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排序方式: 共有1336条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2022,48(6):8297-8305
Pure and Sn/Fe co-doped (0.2 at.% Sn and 0.6 at.% Fe, 0.6 at.% Sn and 0.2 at.% Fe, 1.0 at.% Sn and 1.0 at.% Fe) TiO2 nanoparticles were synthesized via a sol-gel method and subsequently calcined at different temperatures. Furthermore, the particles were analyzed by TG-DSC, XRD, TEM, HRTEM, EDS, SAED and UV–Vis for investigating the influences of dopant and calcination temperature on the thermal effect, composition, morphology, energy band gap (Eg) and the degradation efficiency of methyl orange (MO) under various light irradiations respectively. Results indicated that Sn/Fe co-doping inhibited the crystallization transformation from anatase to rutile phase of TiO2 and decreased the Eg. The increased calcination temperature and Sn/Fe co-doped effect brought about the abnormal grain growth of TiO2 nanoparticles. 0.6 at.% Sn/0.2 at.% Fe and 1.0 at.% Sn/1.0 at.% Fe co-doped TiO2 nanoparticles presented better photocatalytic performance than pure and 0.2 at.% Sn/0.6 at.% Fe co-doped TiO2 nanoparticles under visible light irradiation mainly due to the decreased Eg. On the contrary, 0.2 at.% Sn and 0.6 at.% Fe co-doped TiO2 nanoparticles calcined at 650 °C showed the most excellent photocatalytic performance under UV light irradiation, which was about twice as large as that of pure TiO2 possibly due to the formed hybrid structure of anatase and rutile phase as well as the h+-mediated decomposition pathway. 相似文献
2.
锡基材料在自然界含量丰富、价格低廉, 在电催化还原CO2制液体燃料反应中具有巨大潜力。但是较低的产物选择性和较差的稳定性限制了其应用。本工作制备的锡量子点电催化剂(Sn-QDs), 具有高效、高稳定性和高选择性的电催化还原CO2产HCOOH活性。Sn-QDs的平均颗粒尺寸仅为2~3 nm, 结晶性良好。小的颗粒尺寸增大了电化学活性面积(ECSA), Sn-QDs的ECSA约为锡颗粒的4.4倍。ECSA增大以及CO2还原反应动力学加速, 促进了CO2电化学转化。在-1.0 V (vs RHE)下, Sn-QDs/CN催化剂的HCOOH法拉第效率(FEHCOOH)达到95%, 并且在宽约0.5 V的电势范围内能够保持在83%以上。此外, Sn-QDs/CN可以在24 h内保持良好的电化学稳定性。 相似文献
3.
Zhijun Zhang Kezhen Chen Jichang Lu Qin Zou Yuhui Zhao Yongming Luo Dedong He Rongtao Li 《International Journal of Hydrogen Energy》2021,46(43):22508-22518
Sn modified CuO–CeO2 catalysts with different Sn loadings were prepared by a facile, green and solvent-free method. The effect of Sn/Ce ratio over Sn–Cu–Ce-x (x = 0, 1, 2.5, 5, 7.5) samples on CO activity and O2 selectivity was investigated. The samples were characterized by various techniques using N2-adsorption/desorption, XRD, H2-TPR, XPS, Raman and in-situ DRIFTS. It was revealed that stronger interaction between acitve sites and support, higher amounts of Sn2+ and Ce3+, associated with increased amount of oxygen vacancies, were observed on the catalyst of Sn–Cu–Ce-5. As a result, the optimized catalyst displayed an excellent catalytic performance even in the presence of CO2 and H2O. In this sense, probing the Sn modified CuO–CeO2 catalyst can elucidate some useful keys for the development of high CO2 and H2O-resistance catalyst during CO-preferential oxidation in H2-rich streams. 相似文献
4.
湖南省郴州市饭垄堆北段锡钨多金属矿位于湘南钨锡钼铋多金属成矿带东坡矿田内,成矿地质条件优越,具有很好的找矿前景。根据该矿床地质特征以及已有的地质矿产勘查成果,系统总结了矿区101、102、103号主矿体特征。在此基础上,进一步讨论了该类裂隙充填细脉带型锡钨多金属矿床在勘查过程中探矿工程布置的优化方法:即:①探矿工程不宜按每个矿带单独控制,应对整个赋矿层位进行整体控制;②应对含有毒砂、锡、钨细脉的岩性段进行连续取样化验,既可避免漏矿,又可以为将来工业指标调整后重新圈定矿体提供直接依据。 相似文献
5.
In this study, open-cell Ni–Sn–P alloy foams were prepared by electroless plating. The influence of tin content on the surface morphology and properties of Ni–Sn–P alloy foams were investigated. The surface structure of Ni–Sn–P alloy foams became more uniform and compact with the increase of Sn content. The X-ray diffraction result showed that Ni–Sn–P alloy foams gradually transformed from an amorphous structure into crystallization with the increase of heat-treatment temperature. The introduction of Sn significantly enhanced the corrosion resistance of Ni–P coatings in 3.5 wt% NaCl solution, the corrosion current density decreased from 5.022 to 0.805 μA/cm2 and the corrosion potential shifted positively from −0.423 to −0.294 V after adding 5.96 wt% Sn to Ni–P coatings. However, the corrosion resistance of Ni–Sn–P foams was deteriorated after heat treatment. Adding Sn to the Ni–P system slightly weakened the compressive strength of Ni–P binary foams. Nevertheless, significant improvement in the antioxidant performance of Ni–Sn–P alloy foams was indicated by the reduction of the mass change rate in that the mass change rate of Ni–P foams obviously reduced from 5.15% to 0.25% after adding 5.96 wt% Sn. 相似文献
6.
Effect of Ni-coated MoS2 on microstructure and tribological properties of (Cu−10Sn)-based composites
《中国有色金属学会会刊》2020,30(9):2480-2490
The (Cu−10Sn)−Ni−MoS2 composites, prepared by powder metallurgy, were studied for the effects of Ni-coated MoS2 on the microstructure, mechanical properties and lubricating properties. The mechanism of effects of Ni and MoS2 on the properties of composites was analyzed through a comparative experiment by adding Ni and MoS2 separately. The results show that the nickel wrapping around the MoS2 particles decreases the reaction rate of MoS2 with the copper matrix, and greatly improves the bonding of the matrix. The composites with 12 wt.% Ni-coated MoS2 (C12) show the optimum performance including the mechanical properties and tribological behaviors. Under oil lubrication conditions, the friction coefficient is 0.0075 with a pressure of 8 MPa and a linear velocity of 0.25 m/s. The average dry friction coefficient, sliding against 40Cr steel disc, is measured to be 0.1769 when the linear velocity and pressure are 0.25 m/s and 4 MPa, respectively. 相似文献
7.
高温度梯度(180K/cm)定向凝固方法可制备单相Mg_2Sn晶体,通过凝固理论对平-胞转换临界速率进行了计算,并预测了单相Mg_2Sn晶体的生长距离,与试验结果相吻合。此方法获得的Mg_2Sn晶体由于去除了第二相Sn的影响,可以获得更好的热电性能,在测试温度区间300~700K内,未掺杂条件下最大Seebeck系数和电导率值分别可达-261μV·K~(-1)和525?-1·m~(-1),通过Bi掺杂来对电导率进行优化后,功率因子最高可达2.29 mW·(m·K~2)~(-1)。单相Mg_2Sn晶体的热导率也得到大幅降低,500 K时,最小值为4.3 W·(m·K)~(-1),Bi掺杂量为1.5%(原子分数)时,热电优值ZT最高可达到0.21。这一方法可以为制备高性能的Mg_2B~(IV)体系三元固溶体合金提供参考。 相似文献
8.
《中国有色金属学会会刊》2020,30(8):2079-2089
The effects of Sn content on microstructure and tensile properties of as-cast and as-extruded Mg−8Li−3Al− (1,2,3)Sn (wt.%) alloys were investigated by X-ray diffractometry (XRD), optical microscopy (OM), scanning electron microscopy (SEM) and tensile test. It is found that, as-cast Mg−8Li−3Al−(1,2,3)Sn alloys consist of α-Mg+β-Li duplex matrix, MgLiAl2 and Li2MgSn phases. Increasing Sn content leads to grain refinement of α-Mg dendrites and increase in content of Li2MgSn phase. During hot extrusion, complete dynamic recrystallization (DRX) takes place in β-Li phase while incomplete DRX takes place in α-Mg phase. As Sn content is increased, the volume fraction of DRXed α-Mg grains is increased and the average grain size of DRXed α-Mg grains is decreased. Increasing Sn content is beneficial to strength but harmful to ductility for as-cast Mg−8Li−3Al−(1,2,3)Sn alloys. Tensile properties of Mg−8Li−3Al− (1,2,3)Sn alloys are improved significantly via hot extrusion and Mg−8Li−3Al−2Sn alloy exhibits the best tensile properties. 相似文献
9.
《International Journal of Hydrogen Energy》2020,45(51):27575-27586
This work demonstrates the effect of tin (Sn) doping on the manufacturing, electrochemical performance, and carbon deposition in dry biogas-fuelled solid oxide fuel cells (SOFCs). Sn doping via blending in technique alters the rheology of tape casting slurry and increases the Ni/ScSZ anode porosity. In contrast to the undoped Ni/ScSZ cells, where open-circuit voltage (OCV) drops in biogas, Sn–Ni/ScSZ SOFC OCV increases by 3%. The maximum power densities in biogas are 0.116, 0.211, 0.263, and 0.314 W/cm2 for undoped Ni/ScSZ, undoped Ni/ScSZ with 3 wt% pore former, Sn–Ni/ScSZ and Sn–NiScSZ with 1 wt% pore former, respectively. Sn–Ni/ScSZ reduces the effect of the drop in the maximum power densities by 26%–36% with the fuel switch. A 1.28–2.24-fold higher amount of carbon is detected on the Sn–Ni/ScSZ samples despite the better electrochemical performance, which may reflect an enhanced methane decomposition reaction. 相似文献
10.
《Ceramics International》2020,46(9):12921-12927
The further development of clean energy requires the use of more stable and reliable energy storage system. In addition to lithium ion battery power supplies, sodium ion batteries also have prospects for application and development thanks to the low cost and abundant resource. NaTi2(PO4)3 has attracted much attention due to its three-dimensional channels for sodium ion transfer. In order to meliorate sodium storage properties of NaTi2(PO4)3 electrode, a facile strategy of Sn substitution at Ti sites was employed, and a series of electrodes were successfully synthesized through sol-gel route. The electrochemical performances of Sn substituted composites are significantly improved compared with bare NaTi2(PO4)3/C. And it was found that NaSn0.2Ti1.8(PO4)3 (NTP/C-Sn-2) delivers the largest capacity, and it also demonstrates the outstanding cycling performances. NTP/C-Sn-2 has discharge capacity of 131.1 mAh g−1 at 4 A g−1 in rate test and 121.4 mAh g−1 at 1 A g−1 after 1000 cycles in cycling test. The experimental results show that NaTi2(PO4)3/C with Sn substitution with proper content exhibits the great potential in anode for sodium ion batteries, and can further provide reference for next generation electrode materials and battery systems. 相似文献