Review on synthesis of porous TiO2-based catalysts for energy conversion systems

Porous TiO₂-based catalysts have recently received remarkable attention in the field of energy conversion systems, including hydrogen/oxygen evolution reaction, oxygen/nitrogen reduction reaction, and photodegradation of pollutants owing to their unique structure, large surface area, and good chemical stability. In this report, we review existing research on porous TiO₂-based catalysts for energy conversion systems during the past four years. First, the advantages of porous TiO₂-based catalysts are introduced. Next, the synthetic approaches in developing porous TiO₂-based catalysts are summarized. The different types of energy conversion systems based on porous TiO₂-based catalysts are then presented. Finally, the challenges and future perspectives in synthesizing porous TiO₂-based catalysts are discussed.     

Effect of Operating Parameters on Gas‐Solid Hydrodynamics and Heat Transfer in a Spouted Bed

Through a combined computational fluid dynamics and discrete element method approach, the effect of the operating parameters on the hydrodynamics and heat‐transfer properties of gas‐solid two‐phase flows in a spouted bed are extensively investigated. Considering the high velocity in the fountain region, gas turbulence is resolved by employing the large‐eddy simulation. The rolling friction model is adopted for more precise predictions of solid behavior near the wall. Subsequently, the gas‐solid flow patterns, gas‐solid velocities, and temperature evolution are investigated. Moreover, different operating conditions and geometry configurations are evaluated with respect to heat‐transfer performance. The results provide a fundamental understanding of heat‐transfer mechanisms in spouted beds.     

Ni2V2O7 dandelion microsphere for a high-performance electrocatalyst in water splitting

Water splitting is an effective way to produce hydrogen to solve the energy crisis problem, and inorganic metal compounds are widely used in electrocatalysis field due to efficient hydrogen evolution reaction (HER). Herein, we synthesize Ni₂V₂O₇ dandelion microsphere from nickel nitrate and vanadium pentoxide by “one-step hydrothermal” way, which exhibits large specific surface area of 102.74 m² g⁻¹. The as-prepared Ni₂V₂O₇ microsphere shows good electrocatalysis performances including OER overpotential of 358 mV and good stability, as well as HER overpotential of 195 mV. Furthermore, the Ni₂V₂O₇ microsphere electrode is assembled to Ni₂V₂O₇ microsphere//Ni₂V₂O₇ microsphere system, showing the water splitting voltage of 1.50 V at 10 mA cm⁻² by two-electrode method, which is much lower than those of commercial RuO₂//Pt/C system and most of spinel oxides electrocatalysts. Our work opens up a new and facile avenue for fabricating inorganic microsphere electrocatalyst in hydrogen production field.     

Compiler compatible 5.66 Mb/mm2 8T 1R1W register file in 14 nm FinFET technology

1-read/1-write (1R1W) register file (RF) is a popular memory configuration in modern feature rich SoCs requiring significant amount of embedded memory. A memory compiler is constructed using the 8T RF bitcell spanning a range of instances from 32 b to 72 Kb. An 8T low-leakage bitcell of 0.106 μm² is used in a 14 nm FinFET technology with a 70 nm contacted gate pitch for high-density (HD) two-port (TP) RF memory compiler which achieves 5.66 Mb/mm² array density for a 72 Kb array which is the highest reported density in 14 nm FinFET technology. The density improvement is achieved by using techniques such as leaf-cell optimization (eliminating transistors), better architectural planning, top level connectivity through leaf-cell abutment and minimizing the number of unique leaf-cells. These techniques are fully compatible with memory compiler usage over the required span. Leakage power is minimized by using power-switches without degrading the density mentioned above. Self-induced supply voltage collapse technique is applied for write and a four stack static keeper is used for read Vmin improvement. Fabricated test chips using 14 nm process have demonstrated 2.33 GHz performance at 1.1 V/25 °C operation. Overall V_min of 550 mV is achieved with this design at 25 °C. The inbuilt power-switch improves leakage power by 12x in simulation. Approximately 8% die area of a leading 14 nm SoC in commercialization is occupied by these compiled RF instances.     

A large group linguistic Z-DEMATEL approach for identifying key performance indicators in hospital performance management

In hospital management, performance measurement is of vital importance for improving healthcare service quality. The performance of a healthcare organization is often influenced by numerous indicators, and it is unrealistic to manage them all due to the restriction of resources. In addition, the performance measurement for improvement relates to the benefits of many departments, and it is necessary for large number of experts with different backgrounds to participate in the evaluation process of healthcare indicators. In response, this study develops a large group evaluation approach using linguistic Z-numbers and decision-making trial and evaluation laboratory (DEMATEL) to determine key performance indicators (KPIs) for hospital management. For this approach, the complex and uncertain interrelation evaluations among indicators are given by experts using linguistic Z-numbers. An extended DEMATEL method is proposed to determine KPIs based on the cause and effect relationships of performance indicators. Finally, a case study in a rehabilitation hospital is presented to illustrate the effectiveness and usefulness of the proposed large group linguistic Z-DEMATEL approach. The results indicate that incidents/errors, accidents/adverse events, nosocomial infection, nursing technology pass rate, and length of stay are KPIs for the given application.     

高精度大跨距同轴孔的精密研磨加工

对高精度大跨距同轴孔的加工现状进行了分析,确认采用现有加工方法无法满足要求。在此基础上,提出针对高精度大跨距同轴孔采用精密研磨加工,并改进了研磨工具。介绍了高精度大跨距同轴孔精密研磨加工的注意事项。这一方法可应用于加工孔距1 m以内的高精度大跨距同轴孔,加工效果良好。     

Structural health monitoring system based on multi-agent coordination and fusion for large structure

In practical applications of structural health monitoring technology, a large number of distributed sensors are usually adopted to monitor the big dimension structures and different kinds of damage. The monitored structures are usually divided into different sub-structures and monitored by different sensor sets. Under this situation, how to manage the distributed sensor set and fuse different methods to obtain a fast and accurate evaluation result is an important problem to be addressed deeply. In the paper, a multi-agent fusion and coordination system is presented to deal with the damage identification for the strain distribution and joint failure in the large structure. Firstly, the monitoring system is adopted to distributedly monitor two kinds of damages, and it self-judges whether the static load happens in the monitored sub-region, and focuses on the static load on the sub-region boundary to obtain the sensor network information with blackboard model. Then, the improved contract net protocol is used to dynamically distribute the damage evaluation module for monitoring two kinds of damage uninterruptedly. Lastly, a reliable assessment for the whole structure is given by combing various heterogeneous classifiers strengths with voting-based fusion. The proposed multi-agent system is illustrated through a large aerospace aluminum plate structure experiment. The result shows that the method can significantly improve the monitoring performance for the large-scale structure.     

百吨级支承辊大型钢锭浇铸工艺实践与研究

支承辊应具备以下性能:(1)高的抗接触疲劳强度和抗剥落性;(2)足够的硬度和耐磨性;(3)足够的硬化层和过渡层深度;(4)良好的冶金质量保证使用可靠性。这些冶金质量主要包括控制稳定的化学成分、低含量的残余元素、极低含量的气体、较低的夹杂物含量和良好的夹杂物类型、优良的铸锭表面质量和内部质量。     

Fully coupled LES-DEM of particle interaction and agglomeration in a turbulent channel flow

Coupled large eddy simulation and the discrete element method are applied to study turbulent particle–laden flows, including particle dispersion and agglomeration, in a channel. The particle–particle interaction model is based on the Hertz–Mindlin approach with Johnson–Kendall–Roberts cohesion to allow the simulation of van der Waals forces in a dry air flow. The influence of different particle surface energies, and the impact of fluid turbulence, on agglomeration behaviour are investigated. The agglomeration rate is found to be strongly influenced by the particle surface energy, with a positive relationship observed between the two. Particle agglomeration is found to be enhanced in two separate regions within the channel. First, in the near-wall region due to the high particle concentration there driven by turbophoresis, and secondly in the buffer region where the high turbulence intensity enhances particle–particle interactions.     

The thermal behaviour of French water bodies: From ponds to Lake Geneva

The management of French freshwater bodies (lakes, reservoirs, ponds, etc.) needs to face the challenges imposed by the effects of climate change and by legal requirements to develop standards for water temperature and other physicochemical indicators. While 1D hydrodynamical models could be helpful in improving the knowledge of the thermal and hydrodynamic behaviour of French water bodies, the scarcity of data for calibration and validation, in addition to the unavailability of some forcing data, makes their application difficult for most French water bodies. In this article we explore an alternative statistical approach that takes advantage of the available data in order to inform future modelling applications. We used official monitoring data and satellite measurements to study the thermal characteristics of more than 400 French water bodies (depth: 1–310 m, surface area: 0.1–577 km², volume: 0.1–89,000 hm³). The objective was to identify the importance of size on their thermal behaviour. For this we analysed the annual temperature cycle, the summer temperature profiles and within-lake spatial variability. Together with size, geography and transparency determine the thermal behaviour of water bodies through complex interactions. As a result of the analysis we propose a classification of French water bodies as a function of depth and surface area that reflects the summer vertical temperature gradient and the processes influencing the deepening of the thermocline.