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1.
Dense pressure-sintered reaction-bonded Si3N4 (PSRBSN) ceramics were obtained by a hot-press sintering method. Precursor Si powders were prepared with Eu2O3–MgO–Y2O3 sintering additive. The addition of Eu2O3–MgO–Y2O3 was shown to promote full nitridation of the Si powder. The nitrided Si3N4 particles had an equiaxial morphology, without whisker formation, after the Si powders doped with Eu2O3–MgO–Y2O3 were nitrided at 1400 °C for 2 h. After hot pressing, the relative density, Vickers hardness, flexural strength, and fracture toughness of the PSRBSN ceramics, with 5 wt% Eu2O3 doping, were 98.3 ± 0.2%, 17.8 ± 0.8 GPa, 697.0 ± 67.0 MPa, and 7.3 ± 0.3 MPa m1/2, respectively. The thermal conductivity was 73.6 ± 0.2 W m?1 K?1, significantly higher than the counterpart without Eu2O3 doping, or with ZrO2 doping by conventional methods.  相似文献   
2.
C/SiC composites prepared by chemical vapor infiltration technique (CVI) have been regarded as thermal structural materials widely. However, these composites still suffer from poor functional properties like low thermal conductivity, especially in thickness direction of the composites, limiting their large-scale applications. Herein, mesophase pitch based carbon fiber (MPCF) and continuous wave laser machining were utilized to construct highly effective heat conductive micro-pipelines within CVI C/SiC composite. The effect of initial density on the final density and thermal conductivity of the as-obtained MPCF-C/SiC composites were investigated. The results revealed that higher initial density would directly enhance the thermal conductivity and reduce the negative impact of the bottle-neck effect. At temperatures between 100°C and 500°C, MPCF-C/SiC composites preserved more than threefold of the thermal conductivity (340%) when compared to reference C/SiC composites. This work provides a highly effective route for enhancing the thermal conductivity of C/SiC, which would broaden their future applications.  相似文献   
3.
介绍了高分子材料导热性能影响因素研究进展,重点阐释了聚合物基体的结构特性(链结构、分子间相互作用、取向、结晶度等)、导热填料(种类、含量、形态、尺寸等)以及制备方法等对高分子材料导热性能的影响。  相似文献   
4.
Lithium zirconium phosphate (LiZr2P3O12) thin films have been prepared on platinized silicon substrates via a chemical solution deposition approach with processing temperatures between 700°C and 775°C. Films that were subject to a single high-temperature anneal were found to crystallize at temperatures above 725°C. Crystallization was observed in films annealed after each deposited layer at 700°C and above. In both cases, grain size was found to increase with annealing temperature. Ion conductivity was found to increase with annealing temperature in singly annealed films. In per-layer annealed films ion conductivity was found to initially increase then decrease with increasing annealing temperature. A maximum ion conductivity of 1.6 × 10−6 S/cm was observed for the singly annealed 775°C condition, while a maximum ion conductivity of 5.8 × 10−7 S/cm was observed for the 725°C per-layer annealed condition. These results are consistent with an increasing influence of cross-plane, internal interface resistance and vapor phase carrier loss in the per-layer annealed samples. This work demonstrates that post-deposition processing methods can strongly affect the ion conducting properties of LiZr2P3O12 thin films.  相似文献   
5.
This study focuses on the chemistry, thermal stability, and electrical conductivity of low/intermediate pyrolysis temperature (700?900 °C) polysiloxane derived ceramics. These ceramics were modified with additional carbon derived from divinylbenzene (DVB) added to the precursor. Their electrical properties were investigated for potential uses in micro-electrical mechanical systems (MEMS) and anodes for lithium batteries. The microstructure and chemical composition was investigated by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), Raman spectroscopy, and x-ray photoelectron spectroscopy (XPS); thermogravimetric analysis (TGA) provided insight into the thermal stability; and electrochemical impedance spectroscopy (EIS) into the electrical properties of the material. The increase of pyrolysis temperature and carbon content lead to an enhancement of the electrical conductivity, higher than previously reported values for intermediate pyrolysis temperature SiOC polymer derived ceramics. A limit of the amount of DVB that can be added to PHMS to produce a hybrid precursor has also been obtained.  相似文献   
6.
The introduction of multiple heterogeneous interfaces in a ceramic is an efficient way to increase its thermal resistance. Novel porous SiC–SiO2–Al2O3–TiO2 (SSAT) ceramics were fabricated to achieve multiple heterogeneous interfaces by sintering equal volumes of SiC, SiO2, Al2O3, and TiO2 compacted powders with polysiloxane as a bonding phase and carbon as a template at 600 °C in air. The porosity could be controlled between 66% and 74% by adjusting the amounts of polysiloxane and the carbon template. The lowest thermal conductivity (0.059 W/(m·K) at 74% porosity) obtained in this study is an order of magnitude lower than those (0.2–1.3 W/(m·K)) of porous monolithic SiC, SiO2, Al2O3, and TiO2 ceramics at an equivalent porosity. The typical specific compressive strength value of the porous SSAT ceramics at 74% porosity was 3.2 MPa cm3/g.  相似文献   
7.
8.
This paper investigates the influence of suspension characteristics on microstructure and performance of suspensions plasma sprayed (SPS) thermal barrier coatings (TBCs). Five suspensions were produced using various suspension characteristics, namely, type of solvent and solid load content, and the resultant suspensions were utilized to deposit five different TBCs under identical processing conditions. The produced TBCs were evaluated for their performance i.e. thermal conductivity, thermal cyclic fatigue (TCF) and thermal shock (TS) lifetime. This experimental study revealed that the differences in the microstructure of SPS TBCs produced using varied suspensions resulted in a wide-ranging overall TBC performance. All TBCs exhibited thermal conductivity lower than 1 W/(m. K) except water-ethanol mixed suspension produced TBC. The TS lifetime was also affected to a large extent where 10 wt % solid loaded ethanol and 25 wt % solid loaded water suspensions produced TBCs exhibited the highest and the lowest lifetime, respectively. On the contrary, TCF lifetime was not as significantly affected as thermal conductivity and TS lifetime, and all ethanol suspensions showed marginally better TCF lifetime than water and ethanol-water mixed suspensions deposited TBCs.  相似文献   
9.
张辉 《特种油气藏》2021,28(2):133-138
针对塔里木油田白垩系巴什基奇克组超深裂缝性碎屑岩储层天然裂缝激活方法不明确的问题,根据摩尔-库伦破坏准则,对研究区储层天然裂缝发生剪切激活和张性激活条件进行分析,模拟测试了水力压裂和酸化压裂中的裂缝导流能力。研究结果显示:水力压裂中存在相互错动的裂缝导流能力是无错动裂缝的100~1 000倍,无错动裂缝加砂后导流能力超过1 000倍,缝网压裂过程中天然裂缝剪切滑移也会实现增产改造效果,加砂对无错动裂缝改造效果具有重要影响;在加砂条件下,裂缝是否存在错动对导流能力无本质影响。缝网酸化压裂中充填性天然裂缝在较低闭合应力下(小于20 MPa)酸岩反应时间对导流能力影响不大,在较高闭合应力下,酸岩反应时间越长,充填物溶蚀量越大,导流能力保持程度越高;充填性天然裂缝可以通过酸蚀获得有效导流能力,而非充填性天然裂缝不能通过酸蚀获得有效导流能力。研究成果为库车山前超深储层缝网改造提供了技术支持。  相似文献   
10.
有效导热系数是高温气冷球床堆热工设计和安全分析程序中的基本参数,ZBS模型广泛应用于球床结构有效导热系数的预测。本文针对ZBS模型中的关键经验型参数——接触面积系数φ进行了分析,通过对不同堆积结构球床有效导热系数的数值分析,获得了12组接触直径比和配位数及其对应的φ值,然后通过多元线性分析获得φ的计算公式。与德国SANA实验结果进行比较,发现改进后的ZBS模型预测能力优于其他模型。改进后的ZBS模型的计算结果与先前实验测量的球床主体区域的有效导热系数吻合也很好。本文研究结果可为高温气冷球床堆的设计和安全分析提供理论支持。  相似文献   
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