Synthesis and sintering at low temperature of a new nanostructured beta-Eucryptite dense compact by spark plasma sintering

The solid state reaction between kaolin and Li₂CO₃ with a 1:1 M composition has been studied in the temperature range 380°C-550 °C. The role played by Li₂CO₃ (basic medium) in the thermal transformation of the kaolin has been investigated by X-Ray diffraction, FESEM, TEM, MAS-NMR and XPS techniques. For the first time, a nanostructured high density β- Eucryptite (<10 nm) has been obtained by Spark Plasma Sintering (SPS) at 550 °C in high vacuum. The atmosphere used in sintering treatments has a determinant role in lithium migration and crystallization of β- Eucryptite. In the case of low vacuum treatments, an amorphous LiAlSiO₄ geopolymer type material was obtained. Due to exclusive properties and performances of β- Eucryptite based materials, the results reported in the present investigation open new perspectives for new nanostructured and amorphous functional materials with null thermal expansion, ionic conduction and remarkable mechanical properties.     

黄沙坪铅锌多金属矿的成矿规律及深部找矿远景

众所周知,矿物质的成分是多种多样的,社会的发展和科学的进步需要运用到多重金属矿物质,在专业人员的勘探与挖掘中,发现了黄沙坪铅锌多金属矿,这个矿区中有丰富的有色金属,这个矿的发掘为研究成矿规律提供了物质基础,同时也为深部找矿提供了可靠的依据。本文主要分析黄沙坪铅锌多金属矿的成矿规律及深部找矿远景。     

Fabrication of 3D structures via direct ink writing of kaolin/graphene oxide composite suspensions at ambient temperature

Kaolin/graphene oxide composite has been widely utilized in aero-space and architectural engineering applications due to its excellent mechanical property. Direct ink writing (DIW) is a freeform rapid prototyping technology that could be used to accurately fabricate the resulting size with complex shapes. In this study, we reported the DIW of kaolin/graphene oxide (GO) composite suspensions (KGCS) to assemble 3D structures at ambient temperature for the first time. The effects of GO on the chemical constitution and microstructure of kaolin suspensions were investigated. Rheology was characterized to ensure printability of KGCS. The addition of GO in kaolin suspensions quickened a flocculation structure, which dramatically changed their rheology properties. The DIW of 3D structures from the optimal KGCS sample maintained their initial shape without spreading. The flexural and compressive strengths of the dried optimal KGCS samples were obviously enhanced due to the improvement and reduction of the micro-defects compared from cured kaolin matrix.     

湖北郧西西部地区金、锑矿成矿要素及成矿模式

湖北郧西西部地区金、锑矿位于秦岭泥盆系多金属成矿带的东南部镇旬成矿区的东侧,通过对郧西西部地区金、锑矿的成矿规律的综合分析和成矿要素的总结归纳,认为该区金、锑矿受构造、岩性控制。     

内乡县李沟矽线石矿床地质特征及矿床成因

李沟矽线石矿床位于“豫西南高铝三石成矿带”中,受区域地层、构造及岩浆活动影响显著,属沉积变质矿床。该矿床赋存于古元古界雁岭沟组片岩内,矿床受地层和褶皱构造控制,矿体呈层状产出,成矿地质条件较好。本文在研究前人地质勘查资料的基础上,总结了该矿床的区域及矿区成矿地质条件,并对该地区矽线石矿的矿床成因、找矿标志进行了探讨。笔者认为李沟矽线石矿床及区域地层、构造、岩浆活动构成了“三位一体”的控矿机制,该矿床的周边地区内矽线石矿床(点)分布较多,李沟矽线石矿床及外围地区具有寻找矽线石矿的较好找矿前景。     

水处理对CSP钢厂表面纵裂的影响和优化

文章讨论紧凑型热带钢生产工艺(CSP)由于结晶器传热导致的产品质量问题。结晶器均匀传热对于保证高速薄板坯连铸机的最佳性能至关重要,铜板传热速率的差异导致固化坯壳内出现温度梯度,造成表面缺陷。对该CSP钢厂的产品质量问题进行分析后发现,在结晶器的水质参数与产品表面缺陷频率增加之间存在一定联系。在实施了工程学解决方案后,即在采用独特的水处理技术、改进机械设备和实施创新的自动控制后,减少了水侧沉积,改进结晶器传热均匀性并降低表面纵裂缺陷率。     

东昆仑沙丘低缓磁异常区深部铁多金属矿床找矿标志

那陵郭勒河沙丘地区位于东昆仑祁漫塔格早古生代裂陷槽,经历了早古生代及晚古生代—早中生代的复合造山作用,发育多期次岩浆活动和成矿作用,具有较好的铁多金属找矿前景。文章通过研究沙丘铁多金属矿的成矿地质背景、矿床特征、地磁异常和地球化学异常等,探讨了其找矿标志。研究表明:沙丘地区铁多金属矿床成因类型属接触交代型(矽卡岩型),矽卡岩与磁铁矿体在空间分布紧密共生,是重要的找矿标志;引起该区磁异常的主要地质体为闪锌磁铁矿矿石、闪锌磁铁矿化矽卡岩、矽卡岩、闪长岩、硅质岩、玄武岩、钾长花岗斑岩;利用物探磁异常找寻磁铁矿作用显著,在低缓磁异常区、正负异常接触部位是找寻铁多金属矿最重要也是最直接的找矿标志。     

秘鲁Pachagon铜矿床岩石地球化学特征及成因

帕加贡铜矿床位于秘鲁北部重要斑岩成矿带上,文章就该区岩相学、矿相学、岩石化学及稀土微量元素地球化学等方面进行了研究,并依据宏观地质产状、矿石矿物组成、结构构造及生成顺序、主微量元素组成特征等,总结了矿床成因,推测矿区成矿模型。该区砂岩中的构造破碎带是矿体的主要产出部位,为受构造控制的次生铜富集带,但有证据显示其成矿与深部岩体存在一定关系:(1)矿石镜下见热液成因黄铜矿及半自形中高温矿物晶出;(2)铜的富集过程伴随不相容元素含量的递增;(3)矿物组合由浅至深辉铜矿减少,黄铜矿、磁黄铁矿增加,且随深度增加,硅化逐渐增强。综合判断矿区成矿类型:浅部为受构造控制的次生富集带铜矿,深部为与岩体有关的斑岩型铜矿床。     

广西钨钼矿成矿规律

广西地处古中国构造域南端,是中国著名的有色金属基地,钨钼资源较丰富。广西钨钼矿矿床类型以热液脉型和矽卡岩型为主,成矿时代分布较广,包括加里东晚期、印支晚期及燕山晚期,区内大型钨钼矿床主要成矿于燕山期。钨钼矿床的空间分布与构造和岩浆岩关系密切,区域性断裂和富含W、Mo等成矿元素的复式岩体对成矿更加有利。本文对广西区内主要钨钼矿床进行了梳理,总结了广西钨钼矿成矿规律,并以典型钨钼矿床特征为依据,划分了11个矿床成矿系列,对区内下一步找矿具有指导意义。     

大沽排污河沉积物中重金属的分布特性研究

通过对大沽河上、中游及其支流44个点位沉积物的采样及检测，分析了沉积物中重金属（Cu、Pb、Zn、Cd、Cr、Ni、Hg、As）的分布特点及相关关系。结果显示，大沽河上、中游的沉积物中重金属含量之间存在着相关关系，部分沉积物中重金属含量超标，河床中部沉积物的厚度最大，而在河床两侧重金属含量出现极值，这为河道疏浚及河床断面设计提供了参考。