昌宁含铁低品位高泥锡石矿重-磁选工艺研究

云南昌宁锡矿石主要有用金属矿物为锡石，其次为褐铁矿等，主要脉石矿物为石英，锡主要以锡石及酸溶锡形式存在。原矿Sn品位为0.166%，?0.074 mm矿泥含量为24.61%（其中?0.019 mm矿泥含量为14.27%），属低品位、高泥、含铁难选锡石矿。本文在对该矿石进行原矿性质研究的基础上，开展了该矿的重-磁选工艺研究。结果表明:原矿破碎至?12 mm按0.212 mm粒度洗矿分级，洗矿+0.212 mm粗粒破碎至?3 mm后磨矿至?0.074 mm 55.85%与洗矿细粒?0.212 mm合并，采用螺旋溜槽预先抛尾-溜槽精矿摇床分选-摇床精矿强磁选除铁的选矿工艺流程，可以获得产率为0.21%、Sn品位为41.32%、Sn回收率为52.27%的锡精矿，及产率为0.75%、Sn品位为4.750%、Sn回收率为21.46%的锡富中矿，锡精矿与锡富中矿Sn累计回收率为73.73%，锡精矿质量达到了YS/T339-2011标准中一类VII品级精矿质量要求，较好地实现了该锡矿的分选。      

Improvement in the properties of low carbon MgO-C refractories through the addition of graphite-SiC micro-composite

Graphite–SiC micro-composites have been prepared in–house by carbothermal reduction process. Controlling the process parameters including the weight ratio of SiO₂ to graphite as well as carbothermal reduction temperature during the micro-composite preparation favors the homogeneous formation of SiC with preferred morphologies like ribbons and whiskers/fibers. The micro-composite modified low carbon MgO-C refractories have exhibited significantly improved bulk properties over the standard composition. To understand the beneficial role of SiC reinforcement on hot strength performance under air oxidizing conditions, we propose a scaling parameter known as strength factor (fs) based on the ratio of hot strength (HMOR) to cold strength (CCS). Correlating the strength factor data (fs) with oxidative damage provides new insights into the reinforcing effects of distinct SiC morphologies in this new class of micro-composite fortified refractory systems over the standard compositions.     

羧基含氟聚合物纳米纤维膜的制备及对铜(II)的吸附性能

以甲基丙烯酸十二氟庚酯(DFHMA)和甲基丙烯酸(MAA)为单体,通过溶液聚合法制备出共聚物DFHMA-co-MAA,将DFHMA-co-MAA与聚偏氟乙烯(PVDF)按一定质量共混,采用静电纺丝方法,制备出羧基含氟聚合物(PVDF-DM)纳米纤维膜,用以吸附溶液中Cu(II)。讨论了PVDF和DFHMA-co-MAA的质量配比对纤维微观形貌和对Cu(II)吸附性能的影响,得出当PVDF与DFHMA-co-MAA的质量比为1∶2时,纤维的微观直径较均一且吸附性能最佳,故实验采用该质量配比制备PVDF-DM。使用红外光谱对PVDF-DM进行表征,显示出PVDF-DM纤维膜中含有—OH和C＝O等活性吸附基团。以PVDF-DM纳米纤维膜为吸附剂,探讨了吸附剂用量、吸附pH值和吸附时间对Cu(II)吸附性能的影响,并研究了吸附过程的动力学模型。结果表明,室温下,当吸附剂用量为0.03g,pH=5时,吸附60min达到吸附平衡,吸附率和吸附量分别为94.37%和62.91mg/g,PVDF-DM纳米纤维膜对Cu(II)的吸附过程同时满足拟一级动力学和拟二级动力学模型,说明该吸附过程包含了化学吸附和物理吸附。PVDF-DM纳米纤维膜循环使用5次后,吸附能力仅降低16.23%,说明PVDF-DM纳米纤维膜具有很好的再生使用能力。     

聚乙烯亚胺氨基化磁性氧化石墨烯的制备及其对活性艳红X-3B的吸附

使用改性hummers法制备出氧化石墨烯(GO),通过水热法在GO上生长磁性CoFe₂O₄,再使用聚乙烯亚胺(PEI)进行氨基改性,制备出聚乙烯亚胺氨基化磁性氧化石墨烯(PEI-MGO)。使用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对PEI-MGO的结构和微观形貌进行表征。结果表明:纳米级尖晶石相CoFe₂O₄均匀分散于GO上,且氨基改性成功。探讨了PEI-MGO对水体中活性艳红X-3B的吸附性能。结果表明:在活性艳红X-3B初始质量浓度为150mg/L、体积为100mL、吸附剂质量为0.04g、pH值为1、吸附时间为60min时达到平衡,平衡吸附量为361.15mg/g。PEI-MGO对活性艳红X-3B的饱和吸附量为470.58mg/g。磁分离和磁回收研究表明,PEI-MGO能快速从水体中分离,回收率为98.6%。     

30Cr13不锈钢冶炼过程夹杂物控制技术

  针对30Cr13生产过程中存在的轧材非金属夹杂物合格率偏低仅85%左右的问题，通过对30Cr13不锈钢精炼过程钢中非金属夹杂物存在形态进行分析，并结合现有精炼工艺制度，在实验室研究的基础上制定了不锈钢精炼过程非金属夹杂物控制方案。工业应用后，精炼结束钢中大于5 μm的非金属夹杂物总数、形状以及尺寸等参数均得到了有效改善，钢水洁净度大大提高。     

退火温度对冷轧DP980钢力学性能的影响

利用连续退火模拟机对DP980试验钢进行了连续退火试验,并通过扫描电镜、电子背散射衍射、透射电镜等研究了不同退火温度下(775、800、825和850 ℃),试验钢显微组织的演变规律和力学性能的变化趋势。结果表明:试验钢的屈服强度随着退火温度的升高而不断增大(从705 MPa增大到850 MPa),抗拉强度和断后伸长率则随着退火温度的升高而不断减小(抗拉强度从1150 MPa减小到1030 MPa;伸长率从8.9%减小到5.3%),这与试验钢的显微组织构成和形态分布密切相关。此外,不同退火温度下,试验钢的加工硬化率曲线均呈现单调下降的趋势。     

Flame spectroscopy of waste tire oils and waste cooking oils blends using coaxial burner

Waste tires and cooking oil pose a serious danger to human health and environment. Self-reacting pyrolysis system for waste tires is designed and constructed for converting waste tires into oil that could be used as a sustainable fuel. This study aims to analyze the thermal microstructure of conventional fuels like light diesel oil (LDO) and heavy diesel oil (HDO) as well as blended with waste cooking oil (WCO) and tires pyrolysis oil (TPO) using a co-axial burner via flame spectroscopy analysis. The first Blend 1 (B1) consists of 20% WCO + 80% LDO, the second one (B2) consist of 20% WCO+80%HDO and the last one (B3) was 20%TPO and 80% LDO by mass. This percentage was chosen carefully and according to previous combustion characteristics results. The experimental results showed that B1 will shrink C2 radicals by nearly 61% and 64.5% at Ф = 0.63 and 0.96 respectively. B2 will decrease C2 radicals by nearly 19% and 82% at Ф = 0.63 and 0.96 respectively. Finally, B3 will reduce C2 radical's intensity by nearly 39% and 58% at Ф = 0.63 and 0.96 respectively. TPO produced CH emission radicals lower than that of LDO by nearly 5.9%. LDO droplets absorbed more radiation energy needed for excitation than that of WCO due to droplet size and fuel physic-chemical properties. B2 fuel is recommended to replace LDO at Ф = 0.63 and 0.96.     

攀西地区白马辉长岩型超低品位钒钛磁铁矿选铁试验研究

论文以攀西地区白马辉长岩型超低品位钒钛磁铁矿为研究对象,查明了该矿石中化学组分、矿物组成、铁和TiO₂的相态。在此基础上进行了多粒级多磁场梯度干式磁选抛尾试验,通过铁和TiO₂的相态分析阐述了干式磁选抛尾的合理性；进行了干式磁选精矿阶段磨矿阶段选别试验,二段磁选在-200目占80%细度下获得了TFe 57.78%、TiO₂ 7.72%、V₂O₅ 0.69%的铁精矿,铁精矿产率为12.93%、铁回收率51.56%,相对磁性铁回收率为98.70%,V₂O₅回收率78.26%。结果表明该矿石虽然铁品位低,仍具综合回收利用价值。      

氮含量对HPD-1双相不锈钢组织及力学性能的影响

通过显微组织观察与力学性能测试研究了氮含量(0.08%~0.22％,质量分数)对HPD-1双相不锈钢硬度、拉伸性能、低温冲击性能及疲劳性能的影响。结果表明,氮含量变化可显著影响试验钢γ/α相比例,当氮含量由0.08％升高到0.22％,γ相含量由38.1％提高至56.5％。α相的硬度由273 HV10提高到343 HV10,γ相的硬度由238 HV10提高到299 HV10,试验钢强度明显提升。氮元素对两相比例和奥氏体相韧性的双重影响导致试验钢低温冲击性能呈先上升后下降的趋势;更高的氮含量抑制疲劳裂纹萌生与拓展,是影响HPD-1双相不锈钢室温疲劳性能的主要因素。撕裂棱是疲劳断口的显著特征。