全文获取类型
收费全文 | 1136篇 |
免费 | 74篇 |
国内免费 | 135篇 |
专业分类
电工技术 | 20篇 |
综合类 | 55篇 |
化学工业 | 265篇 |
金属工艺 | 294篇 |
机械仪表 | 8篇 |
建筑科学 | 1篇 |
矿业工程 | 21篇 |
能源动力 | 59篇 |
轻工业 | 9篇 |
水利工程 | 2篇 |
石油天然气 | 22篇 |
武器工业 | 10篇 |
无线电 | 67篇 |
一般工业技术 | 187篇 |
冶金工业 | 246篇 |
原子能技术 | 57篇 |
自动化技术 | 22篇 |
出版年
2023年 | 41篇 |
2022年 | 29篇 |
2021年 | 47篇 |
2020年 | 68篇 |
2019年 | 45篇 |
2018年 | 40篇 |
2017年 | 34篇 |
2016年 | 41篇 |
2015年 | 35篇 |
2014年 | 60篇 |
2013年 | 54篇 |
2012年 | 86篇 |
2011年 | 99篇 |
2010年 | 84篇 |
2009年 | 78篇 |
2008年 | 66篇 |
2007年 | 71篇 |
2006年 | 58篇 |
2005年 | 42篇 |
2004年 | 24篇 |
2003年 | 26篇 |
2002年 | 32篇 |
2001年 | 32篇 |
2000年 | 33篇 |
1999年 | 13篇 |
1998年 | 13篇 |
1997年 | 20篇 |
1996年 | 11篇 |
1995年 | 13篇 |
1994年 | 8篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有1345条查询结果,搜索用时 15 毫秒
1.
Yuelong Ma Le Zhang Tianyuan Zhou Bingheng Sun Chen Hou Shunshun Yang Jin Huang Rui Wang Farida A. Selim Zhongying Wang Ming Li Hao Chen Yun Wang 《Journal of the European Ceramic Society》2021,41(4):2834-2846
Ce:Y3Al5O12 transparent ceramics (TCs) with appropriate emission light proportion and high thermal stability are significant to construct white light emitting diode devices with excellent chromaticity parameters. In this work, strategies of controlling crystal-field splitting around Ce3+ ion and doping orange-red emitting ion, were adopted to fabricate Ce:(Y,Tb)3(Al,Mn)5O12 TCs via vacuum sintering technique. Notably, 85.4 % of the room-temperature luminescence intensity of the TC was retained at 150 °C, and the color rendering index was as high as 79.8. Furthermore, a 12 nm red shift and a 16.2 % increase of full width at half maximum were achieved owing to the synergistic effects of Tb3+ and Mn2+ ions. By combining TCs with a 460 nm blue chip, a warm white light with a low correlated color temperature of 4155 K was acquired. Meanwhile, the action mechanism of Tb3+ ion and the energy transfer between Ce3+ and Mn2+ ions were verified in prepared TCs. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(25):12726-12738
The use of a Pt-based catalyst was evaluated for autocatalytic hydrogen recombination. The Pt was supported on a mixture of Ce-, Zr- and Y-oxides (CZY) to yield nanosized Pt particles. The Pt/CZY/AAO catalyst was then prepared by the spray-deposition of the Pt/CZY intermediate onto an anodized aluminium oxide (AAO) layer on a metallic aluminum core. The Pt/CZY/AAO catalyst (3 × 1 cm) was evaluated for hydrogen combustion (1–8 vol% hydrogen in the air) in a recombiner section testing station. The thermal distribution throughout the catalyst surface was investigated using an infrared camera. The maximum temperature gradient (ΔT) for the examined hydrogen concentrations did not exceed 36 °C. The Pt/CZY/AAO catalyst was also evaluated for prolonged hydrogen combustion duration to assess its durability. An average combustion temperature of 239.0 ± 10.0 °C was maintained for 53 days of catalytic hydrogen combustion, suggesting that there was limited, or no, catalyst deactivation. Finally, a Pt/CZY/AAO catalytic plate (14.0 × 4.5 cm) was prepared to investigate the thermal distribution. An average surface temperature of 212.5 °C and a maximum ΔT of 5.4 °C was obtained throughout the catalyst surface at a 3 vol% hydrogen concentration. 相似文献
3.
Fernando L.G. Silva Amanda G. Veiga Nakédia M.F. Carvalho 《International Journal of Hydrogen Energy》2021,46(21):11677-11687
Manganese oxides of different crystalline structures: α-MnO2, δ-MnO2, α,γ-MnO2 and Mn2O3; were treated with the organic compounds picolinic acid, ethylenediamine and pyridine; and were applied as catalysts in the chemical water oxidation reaction using Ce(IV) ammonium nitrate as sacrificial oxidant. The treatment led to modifications in the oxides properties, such as reduction of the particle size, increase of surface area and partial reduction of Mn4+ to Mn3+ for the Mn(IV) oxides, or of Mn3+ to Mn2+ for Mn2O3, because of favored interactions of the organic molecules with the lattice planes with higher d spacing. Oxygen evolution reaction (OER) tests showed the superior catalytic activity of the treated Mn(IV) oxides, for instance α,γ-MnO2-en presented TOF five times higher than pure α,γ-MnO2. The increase in surface area as well as the higher Mn3+ content caused by the treatment of the Mn(IV) oxides were correlated with the improvement in the OER catalytic activity. 相似文献
4.
Meiling He Yinzi Cheng Linli Shen Huiling Zhang Chenyang Shen Weidong Xiang Xiaojuan Liang 《Journal of the American Ceramic Society》2019,102(3):1090-1100
CsPbX3 (X = Cl, Br, I) perovskite quantum dots (QDs) represent bright and tunable photoluminescence, it is regrettable that the air instability and poor water resistant properties prevent their application in optoelectronic devices. At the same time, the toxicity of lead is also a major factor restricting its development. As a consequence, we demonstrate the partial replacement of Pb with Mn through conventional melt-quenching and heat-treatment method preparation of Mn-doped CsPb(Cl/Br)3 QD glass. Mn-doped CsPb(Cl/Br)3 QD glass exhibits high luminescent intensity like QDs. It is important that Mn-doped CsPb(Cl/Br)3 QD glass with Dual-Color maintained the same lattice structure like Mn-doped CsPb(Cl/Br)3 QDs, and highly homogeneous spectral characteristics of Mn luminescence. The intensity and position of this Mn-related emission are also tunable by altering the experimental parameters, such as the Pb-to-Mn feed ratio, annealing temperature. More importantly, the as-prepared orange Mn-doped CsPb(Cl/Br)3 QD glass was employed to fabricate white LEDs combined with a commercial Ce3+:Y3Al5O12 phosphor-in-glass (Ce-PiG) on top of a InGaN blue chip. And the constructed WLEDs generate a warm white with an optimal luminous efficacy (LE) of 67.00 lm/W, a high CRI of 81.4, and a low CCT of 4902 K. 相似文献
5.
Xiaoyun Li Jian Chen Zhuguang Liu Zhonghua Deng Qiufeng Huang Jiquan Huang Wang Guo 《Journal of the European Ceramic Society》2021,41(8):4590-4597
(Y1-x%Cex%)3Al5O12 (x = 0.2,0.4,0.6,0.8,1.0) transparent ceramics were fabricated by vacuum sintering technology, followed by air annealing at different temperatures. Transmittance of ceramics, valence of cerium, and luminescent properties with varying annealing temperatures are studied in detail. The negative effect of Ce3+ oxidation induced by annealing gets increasingly evident when Ce concentration increases. Collaborating Ce:YAG ceramics with InGaN blue chips, light-emitting diodes (LEDs) with superior performance were constructed. The relationships between Ce concentration, annealing temperature, and luminous flux of LEDs are elucidated, showing that the optimized annealing temperature of Ce:YAG ceramics decreases from 1200 °C to 900 °C as Ce concentration increases from 0.2 at% to 1.0 at%. The luminous fluxes of optimized LEDs increase by ~10 % compared with that of unannealed LEDs. 相似文献
6.
7.
《International Journal of Hydrogen Energy》2020,45(52):28163-28174
Element replacement and mechanical milling are considered as the most effective ways to improve Mg-based alloys in their hydrogen storage performance. The as-milled La7RE3Mg80Ni10 (RE = Sm, Ce) alloys were prepared in this experiment by introducing both element replacement (replacing La by Ce or Sm partially) and mechanical milling technologies. The influence made by different replacing elements on the structure and hydrogen storage property of La7RE3Mg80Ni10 (RE = Sm, Ce) alloys was investigated in detail. X-ray diffraction, transmission electron microscope, automatic Sievert apparatus, thermogravimetry and differential scanning calorimetry were used to investigate the experimental alloys. The experiment reveals that a nanocrystalline and amorphous structure appears after mechanical milling. Moreover, comparing with the RE = Sm alloy, the RE = Ce alloy has a superior hydrogen desorption property, including larger hydrogen absorption capacity, faster hydriding/dehydriding rate, lower onset hydrogen desorption temperature, and lower dehydrogenation activation energy. 相似文献
8.
《能源学会志》2020,93(2):496-507
Hydrocarbons could be used as the reductant for elimination of NOx emissions. Liquid petroleum gas, with higher carbon hydrocarbons and cheaper costs, may be of practical value as reducing agents. Due to the consumption of hydrocarbons by oxygen, the NOx reduction efficiency is significantly inhibited by oxygen in the flue gas. In this research, a novel rotary reactor, realizing the alternating cycle of adsorption zone and reduction zone, was proposed to overcome this negative effect. Co–Ce–Ti mixed oxide catalysts synthesized by a sol–gel method were tested in a simulated rotary reactor for NOx removal by liquid petroleum gas and characterized by SEM, BET, XRD and XPS. The results showed that catalysts exhibited better NO conversion efficiency at higher temperature but were highly susceptible to oxygen. Catalysts achieved nearly full removal of NOx from flue gas at 300 °C in a simulated rotary reactor, and 300 °C is considered to be the most optimum temperature with lower energy consumption and excellent flue gas purification performance. 相似文献
9.
为了研究Ce(SO4)2浓度与合金镀层表面性能的关系,采用喷射电沉积法制备了一系列Ni-W-Ce合金镀层工件。用扫描电镜(SEM)观察了镀层的表面结构,并用能谱仪(EDS)检测镀层中的元素组成。XRD分析表明,镀层存在晶格畸变。LEXT4100激光共焦显微镜观察磨损痕迹,发现磨损机理发生了变化。结果表明,添加Ce(SO4)2改善了涂层的表面微观形貌,当浓度为0.5g/L时,涂层的表面质量最佳。同时,显微硬度、耐磨性和耐腐蚀性随浓度的增加呈现先好后坏的规律。当Ce(SO4)2浓度为0.5g/L时,显微硬度达到峰值519.69HV0.1。此时,镀层耐磨性最好,其耐磨性表征参数均取得最小值。且镀层的耐蚀性也最好,腐蚀电位为-0.5537V,电弧电抗半径最小。 相似文献
10.
《International Journal of Hydrogen Energy》2020,45(29):14728-14743
The main objective of the present work is to investigate the influence of nickel to cerium ratio on hydrogen exchanged Zeolite Socony Mobil-5 (HZSM-5) towards the catalytic upgrading of pine derived oxygenated pyrolysis vapours into aromatic hydrocarbon and phenol in pyrolysis oil via ex-situ fixed bed reactor. The presence of CeO2 could change electron density of Ni, promote the reduction of Ni species, accelerate the transfer of carbon species, and suppress the production of carbon deposits (17.53%–25.11%) compared with the parent HZSM-5 catalyst (28.95%); it also improved the hydrodeoxygenation ability of all xNiyCe/HZSM-5(nickel and cerium bimetal modified HZSM-5) catalysts, resulting increases in noncondensable gas content (from 31.46% to 52.99%–65.53%). Ni to Ce ratio of 1:1 and 1:2 produced highest aromatic hydrocarbon (32.14%) and phenols (55.51%) relative peak areas. The acid center of HZSM-5 and the metal acid center of the Ni:Ce = 1:1 catalyst obviously fine-tuned the formation of coke; and promoted hydrocarbon production. Moreover, high Ni content promoted alkylation of benzene at C6–C9 and increased C10+ PAHs relative peak area; high Ce content promoted the formation of olefin and Increasing the cleavage of C–O bonds and promoted hydrogenation or dehydrogenation, reduced polycyclic aromatic hydrocarbons and coke yield, and increased phenols and alkylphenols selectivity. 相似文献