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1.
溜井是采用平硐-溜井方式开拓矿山的运输咽喉,溜井正常与否对矿山生产影响极大。本文通过黑沟铁矿高深溜井井筒堵塞处理实例,对其堵塞爆破处理方法及经验做了系统分析。重点介绍的爆破冲击波破拱疏通高深溜井井筒高位堵塞的爆破方法,富有新意,可供国内外同类型矿山参考借鉴。  相似文献   
2.
以减压渣油为原料,催化裂化加氢重循环油和工业馏分油窄馏分为供氢溶剂,采用溶剂脱沥青-液相加氢组合工艺,可将减压渣油高效转化为轻质油。结果表明:焦化蜡油(410~430 ℃)、FCC油浆(450~470 ℃)、糠醛抽出油(430~450 ℃)、重循环油(410~430 ℃)窄馏分的供氢能力依次为2.28,2.61,4.86,2.73 mg/g,远低于四氢萘(7.90 mg/g),而加氢重循环油(0.948 7 g/cm3)供氢能力(7.42 mg/g)与后者相近;采用组合工艺,以加氢重循环油为供氢溶剂,减压渣油的综合转化率为90.84%,轻质油收率(质量分数)可达89.35%,焦炭得到有效抑制。  相似文献   
3.
利用氯化胆碱/草酸和氯化胆碱/草酸/乙二醇2种低共熔溶剂(DES)体系预处理竹粉以分馏提取木质素,并通过多种表征手段探究木质素的结构变化。结果表明,在110 ℃反应180 min的条件下,氯化胆碱/草酸二元DES体系提取的木质素(二元DES木质素)中β-O-4芳基醚键的相对含量仅为0.26/Ar,氯化胆碱/乙二醇/草酸三元DES体系提取的木质素(三元DES木质素)此值则为0.43/Ar。同时,二元DES木质素中的缩合结构(β-ββ-5=3.11/Ar)及缩合的芳环C—C连接(Aromatic C—C=2.18/Ar)多于三元DES木质素(β-ββ-5=2.02/Ar,Aromatic C—C=1.99/Ar)。利用超声辅助三元DES体系预处理过程,发现反应20 min后木质素脱除率即可达76.0%。采用水相电位滴定法测定不同反应条件下的三元DES木质素的酚羟基和羧基含量;并提出乙二醇在三元DES体系预处理竹粉过程中抑制木质素缩合的机理,证实乙二醇与对香豆酸和阿魏酸反应生成了酯化的木质素结构。  相似文献   
4.
5.
In this work we have investigated the effect of the solvent during the processing of SrFe12O19 platelet-based permanent magnets by cold sintering process (CSP) plus a post-thermal treatment. Several organic solvents: glacial acetic acid, oleic acid and oleylamine have been analyzed, optimizing the CSP temperatures at 190?270 °C, under pressures of 375?670 MPa and 6?50 wt% of solvent. Modifications in the morphological and structural properties are identified depending on the solvent, which impacts on the magnetic response. Independently of the solvent, the mechanical integrity of ferrite magnets obtained by CSP is improved by a post-annealing at 1100 °C for 2 h, resulting in relative densities around 92 % with an average grain size of 1 μm and a fraction of SrFe12O19 phase >91 %. HC ≥ 2.1 kOe and MS of 73 emu/g are obtained in the final sintered ceramic magnets, exhibiting the highest HC value of 2.8 kOe for the magnet sintered using glacial acetic acid.  相似文献   
6.
采用铸造法制备原位自生亚共晶Al-10Mg2Si复合材料,研究Cu和T6热处理对该复合材料组织与力学性能的影响。结果表明:适量Cu的添加能显著减小共晶Mg2Si相晶粒尺寸,使其晶体结构由粗大的长条状和汉字状转变为细小的条状和纤维状;同时使针状的β-Al5Fe Si相转变为细小的不规则富Cu颗粒。经T6热处理后,质量分数为1.5%的Cu复合材料中的共晶Mg2Si相完全球化。质量分数为1.5%的Cu添加同时提高了材料铸态下的抗拉强度(Rm)、屈服强度(Rp0.2)和伸长率(A),达317、169 MPa和2.3%,比未添加Cu提高了42.2%、24.3%和53.3%;经T6热处理的Rm和Rp0.2值分别增至332、181 MPa,而A值保持不变。同时,材料由脆性断裂完全转变为韧性断裂。  相似文献   
7.
Aiming at the performance degradation of the existing presentation attack detection methods due to the illumination variation, a two-stream vision transformers framework (TSViT) based on transfer learning in two complementary spaces is proposed in this paper. The face images of RGB color space and multi-scale retinex with color restoration (MSRCR) space are fed to TSViT to learn the distinguishing features of presentation attack detection. To effectively fuse features from two sources (RGB color space images and MSRCR images), a feature fusion method based on self-attention is built, which can effectively capture the complementarity of two features. Experiments and analysis on Oulu-NPU, CASIA-MFSD, and Replay-Attack databases show that it outperforms most existing methods in intra-database testing and achieves good generalization performance in cross-database testing.  相似文献   
8.
In the present era of machines and edge-cutting technologies, still document frauds persist. They are done intuitively by using almost identical inks, that it becomes challenging to detect them—this demands an approach that efficiently investigates the document and leaves it intact. Hyperspectral imaging is one such a type of approach that captures the images from hundreds to thousands of spectral bands and analyzes the images through their spectral and spatial features, which is not possible by conventional imaging. Deep learning is an edge-cutting technology known for solving critical problems in various domains. Utilizing supervised learning imposes constraints on its usage in real scenarios, as the inks used in forgery are not known prior. Therefore, it is beneficial to use unsupervised learning. An unsupervised feature extraction through a Convolutional Autoencoder (CAE) followed by Logistic Regression (LR) for classification is proposed (CAE-LR). Feature extraction is evolved around spectral bands, spatial patches, and spectral-spatial patches. We inspected the impact of spectral, spatial, and spectral-spatial features by mixing inks in equal and unequal proportion using CAE-LR on the UWA writing ink hyperspectral images dataset for blue and black inks. Hyperspectral images are captured at multiple correlated spectral bands, resulting in information redundancy handled by restoring certain principal components. The proposed approach is compared with eight state-of-art approaches used by the researchers. The results depicted that by using the combination of spectral and spatial patches, the classification accuracy enhanced by 4.85% for black inks and 0.13% for blue inks compared to state-of-art results. In the present scenario, the primary area concern is to identify and detect the almost similar inks used in document forgery, are efficiently managed by the proposed approach.  相似文献   
9.
贝鹏志  李文英 《化工学报》2022,73(2):739-746
煤焦油物质丰富、组成复杂,其中,含杂原子的芳香族化合物以及稠环芳烃具有极高的工业应用价值,但是难以通过石化行业获取。如何“破坏”杂原子芳香族化合物和稠环芳烃间的缔合作用,是高效分离的关键和萃取剂选择难点。若对待分离体系中各物质之间的“缔合结构”有清晰的认识,便可根据不同的能量范围设计萃取剂。据此,基于分子力场分析,获得了氮/硫杂原子芳香族化合物色散作用能的范围,约为 -15~-70 kJ/mol,比照分析低共熔溶剂萃取氮/硫杂原子芳香族化合物研究动态,对增强分子间相互作用的调控手段归类,印证了可以根据待分离体系不同的能量范围来选择萃取剂,这种萃取剂选择方法可以作为分离杂原子芳香族化合物和稠环芳烃的一种新策略。  相似文献   
10.
Ammonia is considered as a promising hydrogen or energy carrier. Ammonia absorption or adsorption is an important aspect for both ammonia removal, storage and separation applications. To these ends, a wide range of solid and liquid sorbents have been investigated. Among these, the deep eutectic solvent (DES) is emerging as a promising class of ammonia absorbers. Herein, we report a novel type of DES, i.e., metal-containing DESs for ammonia absorption. Specifically, the NH3 absorption capacity is enhanced by ca. 18.1–36.9% when a small amount of metal chlorides, such as MgCl2, MnCl2 etc., are added into a DES composed of resorcinol (Res) and ethylene glycol (EG). To our knowledge, the MgCl2/Res/EG (0.1:1:2) DES outperforms most of the reported DESs. The excellent NH3 absorption performances of metal–containing DESs have been attributed to the synergy of Lewis acid–base and hydrogen bonding interactions. Additionally, good reversibility and high NH3/CO2 selectivity are achieved over the MgCl2/Res/EG (0.1:1:2) DES, which enables it to be a potential NH3 absorber for further investigations.  相似文献   
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