全文获取类型
收费全文 | 18490篇 |
免费 | 1477篇 |
国内免费 | 652篇 |
专业分类
电工技术 | 611篇 |
技术理论 | 1篇 |
综合类 | 1062篇 |
化学工业 | 3827篇 |
金属工艺 | 3821篇 |
机械仪表 | 729篇 |
建筑科学 | 623篇 |
矿业工程 | 1576篇 |
能源动力 | 530篇 |
轻工业 | 730篇 |
水利工程 | 102篇 |
石油天然气 | 274篇 |
武器工业 | 52篇 |
无线电 | 358篇 |
一般工业技术 | 2104篇 |
冶金工业 | 3818篇 |
原子能技术 | 140篇 |
自动化技术 | 261篇 |
出版年
2024年 | 22篇 |
2023年 | 178篇 |
2022年 | 411篇 |
2021年 | 545篇 |
2020年 | 531篇 |
2019年 | 448篇 |
2018年 | 457篇 |
2017年 | 529篇 |
2016年 | 672篇 |
2015年 | 612篇 |
2014年 | 1056篇 |
2013年 | 1216篇 |
2012年 | 1180篇 |
2011年 | 1402篇 |
2010年 | 975篇 |
2009年 | 880篇 |
2008年 | 786篇 |
2007年 | 1054篇 |
2006年 | 1053篇 |
2005年 | 877篇 |
2004年 | 775篇 |
2003年 | 712篇 |
2002年 | 671篇 |
2001年 | 577篇 |
2000年 | 495篇 |
1999年 | 394篇 |
1998年 | 347篇 |
1997年 | 302篇 |
1996年 | 273篇 |
1995年 | 266篇 |
1994年 | 214篇 |
1993年 | 142篇 |
1992年 | 137篇 |
1991年 | 79篇 |
1990年 | 86篇 |
1989年 | 69篇 |
1988年 | 56篇 |
1987年 | 24篇 |
1986年 | 20篇 |
1985年 | 20篇 |
1984年 | 20篇 |
1983年 | 5篇 |
1982年 | 17篇 |
1981年 | 12篇 |
1980年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 17 毫秒
1.
In this work, we designed a magnetically-separable Fe3O4-rGO-ZnO ternary catalyst, ZnO anchored on the surface of reduced graphene oxide (rGO)-wrapped Fe3O4 magnetic nanoparticles, where rGO, as an effective interlayer, can enhance the synergistic effect between ZnO and Fe3O4. The effects of three operational parameters, namely irradiation time, hydrogen peroxide dosage, and the catalyst dosage, on the photo-Fenton degradation of methylene blue and methyl orange were investigated. The results showed that the Fe3O4-rGO-ZnO had great potential for the destruction of organic compounds from wastewater using the Fenton chemical oxidation method at neutral pH. Repeatability of the photocatalytic activity after 5 cycles showed only a tiny drop in the catalytic efficiency. 相似文献
2.
《Ceramics International》2021,47(23):32610-32618
AA7075 + 6%B4C+3%ZrC nano hybrid composite was successfully fabricated, with nano reinforcements composition in AA7075 alloy selected based on previous investigation, to achieve better mechanical performance. Two different sintering techniques, namely conventional and microwave, were implemented to determine the effect on microstructural and mechanical properties. Microstructural investigation was performed with the help of W-SEM. Tensile, compression, and hardness were measured with the help of UTM and Vickers microhardness machine. Porosity was calculated by using Archimedes principle. It was observed that the added nano ZrC particles formed agglomerates and the B4C particles were distributed homogenously. Composites processed by microwave sintering showed excellent mechanical properties compared to the conventionally sintered composites. No intermetallic compounds were detected in microwave sintered composites through XRD analysis, indicating strong and clean interface bonds between matrix and reinforcement particles. High strain to fracture value of 12.24% was noted in microwave sintered nano hybrid composite, while it was 6.12% for conventional sintered one. Fractography revealed no peeling action of reinforcements from the matrix material, and the mode of failure was brittle. It was concluded that, while fabricating nano range hybrid composites, the implementation of advanced sintering technique (microwave sintering) with low sintering temperatures and low sintering times with internal heat generations, helps in eliminating defects that may develop because of high surface energies of nano range reinforcements. 相似文献
3.
4.
Effect of milling ball size on the densification and optical properties of transparent Y2O3 ceramics
Hyeon-Myeong Oh Young-Jo Park Ha-Neul Kim Jae-Woong Ko Hyun-Kwuon Lee 《Ceramics International》2021,47(4):4681-4687
In this study, we report highly transparent Y2O3 ceramics fabricated by hot-pressing only at 1500 °C without a HIP treatment, featuring in-line transmittance levels of 77% and 84% at a wavelength of 400 and 1100 nm, respectively with the grain size suppressed to 710 nm. The effect of the ball size during the grinding of Y2O3 powders on the correlation between the thus-prepared Y2O3 powders and the optical properties of the hot-pressed samples is demonstrated for the first time. With a decrease in the diameter of the ZrO2 balls from 5 mm to 1 mm, the milling efficiency was enhanced and admirable transparency of Y2O3 was attained at a short milling time. However, several micron-sized pores remained in the transparent specimens prepared with 1 mm balls, originating from the inhomogeneously packed region of the green body. Finally, the 2 mm was found to be optimum for obtaining a fine-grained and pore-free microstructure with the best in-line transmittance of Y2O3 ceramics. 相似文献
5.
Bushra Bashir Muhammad Usman Khalid Muhammad Aadil Sonia Zulfiqar Muhammad Farooq Warsi Philips O. Agboola Imran Shakir 《Ceramics International》2021,47(3):3603-3613
NiO nanostructure was synthesized using a simple co-precipitation method and was embedded on reduced graphene oxide surface via ultrasonication. Structural investigations were made through X-ray diffraction (XRD) and functional groups were confirmed by Fourier transform infrared spectroscopy (FTIR). XRD analysis revealed the grain size reduction with doping. Fourier transform infrared spectroscopy confirmed the presence of metal-oxygen bond in pristine and doped NiO nanostructure as well as the presence of carbon containing groups. Scanning electron microscopy (SEM) indicated that the particle size decreased when NiO nanostructure was doped with copper. BET surface area was found to increase almost up to 43 m2/g for Cu doped NiO nanostructure/rGO composite. Current-voltage measurements were performed using two probe method. UV–Visible spectroscopic profiles showed the blue and red shift for Cu doped NiO nanostructure and Cu doped NiO Nanostructure/rGO composite respectively. Rate constant for Cu doped NiO nanostructure/rGO composite found to increase 4.4 times than pristine NiO nanostructure. 相似文献
6.
《Ceramics International》2021,47(23):32963-32968
Effects of carbon source in single-source ZrC-based liquid precursors on the properties of the precursors and precursor-derived nano ZrC powders were investigated. The liquid precursors were prepared by directly blending and heating zirconium n-butoxide with either 2,4-pentanedione, benzoyl acetone or 1,3-diphenyl-1,3-propanedione additives which have the same chemical composition and structure except for the number of benzene rings (0, 1 and 2, respectively) in order to control the carbon content in the precursors. The ceramic yield of the precursor decreased as the number of benzene rings in the precursors increased. The stability of the precursors in air and the carbon content of the ceramic powder increased when using 1,3-diphenyl-1,3-propanedione additive. X-ray pure nano zirconium carbide powders with ultra-fine size (30 nm), isotropic shape and homogeneous particle size distribution were synthesized from the liquid precursors containing two benzene rings in the structure. Compared with ZrC powders derived from the precursors containing zero or one benzene ring, the powder from the precursor containing two benzene rings was finer and more homogeneous in size distribution. 相似文献
7.
8.
9.
《Advanced Powder Technology》2022,33(8):103664
Powder transport systems are ubiquitous in various industries, where they can encounter single powder flow, two-phase flow with solids carried by gas or liquid, and gas–solid–liquid three-phase flow. System geometry, operating conditions, and particle properties have significant impacts on the flow behavior, making it difficult to achieve good transportation of granular materials. Compared to experimental trials and theoretical studies, the numerical approach provides unparalleled advantages over the investigation and prediction of detailed flow behavior, of which the discrete element method (DEM) can precisely capture complex particle-scale information and attract a plethora of research interests. This is the first study to review recent progress in the DEM and coupled DEM with computational fluid dynamics for extensive powder transport systems, including single-particle, gas–solid/solid–liquid, and gas–solid–liquid flows. Some important aspects (i.e., powder electrification during pneumatic conveying, pipe bend erosion, non-spherical particle transport) that have not been well summarized previously are given special attention, as is the application in some new-rising fields (ocean mining, hydraulic fracturing, and gas/oil production). Studies involving important large-scale computation methods, such as the coarse grained DEM, graphical processing unit-based technique, and periodic boundary condition, are also introduced to provide insight for industrial application. This review study conducts a comprehensive survey of the DEM studies in powder transport systems. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(75):32121-32132
This study focused on the large band gap of TiO2 for its use as a photocatalyst under light emitting diode (LED) light irradiation. The photocatalytic activities of core–shell structured Au@TiO2 nanoparticles (NPs), nitrogen doped Au@TiO2 NPs, and Au@TiO2/rGO nanocomposites (NCs) were investigated under various light intensities and sacrificial reagents. All the materials showed better photocatalytic activity under white LED light irradiation than under blue LED light. The N-doped core–shell structured Au@TiO2 NPs (Au@N–TiO2) and Au@TiO2/rGO NCs showed enhanced photocatalytic activity with an average H2 evolution rate of 9205 μmol h?1g?1 and 9815 μmol h?1g?1, respectively. All these materials showed an increasing rate of hydrogen evolution with increasing light intensity and catalyst loading. In addition, methanol was more suitable as a sacrificial reagent than lactic acid. The rate of hydrogen evolution increased with increasing methanol concentration up to 25% in DI water and decreased at higher concentrations. Overall, Au@TiO2 core–shell-based nanocomposites can be used as an improved photocatalyst in photocatalytic hydrogen production. 相似文献