全文获取类型
收费全文 | 9765篇 |
免费 | 942篇 |
国内免费 | 331篇 |
专业分类
电工技术 | 140篇 |
综合类 | 634篇 |
化学工业 | 3142篇 |
金属工艺 | 406篇 |
机械仪表 | 171篇 |
建筑科学 | 811篇 |
矿业工程 | 256篇 |
能源动力 | 850篇 |
轻工业 | 1420篇 |
水利工程 | 398篇 |
石油天然气 | 641篇 |
武器工业 | 39篇 |
无线电 | 257篇 |
一般工业技术 | 956篇 |
冶金工业 | 644篇 |
原子能技术 | 111篇 |
自动化技术 | 162篇 |
出版年
2024年 | 16篇 |
2023年 | 161篇 |
2022年 | 321篇 |
2021年 | 405篇 |
2020年 | 427篇 |
2019年 | 333篇 |
2018年 | 287篇 |
2017年 | 320篇 |
2016年 | 323篇 |
2015年 | 344篇 |
2014年 | 520篇 |
2013年 | 597篇 |
2012年 | 677篇 |
2011年 | 705篇 |
2010年 | 508篇 |
2009年 | 574篇 |
2008年 | 492篇 |
2007年 | 572篇 |
2006年 | 504篇 |
2005年 | 402篇 |
2004年 | 340篇 |
2003年 | 323篇 |
2002年 | 256篇 |
2001年 | 199篇 |
2000年 | 171篇 |
1999年 | 153篇 |
1998年 | 133篇 |
1997年 | 105篇 |
1996年 | 112篇 |
1995年 | 108篇 |
1994年 | 97篇 |
1993年 | 66篇 |
1992年 | 61篇 |
1991年 | 62篇 |
1990年 | 54篇 |
1989年 | 53篇 |
1988年 | 41篇 |
1987年 | 33篇 |
1986年 | 36篇 |
1985年 | 39篇 |
1984年 | 36篇 |
1983年 | 20篇 |
1982年 | 19篇 |
1981年 | 11篇 |
1980年 | 8篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(65):28152-28164
The combustion characteristics of ammonia/methanol mixtures were investigated numerically in this study. Methanol has a dramatic promotive effect on the laminar burning velocity (LBV) of ammonia. Three mechanisms from literature and another four self-developed mechanisms constructed in this study were evaluated using the measured laminar burning velocities of ammonia/methanol mixtures from Wang et al. (Combust.Flame. 2021). Generally, none of the selected mechanisms can precisely predict the measured laminar burning velocities at all conditions. Aiming to develop a simplified and reliable mechanism for ammonia/methanol mixtures, the constructed mechanism utilized NUI Galway mechanism (Combust.Flame. 2016) as methanol sub-mechanism and the Otomo mechanism (Int. J. Hydrogen. Energy. 2018) as ammonia sub-mechanism was optimized and reduced. The reduced mechanism entitled ‘DNO-NH3’, can accurately reproduce the measured laminar burning velocities of ammonia/methanol mixtures under all conditions. A reaction path analysis of the ammonia/methanol mixtures based on the DNO-NH3 mechanism shows that methanol is not directly involved in ammonia oxidation, instead, the produced methyl radicals from methanol oxidization contribute to the dehydrogenation of ammonia. Besides, NOx emission analysis demonstrates that 60% methanol addition results in the highest NOx emissions. The most important reactions dominating the NOx consumption and production are identified in this study. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(33):15084-15093
The effect of ammonia (NH3) contained in hydrogen (H2) gas on hydrogen environment embrittlement (HEE) of SCM440 low-alloy steel was studied in association with the NH3 concentration, loading rate, and gas pressure. NH3 worked as both mitigator of the HEE and inducer of hydrogen embrittlement (HE) depending on the testing conditions. The mitigation of the HEE was achieved by the deactivation of the iron (Fe) surface for H2 dissociation caused by the preferential adsorption of NH3 on the Fe surface, which is enhanced by the increase in the NH3 concentration and decrease in the H2 gas pressure. NH3 induced HE was caused due to creating hydrogen by the NH3 decomposition. Since the NH3 decomposition rate is low, the induction effect was observed when the loading rate was low. The effect of NH3 was determined by the competition of the mitigation and induction effects. 相似文献
3.
《Ceramics International》2022,48(11):15043-15055
This work reports magnetic permeability and ammonia gas sensing characteristics of La3+ substituted Co–Zn nano ferrites possessing chemical formula Co0.7Zn0.3LaxFe2-2xO4 (x = 0–0.1) synthesized by a sol-gel route. Refinement of X-ray diffraction (XRD) patterns of the ferrite powders by the Rietveld technique has revealed the creation of single-phase spinel structure. The tenancy of constituent cations at tetrahedral/octahedral sites was obtained from the refinement of XRD. The crystallite sizes calculated from the W–H method vary from 20 to 24 nm. The scanning electron microscope (SEM) profiles of the ferrite samples were analyzed for the morphological details. The energy dispersive X-ray analysis (EDAX) patterns of the samples were obtained to test the elemental purity of the ferrites within their stoichiometry. The transmission electron microscope (TEM) image of the ferrite (x = 0.1) exhibits the spherical and oval shaped particles with a mean size of 20 nm. Fourier transform infra-red (FTIR) spectra were analyzed to confirm the superseding of La3+ cations at octahedral sites. The Brunauer-Emmett-Teller (BET) analysis of nitrogen adsorption-desorption isotherms of the ferrites was performed to investigate the porous structure and to determine the surface area of the nanocrystalline ferrites. The oxidation states of the constituent ions were confirmed by means of X-ray photoelectron spectroscopy (XPS). The complex permeability as a function of frequency was studied to explore the effects of structural parameters on the magnetic behaviour of the ferrites. Analysis of gas sensing properties of the ferrites have proved that the Co–Zn–La ferrite with controlled La composition can be utilized as an effective ammonia gas sensing material in commercial gas sensors. 相似文献
4.
Liu Chunshuang Li Wei Duan Weichao Huiyun Zhong Yu Haitong Li Yanze Liu Fang Zhao Chaocheng 《中国炼油与石油化工》2021,23(1):105-110
In this study,nitrogen removal performance of the denitrifying ammonium oxidation(DAO)process was investigated when treating sulfamethoxazole(SMX)-laden secondary wastewater effluent.The influent SMX concentration showed negligible effect on efficiencies for removal of nitrate and COD.However,the ammonium ions removal rate was moderately reduced,when the influent SMX concentration in wastewater reached 6 mg/L.Total nitrogen removal efficiency remained as high as 76.77%towards the day 158 at the end of experiment.Candidatus_Brocadia and Candidatus_Kuenenia were the functional anammox strains.The unclassified_f__Rhodobacteraceae sp.was predominant heterotrophic denitrifying strain in the studied reactor.The concentrations of soluble extracellular polymeric substances in sludge obviously increased from 16.76 mg/g VSS to 32.31 mg/g VSS,which might protect the nitrogen removal strains from high-concentration SMX.This result provides a theoretical and technical foundation for the application of denitrifying ammonium oxidation process in treating sulfamethoxazole-laden secondary wastewater effluent. 相似文献
5.
《Ceramics International》2022,48(8):10817-10820
Single-crystal grains of TaN were synthesized by heating Ta2O5, FeTa2O6, or FeTaO4 in a BN crucible together with Na metal in an Ar atmosphere at 1100 °C. The BN crucible acted a solid source of nitrogen. Aggregates of columnar ε-TaN single crystals 10–150 μm in size were formed on the inner wall of the BN crucible when either Ta2O5 or FeTa2O6 was used. On the other hand, platelet-like single crystals of θ-TaN 1–50 μm in size were obtained from FeTaO4. The results of wavelength-dispersive X-ray spectrometry indicated that the compositions of the ε-TaN and θ-TaN crystals were close to the stoichiometric ideal. 相似文献
6.
7.
通过显微组织观察与力学性能测试研究了氮含量(0.08%~0.22%,质量分数)对HPD-1双相不锈钢硬度、拉伸性能、低温冲击性能及疲劳性能的影响。结果表明,氮含量变化可显著影响试验钢γ/α相比例,当氮含量由0.08%升高到0.22%,γ相含量由38.1%提高至56.5%。α相的硬度由273 HV10提高到343 HV10,γ相的硬度由238 HV10提高到299 HV10,试验钢强度明显提升。氮元素对两相比例和奥氏体相韧性的双重影响导致试验钢低温冲击性能呈先上升后下降的趋势;更高的氮含量抑制疲劳裂纹萌生与拓展,是影响HPD-1双相不锈钢室温疲劳性能的主要因素。撕裂棱是疲劳断口的显著特征。 相似文献
8.
针对高含盐氨氮废水,选择具有不同功能基团的树脂为载体,进行负载Cu2+改性制得载铜树脂并对其处理高含盐氨氮废水的性能进行研究。在筛选出最佳载铜树脂的基础上,研究pH及Na+浓度、树脂投加量、反应时间对载铜树脂处理高含盐氨氮废水效果的影响,通过对吸附氨氮前后的载铜树脂进行SEM和EDS表征分析并构建吸附动力学模型以进一步探究配位吸附的过程。结果表明,Cu2+可与螯合树脂D751稳定结合且在宽pH值下均表现出耐盐性和良好的氨氮吸附效果;在室温(25℃)、pH=11及Na+浓度4 g/L、树脂投加量8 g/L、反应时间60 min的条件下,D751载铜树脂对氨氮的去除率为34.8%。D751载铜树脂吸附氨氮后其表面出现明显的晶状结构物质,该物质可能为铜氨络合物。D751载铜树脂对高含盐氨氮的吸附符合准二级动力学模型。 相似文献
9.
Variations in yield and gluten proteins in durum wheat varieties under late‐season foliar versus soil application of nitrogen fertilizer in a northern Mediterranean environment 下载免费PDF全文
10.