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排序方式: 共有6138条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(41):18018-18031
The performance of gallium promoted cobalt-ceria catalysts for ethanol steam reforming (ESR) was studied using H2O/C2H5OH = 6/1 mol/mol at 500 °C. The catalysts were synthetized via cerium-gallium co-precipitation and wetness impregnation of cobalt. A detailed characterization by N2-physisorption, XRD, H2-TPR and TEM allowed the normalization of contact time and rationalization of the role of each catalysts component for ESR. The gallium promoted catalyst, Co/Ce90Ga10Ox, was more efficient for the ethanol conversion to H2 and CO2, and the production of oxygenated by-products (such as, acetaldehyde and acetone) than Co/CeO2. The catalytic performance is explained assuming that: (i) bare ceria is able to dehydrogenate ethanol to ethylene; (ii) Ce–O–Ga interface catalyzes ethanol reforming; (iii) both Ce–O–Co and Ce–O–Ga interfaces takes part in acetone production; and (iv) cobalt sites further allow C–C scission. It is suggested that a cooperative role between Co and Ce–O–Ga sites enhance the H2 and CO2 yields under ESR conditions. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(55):23310-23315
Alkaline aqueous solution of sodium borohydride NaBH4 (denoted SB-fuel) is an indirect fuel when it is used to generate H2 by hydrolysis, with the as-generated H2 feeding a fuel cell, and it is a direct fuel when it is an anodic fuel of a direct fuel cell. However, SB-fuel suffers from a major drawback: NaBH4 spontaneously hydrolyzes. Our study falls within this context. We studied the instability, at the NMR scale and over 12 weeks, of a series of SB-fuels (initial NaBH4 concentration from 3.65 to 31.22 wt%, NaOH concentration from 1 to 16 M, and temperature between ?15 and 60 °C) to find the conditions at which SB-fuel can be stored for weeks in relative safety. We found that SB-fuel with a NaOH concentration of ≥8 M is relatively stable under cold conditions (?15 and 4 °C). In these conditions, NaBH4 is not prevented from hydrolyzing, but the reaction is significantly mitigated. Otherwise, our study highlights the gaps in our understanding of the SB-fuel, emphasizes SB-fuel is a new concept of fuel (it should not be seen as any current fuel), and points out the challenges for attaining higher technology readiness levels. 相似文献
3.
Power conversion efficiency (PCE) and stability are two important properties of perovskite solar cells (PSCs). Particularly, defects in the perovskite films could cause the generation of trap states, thereby increasing the nonradiative recombination. To address this issue, suitable dopants can be incorporated to react with non-bonded atoms or surface dangling bonds to passivate the defects. Herein, we introduced TiI4 into CH3NH3PbI3 (MAPbI3) film and obtained a dense and uniform morphology with large crystal grains and low defect density. The champion cell based on 0.5% TiI4-doped MAPbI3 achieved a PCE as high as 20.55%, which is superior to those based on pristine MAPbI3 (17.64%). Moreover, the optimal solar cell showed remarkable stability without encapsulation. It retained 88.03% of its initial PCE after 300 h of storage in ambient. This work demonstrates TiI4 as a new and effective passivator for MAPbI3 film. 相似文献
4.
《Ceramics International》2022,48(5):5876-5891
Hybrid lead halide perovskite solar cells (PSCs) have experienced a rapid development in the past decade and a certified efficiency up to 25.5% has been achieved. However, the presence of toxic lead component and the inherent poor thermal stability of the organic cations in the hybrid lead halide perovskites obstruct the commercial applications of their corresponding photovoltaic devices. Therefore, fabricating high-efficient all-inorganic lead-free PSCs is a promising direction. This review summarizes the related research progress, which mainly focuses on the structural and optoelectronic properties of inorganic lead-free perovskites and devices. In particular, the strategies for improving the properties and stability of Cs–Sn perovskites, as well as enhancing the photovoltaic performance of the corresponding devices are highlighted. An outlook of challenges and future directions regarding to all-inorganic lead-free PSCs are also proposed. 相似文献
5.
《Ceramics International》2021,47(18):25769-25776
Lithium-sulfur battery cathodes still remain a challenge on capacity decay due to the shuttle effect even though a series of strategies have been tried. Here we report a novel matryoshka-like CuS@void@Co3O4 architecture of double micro-cubes (μ-cubes) that locks sulfur between the CuS core and the Co3O4 shell. Plenty of existing spaces between the μ-cubes suffice a high loading of sulfur and volumetric accommodation. The robust, double closed cubes configuration greatly enhances the confinement of polysulfides. In parallel, the CuS core increases the electronic conductivity and contributes to additional capacity, while the Co3O4 shell ensures a better interface activity. A high Li+ ion diffusion coefficient is obtained during the sulfur and lithium sulfide transformation. The constructed battery displays an initial capacity up to 1480 mAh g−1, and a Coulombic efficiency (CE) exceeding 99%. A capacity retention higher than 500 mAh g−1 with a CE larger than 99.8% after cycling 400 times at 0.2 C are achieved. In addition, under a temperature of −5 °C, a high capacity of 700 mAh g−1 at 0.2 C after 200 cycles is achieved, indicating a good low-temperature tolerance. 相似文献
6.
7.
Waleeporn Donphai Orrakanya Phichairatanaphong Wantana Klysubun Metta Chareonpanich 《International Journal of Hydrogen Energy》2018,43(48):21798-21809
Nickel-based catalyst is highly active for hydrogen production through methane cracking reaction at moderate reaction temperature. However, Ni catalyst is easily deactivated by carbon encapsulation. In order to solve this problem, this research studies the effect of nickel precursors—nickel acetate (NA), nickel carbonate (NC) and nickel nitrate (NN)—on the activity and stability of nickel/bimodal porous silica (Ni/BPS) catalyst in methane cracking reaction. It was found that these nickel precursor solutions had different pH values, resulting in different interactions between surface silanol groups of BPS supports and Ni. Among these catalysts, Ni(NC)/BPS catalyst exhibited high nickel dispersion and weak interaction between Ni and BPS support; it then gave the highest CH4 conversion and better stability compared to the other catalysts. In addition, H2 yield of Ni(NC)/BPS catalyst was 2.90 and 1.40 times higher than those of Ni(NA)/BPS and Ni(NN)/BPS catalysts, respectively. Moreover, carbon nanofibers were grown in Ni(NC)/BPS and Ni(NN)/BPS catalysts, whereas carbon nanotubes were formed on Ni(NA)/BPS catalyst, due to the different nickel particle sizes, dispersions, and Ni—BPS support interactions. 相似文献
8.
Chang-Hyun Kim Jae-Yun Han Sehwa Kim Boreum Lee Hankwon Lim Kwan-Young Lee Shin-Kun Ryi 《International Journal of Hydrogen Energy》2018,43(15):7684-7692
With the aim of producing hydrogen at low cost and with a high conversion efficiency, steam methane reforming (SMR) was carried out under moderate operating conditions in a Pd-based composite membrane reactor packed with a commercial Ru/Al2O3 catalyst. A Pd-based composite membrane with a thickness of 4–5 μm was prepared on a tubular stainless steel support (diameter of 12.7 mm, length of 450 mm) using electroless plating (ELP). The Pd-based composite membrane had a hydrogen permeance of 2.4 × 10?3 mol m?1 s?1 Pa?0.5 and an H2/N2 selectivity of 618 at a temperature of 823 K and a pressure difference of 10.1 kPa. The SMR test was conducted at 823 K with a steam-to-carbon ratio of 3.0 and gas hourly space velocity of 1000 h?1; increasing the pressure difference resulted in enhanced methane conversion, which reached 82% at a pressure difference of 912 kPa. To propose a guideline for membrane design, a process simulation was conducted for conversion enhancement as a function of pressure difference using Aspen HYSYS®. A stability test for SMR was conducted for ~120 h; the methane conversion, hydrogen production rate, and gas composition were monitored. During the SMR test, the carbon monoxide concentration in the total reformed stream was <1%, indicating that a series of water gas shift reactors was not needed in our membrane reactor system. 相似文献
9.
According to Bode's gain-phase relationship, in linear time-invariant controllers, introducing an integral action to eliminate the steady-state error has an adverse effect of increased phase delay and overshoot, leading to performance deterioration. Moreover, increasing the bandwidth of the closed-loop system to enhance the low-frequency disturbance rejection invariably amplifies the sensitivity to high-frequency disturbances. Hence, the performance of the linear controllers is always limited due to these fundamental frequency- and time-domain limitations. Motivated by the desire to address the fundamental limitations of linear controllers and improve the time-varying closed-loop performance, we put forward a novel setpoint-triggered reset integrator strategy that varies the integrator cut-off frequency based on the setpoint information. Particularly, to tackle the time-varying disturbances and setpoint profiles, the proposed controller consists of a nominal linear controller and a variable-gain reset integrator. We show the global asymptotic stability of the proposed methodology using positive-real lemma along with the LaSalle's invariance principle and experimentally validate using measured frequency response function. Moreover, the efficacy of the proposed technique compared to that of the linear controller is experimentally demonstrated on a benchmark rotary servo system. Experimental results assessed using the tracking error and cumulative power spectral density substantiate that the proposed control strategy can not only improve the low-frequency disturbance rejection but also augment the high-frequency trajectory tracking performance. 相似文献
10.
This work presents a pulsatile Zone Model Predictive Control (pZMPC) for the control of blood glucose concentration (BGC) in patients with Type 1 Diabetes Mellitus (T1DM). The main novelties of the algorithm – in contrast to other existing strategies – are: (i) it controls the patient glycemia by injecting short duration insulin boluses for both, the basal and bolus infusions, in an unified manner, (ii) it performs the predictions and estimations (critical to anticipate both, hypo and hyperglycemia) based on a physiological individualized long-term model, (iii) it employs disturbance observers to compensate plant-model mismatches, (iv) it ensures, under standard assumptions, closed-loop stability, and (v) it can be used – under minor modifications – as an optimal basal–bolus calculator to emulate conventional therapies. Because of the latter characteristic, a significantly better performance is achieved, not only in terms of classical indexes (time in the normoglycemia zone, avoidance of hypoglycemia in the short term, avoidance of hyperglycemia in the long term) but also in terms of its applicability (use of the pump or injections). Such a performance is tested in a cohort of in-silico patients from the FDA-accepted UVA/Padova simulation platform, considering the most challenging scenarios. 相似文献