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1.
Flotation has been used in industry for more than a half century as the primary technique for upgrading phosphate. While the flotation of phosphate was inefficient when oleic acid was used alone as a collector, therefore a mixed collector of oleic acid (HOl), linoleic acid (LA) and linolenic acid (LNA) was employed to improve the recovery of phosphate flotation. The batch flotation results showed that the optimal composition of the mixed collector was 54 wt.% HOl, 36 wt.% LA and 10 wt.% LNA. Additionally, the effect of pH on the mixed collector application was studied while considering the surface tension, contact angle and micro-flotation. The results showed that the mixed collector should be used at a pH of 9.5. Above a pH of 9.5, the adsorption of fatty acids dimers on the apatite surface hindered phosphate flotation. The influence of the mixed collector assembly on apatite flotation was also investigated. It was demonstrated that due to its low critical micelle concentration, a sufficiently hydrophobic apatite surface could be generated at a collector concentration of 60 mg/L. In addition, zeta potential experiments suggested that collector adsorption was governed by chemisorption. FTIR and XPS spectra studies further indicated that the chemical reaction involved the carboxyl groups of fatty acids and Ca species at the apatite surface for each fatty acid in the mixed collector.  相似文献   
2.
It is the aim of this paper to examine the effects of conditioning time on the flotation of hematite using three technical grade fatty acid reagents as providing additional evidence on their mechanism of interaction with the hematite surface. Various mechanisms have been postulated as occurring as conditioning time is increased. Both physical (e.g. conditioning time and power input) and chemical (nature, dispersion and solubility of the adsorbing species) contribute to the mechanisms of attachment of collector. In this paper, the mechanism of attachment of oleate to hematite can be readily explained by chemisorption, but the mechanism of attachment of lauric acid appears to be physical adsorption at neutral pH. The flotation of hematite with a mixture of tallow-type fatty acids (palmitic, stearic and oleic acids) is very sensitive to conditioning time, and suggests that, even though flotation is very effective at short conditioning times, it is very susceptible to the presence of fines and their associated high surface areas. It is therefore obvious that both the physical and chemical conditions contribute to the mechanisms of adsorption of fatty acids on iron-containing oxide minerals and must be understood in order to optimise the flotation of these minerals in an industrial situation.  相似文献   
3.
大块非晶合金的性能、制备及应用   总被引:4,自引:0,他引:4  
综述了大块非晶合金的性能、制备方法及应用,对比了吸铸法制备的棒状Zr41.2Ti13.8Cu12.5Ni10Be22.5,Zr57Cu20Al10Ni8Ti5,Zr52.5Ti5Cu17.9Ni14.6Al10(原子分数)大块非晶样品的过冷温度区间宽度(△Tx),给出了3种大块非晶合金系列的热稳定性参数Tg、Tx及△Tx,提出了大块非晶合金领域存在的问题及发展方向.  相似文献   
4.
白钨矿浮选731捕收剂低温乳化试验研究   总被引:2,自引:1,他引:1  
介绍了731捕收剂在低温条件下试验的情况。试验研究结果表明,采用A和B药剂以5:6的比例混合组成的复合乳化剂对731进行乳化,低温时乳化体系稳定性好,浮选过程中降低乳化731的用量,同时提高了选择性,降低了浮选成本,实现了低温环境下白钨矿正常浮选作业,达到选矿技术攻关指标。  相似文献   
5.
Industrial pelletizing of sawdust was carried out as a designed experiment in the factors: sawdust moisture content, fractions of fresh pine, stored pine and spruce. The process parameters and response variables were energy consumption, pellet flow rate, pellet bulk density, durability and moisture content. The final data consisted of twelve industrial scale runs. Because of the many response variables, data evaluation was by principal component analysis of a 12 × 9 data matrix. The two principal component model showed a clustering of samples, with a good reproducibility of the center points. It also showed a positive correlation of energy consumption, bulk density and durability all negatively correlated to flow rate and moisture content. The stored pine was more related to high durability and bulk density. The role of the spruce fraction was unclear. The design matrix, augmented with the process parameters was a 12 × 6 matrix. Partial least squares regression showed excellent results for pellet moisture content and bulk density. The model for durability was promising. A 12 × 21 data matrix of fatty- and resin acid concentrations measured by GC–MS showed the differences between fresh and stored pine very clearly. The influence of the spruce fraction was less clear. However, the influence of the fatty- and resin acids on the pelletizing process could not be confirmed, indicating that other differences between fresh and stored pine sawdust have to be investigated. This work shows that it is possible to design the pelletizing process for moderate energy consumption and high pellet quality.  相似文献   
6.
7.
某铅锌矿选矿尾矿综合利用试验研究   总被引:2,自引:0,他引:2  
针对选矿尾矿的特性,采用高选择性的3ACH捕收剂、F—1抑制剂,回收了绢云母含量分别达96%和64%以上的一、二级绢云母产品。经应用试验表明:绢云母一级品在橡胶中的补强性能基本达到了沉淀法白炭黑水平,二级品也全面超过硅铝炭黑的补强性能。  相似文献   
8.
A mini spray dryer has been used to investigate morphological changes that occur to milk particles during the spray drying process. We have found that the mini spray dryer is ideal for such investigations, because phenomena such as skin and vacuole formation in particles can be analyzed without the added complication of particle agglomeration, which only occurs in much larger spray dryers where particle number concentrations are higher. We have confirmed observations made by various researchers that the bulk density of spray-dried milk powder is greatly affected by the drying temperature, due to the strong influence of the latter on the porosity of the particles. In addition, we have attempted to explain observations made by various workers that fat accumulates preferentially at the surface of a particle during drying by postulating that fluid fat is transported towards the surface, via a network of cracks and pores, by the development of a vacuole overpressure which is also responsible for the inflation of the particle. Finally, we have shown that milk powders can be spray dried a second time, by reconstitution with water, with no change to the thermodynamic characteristics of the resultant powder. Thus, milk concentrates for spray drying research can be prepared from already-spray-dried milk powders rather than using the more arduous evaporation method to concentrate unprocessed milk.  相似文献   
9.
Al-Cu-Fe alloys were prepared from elemental powders in a high-energy planetary ball mill. A sequence of solid state reactions resulting in quasicrystal (QC) phase formation takes place during heating of the as-milled powder. These reactions were studied by both differential scanning calorimetry and x-ray diffraction methods. Mechanically alloyed powders were consolidated by cold and hot pressing, as well as by explosive compaction. After annealing at sufficiently high temperatures, the consolidated samples are single-phase QC, except the ones consolidated by explosion. The high reactivity of the as-milled alloys causes the appearance of high porosity of the consolidated samples after the annealing.  相似文献   
10.
硫酸铵-氯化亚锡-孔雀绿体系浮选分离铂   总被引:5,自引:0,他引:5  
研究了在盐酸介质中硫酸铵存在下氯化亚锡—孔雀绿—水体系浮选分离铂的方法。在最佳实验条件下,铂的浮选率可达100.0%,并与常见贱金属完全分离。  相似文献   
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