于工业生产;连选试验成功并将在现场进行工业试验,为闪速熔炼提供低镁的优质精矿,为金川公司产生明显的经济效益。 相似文献
10.
AbstractPoor dispersion of nanoparticles in polymer matrix would limit the development and application of particulate-filled polymer composites. Therefore, the Sb2O3 nanoparticles were functionalized by a combination of cetyltrimethyl ammonium bromide (CTAB) and silane coupling agent KH-560 via water bath modification method so as to improve the dispersion of Sb2O3 nanoparticles in poly(butylene terephthalate) (PBT) matrix and enhance the interfacial adhesion between nanoparticles and polymer matrix. Besides, the coating efficiency of compound modifiers on the surface of Sb2O3 nanoparticles was characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA). The Sb2O3 nanoparticles with different morphologies were systemically measured using transmission electron microscopy and dynamic light scattering measurement. The effects of particle surface treatment, particle size, particle morphology and particle loading on mechanical properties of composites were studied by the X-ray diffraction (XRD), tensile test machine and impact strength machine. The tensile strength of nanocomposites gradually increases with decreasing the particle size at the same amount of Sb2O3 nanoparticle fillers, which is attributed to improvement of interfacial contact area and stronger interfacial adhesion between Sb2O3 nanoparticles and PBT matrix. And the compound modified Sb2O3 nanoparticles are homogeneously dispersed in PBT matrix and play an important role in the properties enhancement. Moreover, taking consideration of the tensile and impact strengths, the optimal loading is 3?wt%. 相似文献