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Silica gel or zeolites AlPO-5 and SAPO-34 are recommended as adsorbents in water-driven heat pumps because of their selective water uptake. Secondary energy, like solar energy, can be used for regeneration of loaded adsorbers. In case of the availability of only low energy levels, the use of dealuminated Y zeolite (DAY) is the better choice because of the infinitely variation of its hydrophilic properties by tailoring of the framework Si/Al ratio. Actual data on the hydrothermal stability of DAY are lacking. Thus, we report on the long-term behavior of DAY zeolites with different Si/Al ratios. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(95):40340-40348
The enhancement in intrinsic catalytic activity and material conductivity of an electrocatalyst can leads to promoting HER activity. Herein, a successful nitrogenation of CoS2 (N–CoS2) catalyst has been investigated through the facile hydrothermal process followed by N2 annealing treatment. An optimized N–CoS2 catalyst reveals an outstanding hydrogen evolution reaction (HER) performance in alkaline as well as acidic electrolyte media, exhibiting an infinitesimal overpotential of ?0.137 and ?0.097 V at a current density of ?10 mA/cm2 (?0.309 and ?0.275 V at ?300 mA/cm2), corresponding respectively, with a modest Tafel slope of 117 and 101 mV/dec. Moreover, a static voltage response was observed at low and high current rates (?10 to ?100 mA/cm2) along with an excellent endurance up to 50 h even at ?100 mA/cm2. The excellent catalytic HER performance is ascribed to improved electronic conductivity and enhanced electrochemically active sites, which is aroused from the synergy and mutual interaction between heteroatoms that might have varied the surface chemistry of an active catalyst. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(81):34387-34396
This work develops a novel magnetic photocatalysts ZnO/SrFe12O19 (ZS) synthesized with hydrothermal process. The introduction of SrFe12O19 not only enhances the photocatalytic behavior of ZnO towards Rhodamine B (RhB) decomposition, but also reinforces the recycling stability. Especially, ZS-5 composite exhibits the optimal photocatalytic performance, and the RhB decomposition reaches 99.5% after being exposed to simulative sunlight for 70 min, which is obviously superior to that of bare ZnO. Furthermore, the ZS-5 can be recovered from RhB solution by an extra magnet space and reused. After five recycles, the RhB removal efficiency can still be maintained over 90%. Such prominent photocatalytic property and stability of ZS-5 are associated with the greatly improved detachment efficiency of photoexcited carriers in a magnetic field. This study could provide a new-type recyclable photocatalyst that can effectively purify dye wastewater for convenient recovery. 相似文献
5.
《Ceramics International》2022,48(15):21317-21326
1T phase molybdenum disulfide (1T-MoS2) has aroused extensive concern in energy storage devices such as supercapacitors due to its large interlayer spacing, high conductivity and good hydrophilicity. However, it is struggle to synthesize 1T-MoS2 with stable 1T phase with high content. Herein, Ammonium ion intercalation molybdenum disulfide (A-MoS2) with high 1T content and stable 3D microsphere structure was successfully synthesized using a facile hydrothermal method. We explained the feasibility of ammonium ion (NH4+) intercalation through density functional theory (DFT) calculations and proved the successful intercalation of NH4+ by XRD and XPS. Through XPS fitting, the 1T phase content is calculated as high as 83.1%. The as-prepared A-MoS2 presents a stable 3D microsphere structure with the interlayer spacing expanded to 0.93 nm, which provides a wide ion diffusion channel that allows ions to pass through quickly. Moreover, the high 1T content increases the hydrophilicity of MoS2, thereby improving the wettability of the electrode, which contributes to the interaction between the electrolyte and electrode. In 1 M Na2SO4, A-MoS2 electrode material displays high specific capacitance of 228 F g?1 at 5 mV s?1 and retains 127 F g?1 at 80 mV s?1, which proves the good rate capability. Furthermore, the assembled α-MnO2//A-MoS2 asymmetric supercapacitor (ASC) displayed a wide operating voltage of 2.1 V. The assembled ASC displays a high energy density of 35.8 Wh?kg?1 at a power density of 525.0 W kg?1, which indicates excellent energy storage performance. 相似文献
6.
《International Journal of Hydrogen Energy》2022,47(88):37171-37182
In this work, copper sulfide particles are synthesized with different Co doping concentrations such as 0, 1 and 5% at 80 °C by optimizing synthesis times from 1 to 3 h. Copper sulfide particles possess two structural phases of covellite CuS and digenite Cu9S5. The increase in synthesis time from 1 to 3 h increases the Cu9S5 phase growth and changes the morphology from flower to microsphere. The CuS synthesized with 0, 1 and 5% Co dopant concentrations demonstrate flower consisting of agglomerated nanosheets, microsphere and flower like microsphere. The elemental investigation substantiates Co ions presence in CuS microspheres. The A1g (LO) mode intensity is decreased with increase in Co dopant concentration confirming Co incorporation into CuS microsphere. The CuS synthesized with 0, 1, 5% Co dopants exhibit 322 mV, 305 mV and 289 mV to attain 100 mA/cm2 in 1 M KOH seawater. The CuS synthesized with 5% Co dopant demonstrates higher double layer capacitance (Cdl) of 173.9 mFcm?2 and lower charge transfer resistance (Rct) of 6.07 Ω with 78.84% retention after 10 h continuous stability than that of the other pristine (118.3 mFcm?2, 13.72 Ω) and 1% Co doped CuS microsphere (165.7 mFcm?2, 8.55 Ω) indicating more surface active site and rapid charge carrier transport, respectively. 相似文献
7.
《International Journal of Hydrogen Energy》2022,47(1):276-291
To the best of our knowledge, this is the first time to report the preparation of a dotted nanowire arrayed by 5 nm sized palladium and nickel composite nanoparticles (denoted as PdxNiy NPs) via a hydrothermal method using NU and PdO·H2O as the starting materials. The samples prepared at the mass ratio of NU to PdO·H2O 1:1, 1:2 and 2:1 were, respectively, nominated as catalyst c1, c2 and c3. The chemical compositions of all synthesized catalysts were mainly studied by using X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), revealing that metallic Ni was one main component of all prepared catalysts. Surprisingly, the main diffraction peaks appearing in the XRD patterns of all prepared catalysts were assigned to the metallic Ni rather than the metallic Pd. Very interestingly, as indicated by the TEM images, a large number of dotted nanowires arrayed by numerous equidistant 5 nm sized nanoparticles were distinctly exhibited in catalyst c1. More importantly, when being used as electrocatalysts for EOR, all prepared catalysts exhibited an evident electrocatalytic activity towards EOR. In the cyclic voltammetry (CV) test, the peak current density of the forward peak of EOR on catalyst c1 measured at 50 mV s?1 was as high as 56.1 mA cm?2, being almost 9 times higher than that of EOR on catalyst c3 (6.3 mA cm?2). Particularly, the polarized current density of EOR on catalyst c1 at 3600 s, as indicated by the chronoamperometry (CA) experiment, was still maintained to be around 1.47 mA cm?2, a value higher than the latest reported data of 1.3 mA cm?2 (measured on the pure Pd/C electrode). Presenting a novel method to prepare dotted nanowires arranged by 5 nm sized nanoparticles and showing the significant eletrocatalytic activities of the newly prepared dotted nanowires towards EOR were the major contributions of this preliminary work. 相似文献
8.
Fahad A. Alharthi M. Shashank Shashikanth J Viswantha R Abdulaziz Ali Alghamdi JariS. Algethami Mabkhoot A. Alsaiari Mohammed S. Jalalah Nagaraju Ganganagappa 《Ceramics International》2021,47(7):10242-10249
The high capacity anode material is required to replace the most commonly used anode - graphite to keep up the global demand to achieve the goal. Multi-metal oxide has gained keen attention for its higher theoretical capacity and relatively stable than a single metal oxide. α-SnWO4 has a theoretical capacity of 850 mAh g?1 which is greater than graphite (372 mAh g?1). α-SnWO4 has been synthesized through low-temperature hydrothermal method using tin chloride and sodium tungstate as a precursor in acidic medium (succinic acid) at 200 °C for 12 h. The obtained product has been characterized using various analytical tools such as XRD, FT-IR, UV-DRS, BET, PL, SEM, and HR-TEM. XRD analysis shows the orthorhombic phase with a crystallite size of ~25 nm α-SnWO4has been examined as an electrode material for Li-ion battery (LIB) and displays an initial discharge capacity of 985 mAh g?1. Columbic efficiency close to 100% has been observed for 100 cycles. The stability of the electrode material was studied at different C-rates. Band-gap calculated using UV-DRS (Eg = 1.9 eV) shows that α-SnWO4 is a good candidate for photocatalytic degradation. Results of the photocatalytic experiment using methylene blue (MB) as a model pollutant in an aqueous medium shows good results. The above applications show that α-SnWO4 is multifunctional materials for diverse applications. 相似文献
9.
《Ceramics International》2021,47(21):29660-29669
Hydroxyapatite (HA) powder has been successfully synthesized from low-cost Indian clam seashells by using hydrothermal method. The mixture of tri-calcium phosphate [Ca3(PO4)2], heat-treated ball-milled clam seashell, and demineralized water are heat-treated at several temperatures (700 °C, 800 °C, 900 °C, 1000 °C, and 1100 °C) for various time periods (1 h, 2 h, and 3 h) to perform the hydrothermal reactions. The phases and microstructure of the solid-state reaction products are analyzed through X-ray diffraction (XRD) method and field emission scanning electron microscopy (FESEM) respectively. The crystallite size of all the synthesized powders is calculated by using Scherrer's model. Mainly HA phase is obtained in all the different reaction products. However, these HAs are found to be non-stoichiometric in nature. As per the literature, non-stoichiometric HA is a more biologically active material compared to the stoichiometric one. Almost pure HA is formed with any selected reaction temperature applied for 2 h time duration. The crystallinity and Ca/P ratio of the synthesized pure HA are estimated by using standard model and energy-dispersive X-ray spectroscopy (EDS) analysis, respectively. The highest amount of near stoichiometric crystalline HA has been obtained at 900 °C of reaction temperature applied for 2 h time duration. With raising reaction temperature, the grain size of pure HA is found to be increased. Needle/rod shaped nano grains are noticed to form at lower reaction temperature whereas; beyond 1000 oC of temperature globular/spherical shaped grains are also observed to form. At 3 h reaction time agglomeration of grains is found to occur in all the synthesized powders. 相似文献
10.
Felix Schmutzler Christopher Zschiesche Juliane Titus David Poppitz Jens Freiding Rainer Rakoczy Andreas Reitzmann Roger Gläser 《化学,工程师,技术》2021,93(6):981-989
The hydroisomerization of two long-chain n-alkane mixtures was investigated over bifunctional Pt/H-ZSM-5 catalysts before and after dealumination of preshaped zeolite/binder pellets. The hydroisomerization over the dealuminated catalysts leads to more isomers and less cracking products. Consequently, higher ratios of multi- to mono-branched isomerization products are formed as expected for large- rather than medium-pore zeolites. This indicates a higher availability of space in the vicinity of the active sites and provides an attractive route to make medium-pore zeolites suitable for upgrading higher boiling hydrocarbon feeds. 相似文献